IP Library Granted Patent US 7,544,639
Granted Patent B2
US 7,544,639 · App. 11/122,681 · Granted Jun 9, 2009

Composition and process for the treatment of hydrogen sulfide

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Quick Facts
Patent No.
US 7,544,639
App. No.
11/122,681
Granted
Jun 9, 2009
Kind
B2
Abstract

Disclosed is a method for the treatment of hydrogen sulfide. The method preferably includes forming a solvent-surfactant blend, preparing a microemulsion by combining the solvent-surfactant blend with a carrier fluid and contacting the hydrogen sulfide with the microemulsion. In preferred embodiments, the solvent-surfactant blend includes a surfactant and a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols.

Claims (18)

1. A method for the treatment of hydrogen sulfide; comprising:

forming a solvent-surfactant blend;

preparing a microemulsion by combining the solvent-surfactant blend with a carrier fluid, wherein the microemulsion does not contain a hydrogen sulfide scavenger; and

treating the hydrogen sulfide by injecting the microemulsion into a wellbore and contacting the hydrogen sulfide with the microemulsion.

2. The method of claim 1 , wherein the step of forming the solvent-surfactant blend comprises:

combining a solvent with a surfactant, wherein the solvent is selected from the group consisting of terpenes.

3. The method of claim 2 , wherein the step of forming the solvent-surfactant blend comprises:

combining a solvent with a surfactant, wherein the solvent is d-limonene.

4. The method of claim 1 , wherein the step of treating the hydrogen sulfide with the microemulsion into a wellbore and contacting the hydrogen sulfide with the microemulsion comprises:

placing the microemulsion in a container in fluid communication with a source of hydrogen sulfide.

5. The method of claim 1 , wherein the carrier fluid is water-based and the step of forming the solvent-surfactant blend comprises:

combining a solvent and a surfactant, wherein the surfactant has a hydrophile-lipophile balance value of between 8-18.

6. The method of claim 1 , wherein the carrier fluid is water-based and the step of forming the solvent-surfactant blend comprises:

combining a solvent and a surfactant, wherein the surfactant is an oil-in-water surfactant mix mixture that includes polyoxyethylene sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol.

7. The method of claim 1 , wherein the carrier fluid is oil-based and the step of forming the solvent-surfactant blend comprises:

combining a solvent and a surfactant, wherein the surfactant has a hydrophile-lipophile balance value of between 3-8.

8. The method of claim 1 , wherein the carrier fluid is oil-based and the step of forming the solvent-surfactant blend comprises:

combining a solvent and a surfactant, wherein the surfactant is an oil-based surfactant mixture that includes sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol.

