Light adjustable lenses capable of post-fabrication power modification via multi-photon processes
The invention relates to novel photoinitiators and their use in light adjustable compositions. The initiatives comprise two or more multiphoton chromophores linked by a bridging compound. The bridging compound consists of a material that is compatible with the base material of the light adjustable composition. The novel photoinitiator permit the readjustment of light adjustable material without the need for significant amounts of photoabsorbers.
1. A photoinitiator having the formula:
A-B-A 1
wherein A and A 1 are independently selected from multiphoton chromophores having the formula
D-π-D
wherein D is a tertiary amino electron donor and π is a conjugated bridge and B is a bridging compound comprising an acrylic or siloxane moiety.
2. The photoinitiator of claim 1 wherein B comprises a siloxane moiety having the formula:
wherein m and n are integers from 1 to 10 and R 1 , R 2 , R 3 and
R 4 are independently selected from the group consisting of hydrogen, alkyl, halogenated alkyl, phenyl and aryl.
3. The photoinitiator of claim 1 wherein B comprises an acrylic moiety having the formula:
wherein n is an integer ranging from 1 to 10 and R 1 , R 2 ,
R 3 and R 4 are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, phenyl and aryl.
4. A photoinitiator having the formula:
wherein m is an integer from 1 to 10 and R 1 , R 2 , R 3 and
R 4 independently selected from the group consisting of hydrogen, alkyl, halogenated alkyl, phenyl and aryl.
5. A light adjustable composition comprising:
a base material;
photopolymerizable macromers;
a photoinitiator, said photoinitiator having the formula:
A-B-A 1
wherein A and A 1 are independently selected from multiphoton chromophores and B is a bridging compound comprising an acrylic or siloxane moiety.
6. The composition of claim 5 wherein the bridging compound is a acrylic moiety having the general formula:
wherein n is an integer from 1 to 10 and R 1 , R 2 , R 3 and
R 4 are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, phenyl and aryl.
7. The composition of claim 5 wherein the bridging compound comprises an siloxane moiety having the formula:
wherein m and n are integers and R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, phenyl and aryl.
8. The composition of claim 5 wherein the base material comprises polysiloxane.
9. The composition of claim 5 wherein the base material comprises poly(acrylate).
10. The composition of claim 5 wherein the photoinitiator has the formula:
wherein m is an integer from 1 to 10, and R 1 , R 2 , R 3 and
R 4 independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, phenyl and aryl.
11. The composition of claim 5 wherein the chromophores have the formula:
Dπ-D
wherein D is a teritary amino electron donor and π is a conjugated bridge.