IP Library Granted Patent US 7,018,596
Granted Patent B2
US 7,018,596 · App. 09/555,073 · Granted Mar 28, 2006

Mesoporous silica, process for the preparation of the same, and use thereof

Assignee: Asahi Kasei Kabushiki Kaisha
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Quick Facts
Patent No.
US 7,018,596
App. No.
09/555,073
Granted
Mar 28, 2006
Kind
B2
Abstract

Accordingly, the invention provides: (1) mesoporous silica characterized by having an average pore diameter in the mesopore region of from 1.5 to 10 nm, a nitrogen adsorption specific surface area determined by the BET method of from 500 to 1400 m 2 /g, and a monolayer adsorption of water at 25° C. of 1.7 H 2 O molecules/nm 2 specific surface area or more; (2) a process for synthesizing the mesoporous silica characterized by mixing and reacting active silica with a neutral template and removing the neutral template from the thus formed complex; (3) ink absorbents characterized by containing mesoporous silica; (4) ink absorbent slurries composed of the above-described ink absorbent and a solvent; and (5) recording sheets characterized by containing the above-described ink absorbent.

Claims (57)

1. Mesoporous silica characterized by having an average pore diameter in the mesopore region of from 1.5 to 10 nm, a nitrogen adsorption specific surface area determined by the BET method of from 500 to 1400 m 2 /g and a monolayer adsorption of water at 25° C. of 1.7 H 2 O molecules/nm 2 specific surface area or more.

2. A process for synthesizing mesoporous silica comprising the steps of:

mixing and reacting active silica with a neutral template to synthesize an active silica/neutral template complex; and

bringing the active silica/neutral template complex into contact with a solvent to remove the neutral template from said complex;

wherein said mesoporous silica is characterized by having a monolayer adsorption of water at 25° C. of 1.7 H 2 O molecules/nm 2 specific surface area or more.

3. The process for synthesizing mesoporous silica as claimed in claim 2 , wherein said neutral template is an amine represented by the following structural formula (1):

RNH 2   (1)

wherein R represents an alkyl group having 8 to 20 carbon atoms.

4. The process for synthesizing mesoporous silica as claimed in claim 2 , wherein said neutral template is a nonionic surfactant represented by the following structural formula (2):

R(OCH 2 CH 2 ) n OH  (2)

wherein R represents an alkyl group having 12 to 20 carbon atoms; and n is from 2 to 30.

5. The process for synthesizing mesoporous silica as claimed in claim 2 , wherein said neutral template is an amine oxide represented by the following structural formula (3):

R(CH 3 ) 2 NO  (3)

wherein R represents an alkyl group having 8 to 20 carbon atoms.

6. The process as claimed in claim 2 , wherein said solvent to be used in removing the neutral template is an alcohol.

7. An ink absorbent comprising a mesoporous silica synthesized by using a template, wherein said mesoporous silica is the mesoporous silica as claimed in claim 1 .

8. An ink absorbent slurry composed of the ink absorbent as claimed in claim 7 and a solvent.

9. A recording sheet characterized by containing the ink absorbent as claimed in claim 7 .

10. An ink absorbent comprising the mesoporous silica as claimed in claim 1 .

11. An ink absorbent comprising the mesoporous silica of claim 1 , which is synthesized by a process comprising mixing and reacting a silica source with a template to synthesize a silica/template complex.

12. The ink absorbent as claimed in claim 11 , wherein said template is a neutral template and said silica/template complex is a silica/neutral template complex.

13. The ink absorbent as claimed in claim 12 , wherein said process further comprising removing said neutral template from said silica/neutral template complex.

14. The ink absorbent as claimed in claim 11 , wherein said silica is an active silica.

15. The ink absorbent as claimed in claim 12 , wherein said neutral template is an amine represented by the following structural formula (1):

RNH 2   (1)

wherein R represents an alkyl group having 8 to 20 carbon atoms.

16. The ink absorbent as claimed in claim 12 , wherein said neutral template is a nonionic surfactant represented by the following structural formula (2):

R(OCH 2 CH 2 ) n OH  (2)

wherein R represents an alkyl group having 12 to 20 carbon atoms; and n is from 2 to 30.

17. The ink absorbent as claimed in claim 12 , wherein said neutral template is an amine oxide represented by the following structural formula (3):

R(CH 3 )NO  (3)

wherein R represents an alkyl group having 8 to 20 carbon atoms.

18. The ink absorbent as claimed in claim 13 , wherein said neutral template-removing step is carried out by bringing said silica/neutral template complex into contact with a solvent.

19. The ink absorbent as claimed in claim 18 , wherein said solvent comprises an alcohol.

20. An ink absorbent slurry comprising the ink absorbent as claimed in claim 10 and a solvent.

21. An ink absorbent slurry comprising the ink absorbent as claimed in claim 11 and a solvent.

22. A recording sheet containing the ink absorbent as claimed in claim 10 .

23. A recording sheet containing the ink absorbent as claimed in claim 11 .

24. An ink absorbent slurry comprising the ink absorbent as claimed in claim 14 and a solvent.

25. A recording sheet containing the ink absorbent as claimed in claim 14 .

26. An ink absorbent comprising mesoporous silica synthesized by the process of claim 2 .

27. An ink absorbent slurry comprising the ink absorbent of claim 26 and a solvent.

28. A recording sheet comprising the ink absorbent of claim 26 .

29. An ink absorbent slurry comprising the ink absorbent of claim 12 and a solvent.

30. A recording sheet containing the ink absorbent of claim 12 .

31. An ink absorbent slurry comprising the ink absorbent of claim 13 and a solvent.

32. A recording sheet containing the ink absorbent of claim 13 .

33. An ink absorbent slurry comprising the ink absorbent of claim 15 and a solvent.

34. A recording sheet containing the ink absorbent of claim 15 .

35. An ink absorbent slurry comprising the ink absorbent of claim 16 a solvent.

36. A recording sheet containing the ink absorbent of claim 16 .

37. An ink absorbent slurry comprising the ink absorbent of claim 17 and a solvent.

38. A recording sheet containing the ink absorbent of claim 17 .

39. An ink absorbent slurry comprising the ink absorbent of claim 18 and a solvent.

40. A recording sheet containing the ink absorbent of claim 18 .

41. An ink absorbent slurry comprising the ink absorbent of claim 19 and a solvent.

42. A recording sheet containing the ink absorbent of claim 19 .

Assignments (3)
CHANGE OF NAME Recorded Nov 18, 2004
From: ASAHI KASEI KOGYO KABUSHIKI KAISHA
To: ASAHI KASEI KABUSHIKI KAISHA
Reel/Frame 016664/0556 →
CHANGE OF NAME Recorded Feb 7, 2001
From: ASAHI KASEI KOGYO KABUSHIKI KAISHA (OLD NAME)
To: ASAHI KASEI KABUSHIKI KAISHA
Reel/Frame 011537/0189 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 22, 2000
From: SATOU, SEIJI; SHIMIZU, TADASHI
To: ASAHI KASEI KOGYO KABUSHIKI KAISHA
Reel/Frame 010877/0624 →
Priority Claims (1)
JP 9-320801 · Nov 21, 1997 · national
Continuity (1)
Related Publication 20030031615A1 · Feb 13, 2003