Process and catalyst for treatment of synthesis gas
A process for the treatment of synthesis gas to increase content of hydrogen and/or carbon monoxide in the gas comprising the step of contacting the synthesis gas with a catalyst comprising oxides of manganese and zirconium, which metals are present in a molar ratio Mn/Zr of between 0.05 to 5.00.
1. A process for the treatment of synthesis gas to increase content of hydrogen and/or carbon monoxide in the synthesis gas comprising the step of contacting the synthesis gas with a catalyst comprising oxides of manganese and zirconium, which metals are present in the catalyst in a molar ratio Mn/Zr of between 0.05 to 5.00 and wherein the oxides of manganese and zirconium constitute at least 50% by weight of the catalyst in its reduced form.
2. The process of claim 1 , wherein the catalyst further comprises a metallic component selected from the group consisting of copper, silver, gold, palladium, platinum, oxides of transition metals from Group 3 to 8 of the Periodic Table, and the lanthanides.
3. The process of claim 2 , wherein the metallic component is copper.
4. The process of claim 2 , wherein the oxides of transition metals are selected from the group consisting of oxides of yttrium, titanium, vanadium, niobium, chromium, iron, cerium, lanthanides and mixtures thereof.
5. The process of claim 1 , wherein the catalyst is in the form of a thin layer supported on a geometrical body placed in at least part of a passageway through which the synthesis gas is transported.
6. The process of claim 1 , wherein the catalyst is in the form of a thin layer supported on at least part of an inner wall of a passageway through which the synthesis gas is transported.
7. The of claim 1 , wherein the catalyst is in the form of one of pellets, extrudates, tablets, monoliths and geometrical bodies.
8. The process of claim 1 , wherein the synthesis gas is an effluent stream of a reaction selected from the group consisting of catalytic steam reforming of hydrocarbons, autothermal steam reforming of hydrocarbons, secondary steam reforming of hydrocarbons, gasification of hydrocarbons, gasification of coal, and fuel-processing for the production of energy.