Cascaded organic electroluminescent devices
View Patent ↗A cascaded organic electroluminescent device includes an anode, a cathode, and a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer. The device also includes a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer, and a p-type doped organic layer wherein the p-type doped organic layer includes a dihydrophenazine derivative compound.
1. A cascaded organic electroluminescent device comprising:
a) an anode;
b) a cathode;
c) a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer;
d) a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer, and a p-type doped organic layer; and
e) wherein the p-type doped organic layer includes a dihydro-phenazine derivative compound.
2. A cascaded organic electroluminescent device comprising:
a) an anode;
b) a cathode;
c) a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer;
d) a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises an n-type doped organic layer, and a p-type doped organic layer; and
e) wherein the p-type doped organic layer includes a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 2 to form 5 or 6 member ring systems;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 3 to form 5 or 6 member ring systems;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 6 to form 5 or 6 member ring systems;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 7 to form 5 or 6 member ring systems;
R 2 and R 3 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 6 and R 7 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.
3. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
4. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
5. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
6. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
7. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
8. The cascaded organic electroluminescent device according to claim 2 wherein the p-type doped organic layer has a compound of the formula:
9. A cascaded organic electroluminescent device comprising:
a) an anode;
b) a cathode;
c) a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer;
d) a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer, an interfacial layer, and a p-type doped organic layer; and
e) wherein the p-type doped organic layer includes a dihydro-phenazine derivative compound.
10. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer has at least 90% optical transmission in the visible region of the spectrum.
11. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer comprises at least one material having an electron energy band gap less than 4.0 eV.
12. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer includes the stoichiometric oxides or nonstoichiometric oxides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
13. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer includes the stoichiometric sulfides or nonstoichiometric sulfides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
14. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer includes the stoichiometric selenides or nonstoichiometric selenides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
15. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer includes the stoichiometric nitrides or nonstoichiometric nitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
16. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer includes the stoichiometric carbides or nonstoichiometric carbides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
17. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer comprises at least one metallic material.
18. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer comprises at least one metallic material having a work function higher than 4.0 eV.
19. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer has a thickness in a range of 0.1 nm to 10 nm.
20. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer has a thickness in a range of 0.1 nm to 5 nm.
21. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer is produced by thermal evaporation.
22. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer is produced by electron-beam evaporation.
23. The cascaded organic electroluminescent device according to claim 9 wherein the interfacial layer is produced by ion-sputtering technique.
24. A cascaded organic electroluminescent device comprising:
a) an anode;
b) a cathode;
c) a plurality of organic electroluminescent units disposed between the anode and the cathode, wherein the organic electroluminescent units comprise at least a hole-transporting layer and an electron-transporting layer;
d) a connecting unit disposed between each adjacent organic electroluminescent unit, wherein the connecting unit comprises, in sequence, an n-type doped organic layer, an interfacial layer, and a p-type doped organic layer; and
e) wherein the p-type doped organic layer includes a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 2 to form 5 or 6 member ring systems;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 3 to form 5 or 6 member ring systems;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 6 to form 5 or 6 member ring systems;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 7 to form 5 or 6 member ring systems;
R 2 and R 3 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 6 and R 7 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.
25. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer has at least 90% optical transmission in the visible region of the spectrum.
26. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer comprises at least one material having an electron energy band gap less than 4.0 eV.
27. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer includes the stoichiometric oxides or nonstoichiometric oxides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
28. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer includes the stoichiometric sulfides or nonstoichiometric sulfides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
29. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer includes the stoichiometric selenides or nonstoichiometric selenides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
30. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer includes the stoichiometric nitrides or nonstoichiometric nitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
31. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer includes the stoichiometric carbides or nonstoichiometric carbides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, zinc, cadmium, gallium, thallium, silicon, germanium, lead, and antimony, or combinations thereof.
32. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer comprises at least one metallic material.
33. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer comprises at least one metallic material having a work function higher than 4.0 eV.
34. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer has a thickness in a range of 0.1 nm to 10 nm.
35. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer has a thickness in a range of 0.1 nm to 5 nm.
36. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer is produced by thermal evaporation.
37. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer is produced by electron-beam evaporation.
38. The cascaded organic electroluminescent device according to claim 24 wherein the interfacial layer is produced by ion-sputtering technique.
39. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
40. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
41. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
42. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
43. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
44. The cascaded organic electroluminescent device according to claim 24 wherein the p-type doped organic layer has a compound of the formula:
45. The cascaded organic electroluminescent device according to claim 1 wherein the p-type doped organic layer has a compound of the formula:
wherein:
R1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino or connected to R 11 to form 5 or 6 member ring systems;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino or connected to R 14 to form 5 or 6 member ring systems;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 6 to form 5 or 6 member ring systems;
R 6 and 1(7 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 7 to form 5 or 6 member ring systems;
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl;
R 11 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, connected to R 1 to form 5 or 6 member ring systems or connected to R 12 to form 5 or 6 member ring systems;
R 12 and R 13 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems; and
R 14 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, connected to R 4 to form 5 or 6 member ring systems or connected to R 13 to form 5 or 6 member ring systems.
46. The cascaded organic electroluminescent device according to claim 9 wherein the p-type doped organic layer has a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino or connected to R 11 to form 5 or 6 member ring systems;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino or connected to R 14 to form 5 or 6 member ring systems;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 6 to form 5 or 6 member ring systems;
R 6 and R 7 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, or connected to R 7 to form 5 or 6 member ring systems;
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl;
R 11 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, amino, connected to R 1 to form 5 or 6 member ring systems or connected to R 12 to form 5 or 6 member ring systems;
R 12 and R 13 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, halogen, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, thioaryl, thioalkyl, or connected to form 5 or 6 member ring systems; and
R 14 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, amino, connected to R 4 to form 5 or 6 member ring systems or connected to R 13 to form 5 or 6 member ring systems.
47. The cascaded organic electroluminescent device according to claim 1 wherein the p-type doped organic layer has a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, or amino;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino; and
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.
48. The cascaded organic electroluminescent device according to claim 9 wherein the p-type doped organic layer has a compound of the formula:
wherein
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, or amino;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino; and
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.
49. The cascaded organic electroluminescent device according to claim 1 wherein the p-type doped organic layer has a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, or amino;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino; and
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.
50. The cascaded organic electroluminescent device according to claim 9 wherein the p-type doped organic layer has a compound of the formula:
wherein:
R 1 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 4 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino;
R 5 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl, substituted alkenyl, alkoxy, aryloxy, or amino;
R 8 is hydrogen, halogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl, alkoxy, aryloxy, or amino; and
R 9 and R 10 are individually hydrogen, alkyl of from 1 to 24 carbon atoms, which are branched, unbranched, or cyclic, aryl or substituted aryl of from 5 to 24 carbon atoms, heterocyclic or substituted heterocyclic, alkenyl or substituted alkenyl.