Impact-modified thermoplastic molding compositions based on vinyl aromatic copolymers and polyamide
The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.
1. A thermoplastic molding composition, comprising
A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of
A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride all), from at least one vinylaromatic comonomer a12), and if appropriate from other comonomers a13), and
A2) from 5 to 95% by weight of an aliphatic polyamide A2),
B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A),
C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C),
D) from 0 to 60% by weight of at least one copolymer D) composed of vinylaromatic monomers dl) and of comonomers d2), and
E) from 0 to 40% by weight of at least one other additive E),
where the entirety of components A) to E) gives 100% by weight, and
wherein the rubber B) is based on ethylene and octane and has functional groups which can react with the end groups of the graft copolymer A).
2. The molding composition according to claim 1 , wherein the dicarboxylic anhydride a11) has been selected from maleic anhydride, methylmaleic anhydride, and itaconic anhydride.
3. The molding composition according to claim 1 wherein the vinylaromatic comonomer a12) has been selected from styrene, α-methylstyrene, p-methyl-styrene, and vinylnaphthalene.
4. The molding composition according to claim 1 wherein the other comonomers a13) are acrylonitrile, methacrylonitrile, methyl methacrylate, N-phenylmaleimide, or N-alkylmaleimides.
5. The molding composition according to claim 1 wherein the polymer A1) comprises from 0.5 to 10% by weight of the dicarboxylic anhydrides a11), from 42 to 85.5% by weight of the vinylaromatic comonomers a12), and from 14 to 38% by weight of the other comonomers a13)
where the entirety of the components a11), a12) and a13) gives a total of 100% by weight.
6. The molding composition according to claim 1 wherein the polymer A1) is obtainable from the following monomers
styrene and maleic anhydride,
styrene, α-methylstyrene and maleic anhydride,
styrene, acrylonitrile, and maleic anhydride, or
styrene, N-phenylmaleimide, and maleic anhydride.
7. The molding composition according to claim 1 wherein the aliphatic polyamide A2) has been selected from the group consisting of nylon-6, nylon-6,6, and the copolyamide nylon 6/6,6.
8. The molding composition according to claim 1 wherein the amounts used of A1) and A2) are such that the molar ratio of anhydride groups in polymer A1to the amino end groups in polymer A2 is from 3:1 to 0.7:1.
9. The molding composition according to claim 1 wherein the amounts used of A1) and A2) are such that the molar ratio of anhydride groups in polymer A1to the amino end groups in polymer A2 is from 2:1 to 0.85:1.
10. The molding composition according to claim 1 wherein the rubber B) has been selected from the group consisting of ethylene copolymers, ethylene-propylene copolymers, ethylene-propylene-diene copolymers, styrene-butadiene block copolymers, and ethylene-octene copolymers, and has functional groups which can react with the end groups of component A).
11. The molding composition according to claim 1 wherein the rubber B) is composed of ethylene-propylene copolymers and has functional groups which can react with the end groups of component A).
12. A process for preparation of the thermoplastic molding compositions according to claim 1 which comprises, in a first step, reacting the polymer A1) with the polyamide A2) via mixing of melts or reaction in solution to give the graft copolymer A), and, in a second step, mixing this component A) with components B) and, if appropriate, C) to E) in a mixing apparatus.
13. A process for preparation of the thermoplastic molding compositions according to claim 1 which comprises, in one step, reacting the polymer A1) and the polyamide A2) with components B) and, if appropriate, C) to E) via mixing of melts in a mixing apparatus.
14. The process for preparation of the thermoplastic molding compositions according to claim 1 wherein at least 35 mol % of the polyamide A2) used react with the polymer A1) to give the graft copolymer A).
15. The process for preparation of the thermoplastic molding compositions according to claim 1 wherein at least 45 mol % of the polyamide A2) used react with the polymer A1) to give the graft copolymer A).
16. A molding, a foil, a fiber, or a foam obtainable from the thermoplastic molding compositions according to claim 1 .