Liquid crystal composition and liquid crystal display device
View Patent ↗A liquid crystal composition having a nematic phase that includes two components, wherein the first component is at least one compound selected from the group of compounds represented by formula (1), and the second component is at least one compound selected from the group of compounds represented by formula (2): wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A and ring B are each independently 1,4-cyclohexylene, 1,3-dioxan-2,5-diyl, 1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 1 is a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; and p is 0, 1 or 2.
1. A liquid crystal composition having a nematic phase comprising two components, wherein the first component is at least one compound selected from the group of compounds represented by formula (1), and the second component is at least one compound selected from the group of compounds represented by formula (2):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons ring A and ring B are each independently 1,4-cyclohexylene, 1,3-dioxan-2,5-diyl, 1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 1 is a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; and p is 0, 1 or 2.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1) to (1-3):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; and X 1 , X 2 , X 3 , X 4 , X 5 and X 6 are each independently hydrogen or fluorine.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-3).
4. The liquid crystal composition according to claim 1 , wherein a ratio of the first component is from approximately 5% by weight to approximately 40% by weight, and a ratio of the second component is from approximately 5% by weight to approximately 30% by weight, based on the total weight of the liquid crystal composition.
5. The liquid crystal composition according to claim 1 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; ring C and ring D are each independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 2 and Z 3 are each independently a single bond, ethylene or carbonyloxy; and m is 0 or 1.
6. The liquid crystal composition according to claim 5 , wherein the third component is at least one compound selected from the group of compounds represented by formulas (3-1) to (3-5):
wherein R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons.
7. The liquid crystal composition according to claim 6 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1).
8. The liquid crystal composition according to claim 6 , wherein the third component is a mixture of at least one compound selected from the group of compounds represented by formula (3-1) and at least one compound selected from the group of compounds represented by formula (3-4).
9. The liquid crystal composition according to claim 6 , wherein a ratio of the third component is from approximately 35% by weight to approximately 80% by weight based on the total weight of the liquid crystal composition.
10. The liquid crystal composition according to claim 1 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; ring E is 1,4-cyclohexylene, 1,3-dioxan-2,5-diyl, 1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 1 is a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and n is 1, 2 or 3.
11. The liquid crystal composition according to claim 10 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1) to (4-17):
wherein R 4 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons.
12. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-9).
13. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-10).
14. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-11).
15. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-17).
16. The liquid crystal composition according to claim 11 , wherein the fourth component is a mixture of at least one compound selected from the group of compounds represented by formula (4-9) and at least one compound selected from the group of compounds represented by formula (4-11).
17. The liquid crystal composition according to claim 11 , wherein the fourth component is a mixture of at least one compound selected from the group of compounds represented by formula (4-11) and at least one compound selected from the group of compounds represented by formula (4-17).
18. The liquid crystal composition according to claim 10 , wherein a ratio of the fourth component is from approximately 5% by weight to approximately 35% by weight based on the total weight of the liquid crystal composition.
19. The liquid crystal composition according to claim 1 , wherein the composition has a maximum temperature of a nematic phase of approximately 70° C. or more, an optical anisotropy (25° C.) at a wavelength of 589 nm of approximately 0.08 or more, and a dielectric anisotropy (25° C.) at a frequency of 1 kHz of approximately 2 or more.
20. A liquid display device that includes the liquid crystal composition according to claim 1 .
21. The liquid crystal display device according to claim 20 , wherein the liquid crystal display device has an operation mode of a TN mode, an OCB mode or an IPS mode, and has a driving mode of an active matrix mode.
22. The liquid crystal display device according to claim 20 , wherein the liquid crystal display device has an operation mode of a PSA mode, and has a driving mode of an active matrix mode.