Method for producing cellulose acylate film
View Patent ↗According to the present invention, a cellulose acylate film difficult to be broken even if the stretching ratio is increased upon stretching and whose retardation (Re) is easily controllable to a desired value can be produced by melt film forming. Accordingly, a stretched cellulose acylate film highly oriented and having an appropriate retardation (Re) required from liquid crystal display device manufacturers can be produced.
1. A method for producing a cellulose acylate film by melt film formation, including discharging a molten cellulose acylate resin melted in an extruder on a running or rotating cooling support through a die in a form of a sheet, thereby solidifying the discharged molten resin by cooling, the method comprising:
measuring an in-plane a retardation (Re) of a slow axis which is a lengthwise direction of the cellulose acylate film and a retardation (Rth) of the cellulose acylate film in thickness direction; and
controlling the temperature of the molten resin at an outlet of the die to a range of glass transition temperature Tg+70° C. to Tg+150° C. so that the measured retardations Re and Rth fall into the range of −10 nm to 80 nm and 0 to 60 nm, respectively; and
controlling a lip clearance ratio (D/W), which is a ratio of a lip clearance (D) of the die to a thickness (W) of the molten resin extruded through the die, to a range of 1.5 to 10,
wherein the extruder employs conditions of a screw compression ratio of 2.5 to 4.5, an L/D (the ratio of cylinder length (L) to cylinder bore diameter (D) of the extruder) of 20 to 70, and a temperature of the molten resin at an outlet of the extruder of 190° C. to 245° C.
2. The method for producing a cellulose acylate film according to claim 1 , wherein a distance for the molten resin discharged through the outlet of the die to land on the cooling support ranges from 5 mm to 200 mm.
3. A method for producing a stretched cellulose acylate film, comprising stretching a cellulose acylate film produced according to claim 1 in at least a lengthwise direction and a transverse direction of the film by 1% to 300%.
4. A method for producing a stretched cellulose acylate film, comprising stretching a cellulose acylate film produced according to claim 2 in at least a lengthwise direction and a transverse direction of the film by 1% to 300%.
5. The method for producing a cellulose acylate film according to claim 1 , wherein the cellulose acylate film has an elongation at break of 50% or more when the film is uniaxially stretched at the glass transition temperature Tg+10° C.
6. The method for producing a cellulose acylate film according to claim 1 , wherein the cellulose acylate has an average polymerization degree of 100 to 300.