Spark plug with multi-layer firing tip
View Patent ↗A spark plug having a multilayer firing tip that minimizes the amount of precious metal used and a method of assembling a spark plug with a multilayer firing tip. The firing tip includes a discharge end and a weld end, with the weld end being connected to a center electrode, and more specifically to a base electrode on the center electrode. The weld end has a coefficient of thermal expansion, which is not between the values for the coefficients of thermal expansion for the discharge end and the base electrode. More specifically, the weld end has a coefficient of thermal expansion which is greater than the coefficients of thermal expansion for the discharge end and base electrode. The weld end is formed from Nickel and Chromium with a limited amount of additional elements. The spark plug is assembled by providing a first elongated material formed from the material used for the discharge end and a second elongated material formed from a material used for the weld end. The two materials are then joined to form a single joined material and are severed to create a firing tip. The firing tip is welded to the center electrode of the spark plug and more specifically, the base electrode.
1. A spark plug comprising:
a center electrode assembly including a base electrode and a multi-layered firing tip, said firing tip including a weld end and a discharge end, said base electrode being formed of a material that includes nickel, said weld end being formed from a first material including nickel and at least one element selected from the group consisting of chromium, vanadium, zirconium, tungsten, osmium, gold, iron, cobalt, and aluminum, and said discharge end being formed from a second material that is different in composition from that of said first material, said second material including at least one element selected from the group consisting of iridium, platinum, palladium, rhodium, ruthenium, and rhenium.
2. The spark plug of claim 1 wherein said weld end includes less than 3% of any element selected from the group consisting of ruthenium, rhenium, and rhodium.
3. The spark plug of claim 1 wherein said weld end consists of nickel, chromium, less than approximately 2.0% of any element selected from the group consisting of iron, platinum, iridium, platinum, ruthenium, rhenium, manganese, magnesium, aluminum, silicon, zirconium, tungsten, vanadium, osmium, copper, and gold, less than 2.7% of rhodium, and less than approximately 10% cobalt.
4. The spark plug of claim 3 wherein said weld end includes less than 45% chromium.
5. The spark plug of claim 4 wherein said weld end includes approximately less than 1.0% iron, approximately less than 0.08% manganese, approximately less than 1.5% silicon, approximately less than 0.2% aluminum and approximately less than 0.04% rhenium.
6. The spark plug of claim 4 wherein said weld end includes 19-21% chromium.
7. The spark plug of claim 1 wherein said weld end includes 15-45% chromium by weight.
8. The spark plug of claim 1 wherein said weld end includes less than 30% of any element selected from the group consisting of platinum and iridium.
9. The spark plug of claim 8 wherein said weld end includes less than 20% of any element selected from the group consisting of platinum and iridium.
10. The spark plug of claim 8 wherein said weld end includes less than 10% of any element selected from the group consisting of platinum and iridium.
11. The spark plug of claim 1 wherein said weld end is formed predominantly of nickel and chromium with at least one other element selected from the group consisting of copper, vanadium, zirconium, tungsten, osmium, gold, iron, cobalt and aluminum.
12. The spark plug of claim 1 , wherein said weld end is joined to said base electrode by a first weld joint and said discharge end is joined to said weld end by a second weld joint that is spaced from said first weld joint.
13. The spark plug of claim 1 , wherein the material compositions of the base electrode the weld end and the discharge end are all different from one another.
14. A spark plug comprising a center electrode assembly including a base electrode and a multi-layered firing tip including a weld end and a discharge end and wherein said base electrode includes nickel, said discharge end being formed of a first material that includes at least one element selected from the group consisting of iridium, platinum, palladium, rhodium, ruthenium, and rhenium and wherein said weld end is formed of a second material that includes a positive amount less than 45% by weight chromium and a positive amount less than approximately 2.0% by weight of any element selected from the group consisting of iron, platinum, iridium, ruthenium, rhenium, manganese, magnesium, aluminum, silicon, zirconium, tungsten, vanadium, osmium, copper, and gold, and a positive amount less than 2.7% by weight of rhodium, and a positive amount less than approximately 10% by weight cobalt.
