Method and apparatus for thin film solar cell manufacturing
View Patent ↗The present invention provides a method of making a Cu—In—Ga sputtering target by melting Cu, In and Ga, Cu and In or Cu and Ga to form a uniform melt with a pre-determined stoichiometry, which melt is sprayed to cause sprayed uniform melt particles to solidify into Cu—In—Ga particles with the pre-determined stoichiometry. The sputtering target is then made using the Cu—In—Ga particles. In a further aspect of the invention, there is provided a method of producing a thin film absorber layer for solar cell fabrication by sputter depositing a precursor film with a first composition
1. A method of producing a thin film absorber layer for solar cell fabrication comprising:
providing a single compositionally uniform Cu—In—Ga target, wherein the single compositionally uniform Cu—In—Ga target is formed solely of a plurality of different solid particles that were each separately formed, intermixed to be compositionally uniformly distributed, and then compressed together, wherein the plurality of different solid particles include at least a plurality of alloy particles, with each of said plurality of alloy particles including at least two of Cu, In and Ga therein, wherein said plurality of different solid particles have a pre-determined stoichiometry, and wherein no Group VIA material is within the compositionally uniform Cu—In—Ga target;
sputter depositing a precursor film with a first composition and comprising Cu, In and Ga using, as an only target, the single compositionally uniform Cu—In—Ga target, wherein the step of sputter depositing occurs in the absence of a Group VIA material, and wherein the step of sputter depositing further occurs with the single compositionally uniform Cu—In—Ga target being cooled below about 10° C. during the step of sputter depositing; and
after completion of the sputter depositing, reacting the precursor film with at least one Group VIA material thereby forming a Cu(In,Ga)(VIA) 2 compound on the solar cell to produce said absorber layer.
2. The method of claim 1 wherein the first composition has Cu/(In—Ga) molar ratio of less than or equal to 1.0.
3. The method of claim 1 wherein the single compositionally uniform Cu—In—Ga target is made solely from a plurality of Cu—In—Ga particles that were each separately formed, intermixed to be compositionally uniformly distributed with the plurality of different solid particles, and then compressed together to form the single compositionally uniform Cu—In—Ga target, such that the plurality of different solid particles are made solely of the plurality of Cu—In—Ga particles.
4. The method of claim 3 wherein the Cu—In—Ga particles are separately formed by a method comprising: preparing a melt comprising Cu, In and Ga, and having the first composition; and spraying the melt into a gas having a lower temperature than the melt, thereby causing the sprayed melt particles to solidify into the Cu—In—Ga particles with the first composition and the pre-determined stoichiometry.
5. The method according to claim 4 wherein the gas is an inert gas.
6. The method according to claim 5 wherein the pre-determined stoichiometry is the same as the first composition.
7. The method according to claim 6 wherein the pre-determined stoichiometry has a Cu/(In+Ga) molar ratio of less than or equal to 1.0.
8. The method according to claim 4 wherein the step of spraying further includes using Cu—In—Ga particles that are uniformly mixed.
9. The method according to claim 3 wherein the step of sputter depositing uses a direct current.
10. The method of claim 1 wherein the plurality of different alloy particles are made from Cu—In particles and Cu—Ga particles, which Cu—In particles and Cu—Ga particles are each separately formed, intermixed to be compositionally uniformly distributed with the plurality of different solid particles, and then compressed together to form the single compositionally uniform Cu—In—Ga target.
11. The method of claim 10 wherein the plurality of different solid particles are further made from at least one of Cu—In—Ga particles, Cu particles, In particles, and Ga particles which are each separately formed, intermixed to be compositionally uniformly distributed with the plurality of different solid particles, and then compressed together to form the single compositionally uniform Cu—In—Ga target.
12. The method of claim 1 wherein the plurality of different alloy particles are made from Cu—In particles, Cu—Ga particles and In—Ga particles, which Cu—In particles, Cu—Ga particles, and In—Ga particles are each separately formed, intermixed to be compositionally uniformly distributed with the plurality of different solid particles, and then compressed together to form the single compositionally uniform Cu—In—Ga target.
13. The method of claim 1 wherein the plurality of different alloy particles are made from Cu—Ga particles, wherein the plurality of different solid particles further includes In particles, wherein the plurality of different solid particles are only Cu—Ga particles and In particles, wherein the Cu—Ga particles and the In particles are each separately formed, intermixed to be compositionally uniformly distributed with the plurality of different solid particles, and then compressed together to form the single compositionally uniform Cu—In—Ga target.
14. The method according to claim 1 wherein the step of sputter depositing uses a direct current.
15. The method according to claim 1 , wherein the plurality of particles are compressed together using a cold pressing process.