Electrochemical device comprising aliphatic mono-nitrile compound
View Patent ↗Disclosed is a cathode comprising a complex formed between the surface of a cathode active material and an aliphatic mono-nitrile compound, and an electrochemical device comprising the cathode. A non-aqueous electrolyte containing a lithium salt, a solvent and an aliphatic mono-nitrile compound, and an electrochemical device comprising the electrolyte are also disclosed. The electrochemical device shows excellent low-temperature characteristics, high-temperature life characteristics and safety.
1. A cathode comprising,
a complex formed between a surface of a cathode active material and an aliphatic mono-nitrile compound to provide a protective layer of the aliphatic mono-nitrile compound on the surface of the cathode active material,
wherein the protective layer of the aliphatic mono-nitrile compound is bonded to the cathode active material by a ligand-metal bond formed between a transition metal of the cathode active material and the aliphatic mono-nitrile compound.
2. The cathode according to claim 1 , wherein the aliphatic mono-nitrile compound is a compound represented by the following formula 1:
R—C≡N [Formula 1]
wherein R is a C1-C15 alkane.
3. The cathode according to claim 1 , wherein the complex between the surface of the cathode active material and the aliphatic mono-nitrile compound is formed by dipping the cathode, comprising the cathode active material coated on a collector, into an electrolyte containing the aliphatic mono-nitrile compound added thereto, followed by heat treatment at high temperature.
4. The cathode according to claim 3 , wherein the heat treatment is performed at a temperature of 30□ or higher.
5. An electrochemical device including,
a cathode according to claim 1 , the cathode having a complex formed between a surface of a cathode active material and an aliphatic mono-nitrile compound;
an anode; and
an electrolyte comprising a lithium salt and a solvent.
6. The electrochemical device according to claim 5 , wherein the aliphatic mono-nitrile compound is a compound represented by the following formula 1:
R—C≡N [Formula 1]
wherein R is a C1-C15 alkane.
7. The electrochemical device according to claim 5 , wherein the cathode comprises a complex formed between the surface of the cathode active material and the aliphatic mono-nitrile compound; and the anode comprises a passivation layer formed by a compound selected from the group consisting of vinylene carbonate, derivatives thereof and ether compounds.
8. The electrochemical device according to claim 5 , wherein the solvent includes either or both of at least one cyclic carbonate selected from the group consisting of ethylene carbonate, propylene carbonate and gamma-butyrolactone; and at least one linear carbonate selected from the group consisting of diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate and methyl propyl carbonate.
9. The electrochemical device according to claim 5 , wherein the cathode comprises a complex formed between the surface of the cathode active material and the aliphatic mono-nitrile compound; and the anode comprises a passivation layer formed by a compound selected from the group consisting of vinylene carbonate, derivatives thereof and ether compounds.