15. A spark plug comprising:
a center electrode assembly including a base electrode and a multi-layer firing tip including a weld end forming one layer and a discharge end forming another layer, said weld end being located between and in contact with said base electrode and said discharge end, said weld end being formed from a first material including nickel, chromium and wherein said weld end includes less than 3% of any element selected from the group consisting of ruthenium, rhenium, and rhodium and said discharge end is formed from a second material that is different in composition from that of said first material.
16. The spark plug of claim 15 wherein said weld end includes less than 90% of any element, or combination thereof, selected from the group consisting of platinum and iridium.
17. The spark plug of claim 16 wherein said weld end includes less than 10% of any element selected from the group consisting of platinum and iridium.
18. The spark plug of claim 17 wherein said weld end includes less than 5% of any element elected from the group consisting of platinum and iridium.
19. The spark plug of claim 15 wherein said weld end includes less than 2.5% rhodium and less than 2% of any element selected from the group consisting of rhenium, ruthenium, palladium, tungsten, zirconium, vanadium, osmium.
20. The spark plug of claim 15 wherein said weld end includes less than 2% of any element selected from the group consisting of copper, iron, cobalt and aluminum.
21. The spark plug of claim 20 wherein said weld end includes less than 1.5% of any element selected from the group consisting of copper, iron, and aluminum.
22. The spark plug of claim 15 wherein said weld end includes less than 1 .0% iron, less than 0.08% manganese, less than 1.5% silicon, less than 0.2% aluminum, less than 0.040% rhenium.
23. The spark plug of claim 15 wherein said weld end includes 5-45% chromium and at least 20% nickel.
24. The spark plug of claim 15 wherein said weld end includes 15-40% chromium.
25. The spark plug of claim 24 wherein said weld end includes 15-30% chromium, greater than 50% nickel, less than 10% iridium and platinum, less than 2% of any clement selected from the group consisting of silicon and iron, and less than 1% of any element selected from the group consisting of manganese, aluminum, rhenium, rhodium, and ruthenium.
26. The spark plug of claim 15 wherein said discharge end includes at least 90% of iridium, platinum or a combination of iridium and platinum.
27. The spark plug of claim 26 wherein said discharge end further includes rhodium, tungsten, and zirconium.
28. The spark plug of claim 15 wherein said weld end is substantially free of iridium and platinum.
29. The spark plug of claim 15 wherein said weld end includes less than 10% platinum and iridium and 15-25% chromium by weight.
30. A spark plug having a center electrode assembly, said spark plug comprising:
a multi-layer firing tip formed having a discharge portion secured to a weld portion, said weld portion being attached to the center electrode assembly and located between said discharge portion and the center electrode assembly, and wherein said discharge portion is formed from a material including at least one element selected from the group consisting of iridium, platinum, rhodium, ruthenium, rhenium, tungsten, and zirconium and wherein said weld portion is formed from a material different in composition from that of said discharge portion and including nickel and less than 10% of any element selected from the group consisting of iridium, platinum, rhodium, ruthenium, rhenium, tungsten, and zirconium.
31. The spark plug of claim 30 wherein said weld portion includes 15%-45% chromium.
32. The spark plug of claim 30 wherein said weld portion includes less than 2% of any element selected from the group consisting of iron, ruthenium, rhenium, manganese, magnesium, aluminum, silicon, zirconium, tungsten, vanadium, osmium, gold, copper and cobalt.
33. The spark plug of claim 30 wherein said weld portion includes less than 0.5% copper.
34. The spark plug of claim 1 wherein said discharge end is formed predominantly from one of platinum or iridium and further includes greater than 0% but less than 5% of elements rhodium, tungsten, and zirconium.