Assignments (13)
RELEASE OF SECURITY INTEREST Recorded Apr 17, 2019
From: PNC BANK NATIONAL ASSOCIATION
To: CESI CHEMICAL, A FLOTEK COMPANY
Reel/Frame 048914/0120 →
CONVERSION Recorded Mar 21, 2016
From: CESI CHEMICAL, INC.
To: FLOTEK CHEMISTRY, LLC
Reel/Frame 038183/0840 →
CHANGE OF NAME Recorded Mar 9, 2015
From: CHEMICAL & EQUIPMENT SPECIALTIES, INC.
To: CESI CHEMICAL, INC.
Reel/Frame 035146/0629 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ORIGINAL ASSIGNMENT PREVIOUSLY RECORDED ON REEL 016531 FRAME 0101. ASSIGNOR(S) HEREBY CONFIRMS THE UPDATE TO ASSIGNEE NAME FROM CESI CHEMICAL, A FLOTEK COMPANY TO CHEMICAL & EQUIPMENT SPECIALTIES, INC. Recorded Aug 8, 2014
From: PURSLEY, JOHN T; HOLCOMB, DAVID L; PENNY, GLENN S
To: CHEMICAL & EQUIPMENT SPECIALTIES, INC.
Reel/Frame 033500/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 7, 2013
From: FLOTEK INDUSTRIES, INC.; CESI CHEMICAL, INC.; CESI MANUFACTURING, LLC; MATERIAL TRANSLOGISTICS, INC.; TELEDRIFT COMPANY; TURBECO, INC.; USA PETROVALVE, INC.; FLOTEK ACQUISITION INC.; FLORIDA CHEMICAL COMPANY, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 030569/0758 →
RELEASE OF SECURITY INTEREST Recorded May 9, 2013
From: U.S. BANK, NATIONAL ASSOCIATION
To: FLOTEK INDUSTRIES, INC.
Reel/Frame 030386/0077 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jan 6, 2012
From: FLOTEK INDUSTRIES, INC.; CESI CHEMICAL, INC.; CESI MANUFACTURING, LLC; MATERIAL TRANSLOGISTICS, INC.; SOONER ENERGY SERVICES, LLC; TELEDRIFT COMPANY; TURBECO, INC.; USA PETROVALVE, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 027491/0420 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jan 4, 2012
From: WHITEBOX ADVISORS LLC
To: FLOTEK INDUSTRIES, INC.
Reel/Frame 027480/0209 →
SECURITY AGREEMENT Recorded Apr 7, 2010
From: FLOTEK INDUSTRIES, INC.; TELEDRIFT COMPANY; FLOTEK PAYMASTER INC.; MATERIAL TRANSLOGISTICS, INC.; PETROVALVE, INC.; TURBECO, INC.; USA PETROVALVE, INC.; FLOTEK INTERNATIONAL, INC.; PADKO INTERNATIONAL INCORPORATED; FLOTEK ECUADOR MANAGEMENT, LLC; FLOTEK ECUADOR INVESTMENTS, LLC; CESI CHEMICAL, INC.; CESI MANUFACTURING, LLC; SOONER ENERGY SERVICES, LLC; FLOTEK INDUSTRIES FZE
To: WHITEBOX ADVISORS LLC; WHITEBOX HEDGED HIGH YIELD PARTNERS, LP; IAM MINI-FUND 14 LIMITED; PANDORA SELECT PARTNERS, LP; WHITEBOX SPECIAL OPPORTUNITIES FUND, LP - SERIES B; WHITEBOX COMBINED PARTNERS, LP; WHITEBOX CONVERTIBLE ARBITRAGE PARTNERS, LP; ECF VALUE FUND, L.P.; ECF VALUE FUND II, L.P.; ECF VALUE FUND INTERNATIONAL LTD.
Reel/Frame 024195/0637 →
SECURITY AGREEMENT Recorded Apr 7, 2010
From: FLOTEK INDUSTRIES, INC.; TELEDRIFT COMPANY; FLOTEK PAYMASTER INC.; MATERIAL TRANSLOGISTICS, INC.; PETROVALVE, INC.; TURBECO, INC.; USA PETROVALVE, INC.; FLOTEK INTERNATIONAL, INC.; PADKO INTERNATIONAL INCORPORATED; FLOTEK ECUADOR MANAGEMENT, LLC; FLOTEK ECUADOR INVESTMENTS, LLC; CESI CHEMICAL, INC.; CESI MANUFACTURING, LLC; SOONER ENERGY SERVICES, LLC; FLOTEK INDUSTRIES FZE
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 024195/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2010
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: WHITEBOX ADVISORS LLC
Reel/Frame 024151/0624 →
SECURITY AGREEMENT Recorded May 2, 2008
From: FLOTEK INDUSTRIES, INC.; TELEDRIFT COMPANY; FLOTEK PAYMASTER, INC.; MATERIAL TRANSLOGISTICS, INC.; PETROVALVE, INC.; TURBECO, INC.; USA PETROVALVE, INC.; SOONER ENERGY SERVICES, INC.; CAVO DRILLING MOTORS, LTD. CO.; SES HOLDINGS, INC.; CESI CHEMICAL, INC.; PADKO INTERNATIONAL, INC.
To: WELLS FARGO BANK, N.A.
Reel/Frame 020886/0649 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2005
From: PURSLEY, JOHN T.; HOLCOMB, DAVID L.; PENNY, GLENN S.
To: CESI CHEMICAL, A FLOTEK COMPANY
Reel/Frame 016531/0101 →