Acrylic pressure sensitive adhesive compositions
The present invention relates to acrylic adhesive compositions, and more precisely, acrylic adhesive compositions having improved anti-static capacity without damaging durability, transparency and peel strength which are composed of an acrylic copolymer, a hydrophilic complex compound and a hydrophobic complex compound to sufficiently inhibit the development of static electricity, regardless of the surface condition (hydrophobicity or hydrophilicity) of a polarizing plate.
1. An acrylic adhesive composition, which comprises:
a) 100 weight part of an acrylic copolymer;
b) 0.01˜10 weight part of a hydrophilic complex compound; and
c) 0.01˜10 weight part of a hydrophobic complex compound,
wherein the hydrophilic complex compound of (b) is composed of a compound having an alkylene oxide group in its molecular structure and an ionic compound having a hydrophilic anion.
2. The acrylic adhesive composition according to claim 1 , wherein the acrylic copolymer of a) is prepared by co-polymerization of i) 90˜99.9 weight % of (meth)acrylic acid ester monomer having a C 1 ˜C 12 alkyl group and ii) 0.1˜10 weight % of vinyl monomer and/or acrylic monomer having a cross-linkable functional group.
3. The acrylic adhesive composition according to claim 2 , wherein the (meth)acrylic acid ester monomer having a C 1 ˜C 12 alkyl group of i) is one or more compounds selected from a group consisting of butyl(meth)acrylate, ethyl(meth)acrylate, methyl(meth)acrylate, n-propyl(meth)acrylate, isopropyl(meth)acrylate, t-butyl(meth)acrylate, pentyl(meth)acrylate, n-octylmethacrylate, n-tetradecylmethacrylate, 2-ethylhexyl(meth)acrylate, isooctyl(meth)acrylate, isononyl(meth)acrylate and 2-ethylbutyl(meth)acrylate.
4. The acrylic adhesive composition according to claim 2 , wherein the (meth)acrylic acid ester monomer having a C 1 ˜C 12 alkyl group of i) is mixed with one or more co-monomers selected from a group consisting of methyl acrylate, methyl methacrylate, ethyl metherylate, vinyl acetate, styrene and acrylonitrile.
5. The acrylic adhesive composition according to claim 2 , wherein the vinyl monomer and/or acrylic monomer having a cross-linkable functional group of ii) is one or more compounds selected from a group consisting of 2-hydroxyethyl(meth)acrylate, 2-hydroxypropyl(meth)acryl ate, 4-hydroxybutyl(meth)acrylate, 6-hydroxyhexyl(meth)acrylate, 2-hydroxyethyleneglycol(meth)acrylate, 2-hydroxypropyleneglycol (meth)acrylate; (meth)acrylic acid, maleic acid, fumaric acid, acryl amide, N-vinyl pyrrolidone and N-vinyl caprolactam.
6. The acrylic adhesive composition according to claim 1 , wherein the compound having an alkylene oxide group has one or more repetitive units selected from a group consisting of methylene oxide, ethylene oxide, propylene oxide and butylene oxide.
7. The acrylic adhesive composition according to claim 1 , wherein the weight average molecular weight of the compound having an alkylene oxide group is 100˜10,000.
8. The acrylic adhesive composition according to claim 1 , wherein the ionic compound having a hydrophilic anion is one or more compounds selected from a group consisting of the compounds comprising anions of ClO 4 − , I − , Cl − , Br − , BF 4 − , PF 6 − , N 3 − , CH 3 CO 2 − , HPO 4 2− , SO 4 2− or NO 3 − ; and cations of lithium, sodium, potassium, magnesium, calcium, barium or cesium.
9. The acrylic adhesive composition according to claim 1 , wherein the compound having an alkylene oxide group and the compound having a hydrophilic anion are mixed at the molar ratio of 1/1˜1/100 ([M + ]/[RO]; whereby [M + ] indicates the molarity of the ionic compound and [RO] indicates the molarity of the repetitive unit of alkylene oxide group).
10. The acrylic adhesive composition according to claim 1 , wherein the hydrophobic complex compound of (c) is an inorganic or an organic ionic compound having a hydrophobic anion.
11. The acrylic adhesive composition according to claim 10 , wherein the hydrophobic complex compound is one or more compounds selected from a group consisting of inorganic ionic compounds comprising hydrophobic anions of CF 3 SO 3 − , N(CF 3 SO 2 ) 2 − , N(CF 3 CO) 2 − , N(C 2 F 5 SO 2 ) 2 − , N(C 2 F 5 CO) 2 − , N(C 4 F 9 SO 2 ) 2 − or C(CF 3 SO 2 ) 3 − ; and cations of lithium, sodium, potassium, magnesium, calcium, barium or cesium.
12. The acrylic adhesive composition according to claim 11 , wherein the inorganic ionic compound additionally includes a compound that is able to form a complex with one or more metal cations selected from a group consisting of oxalate, polyvalent acid group, diamine and acetyl ketone group.
13. The acrylic adhesive composition according to claim 10 , wherein the hydrophobic complex compound is one or more compounds selected from a group consisting of organic ionic compounds comprising hydrophobic anions of CF 3 SO 3 − , N(CF 3 SO 2 ) 2 − , N(CF 3 CO) 2 − , N(C 2 F 5 SO 2 ) 2 − , N(C 2 F 5 CO) 2 − , N(C 4 F 9 SO 2 ) 2 − or C(CF 3 SO 2 ) 3 − ; and cations of pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, triazolium or quaternary ammonium.
14. The acrylic adhesive composition according to claim 1 , wherein the composition additionally includes a cross-linking agent.
15. The acrylic adhesive composition according to claim 14 , wherein the cross-linking agent is one or more compounds selected from a group consisting of isocyanate compounds, epoxy compounds, aziridine compounds and metal chelate compounds.
16. The acrylic adhesive composition according to claim 14 , wherein the content of the cross-linking agent based on 100 weight part of the acrylic copolymer is 0.01˜10 weight part.
17. The acrylic adhesive composition according to claim 14 , wherein the composition additionally includes one or more additives selected from a group consisting of tackifier resin, acrylic low-molecular substance, epoxy resin, hardener, UV stabilizer, antioxidant, toning agent, reinforcing agent, filler, antifoaming agent, surfactant, plasticizer, blowing agent and organic salt.
18. The acrylic adhesive composition according to claim 1 , wherein the composition is applied to an industrial sheet, a protective film, a cleaning sheet, a reflective sheet, or provided as part of a structural adhesive sheet, a photographic adhesive sheet, an adhesive sheet for a traffic lane, an optical adhesive product, an adhesive for an electronic device, a multiple structured laminate product, a commercial adhesive sheet product, a medical patch or heat activated pressure sensitive adhesive.
19. A protective film in which an adhesive layer covering one side or both sides of a substrate contains the acrylic adhesive composition according to claim 1 ,
20. A liquid crystal display device which contains a liquid crystal panel, wherein a polarizing plate coated with the protective film of claim 19 is layered on one side or both sides of a liquid crystal cell.