Coating composition and resin multilayer body

1. A coating composition comprising components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having an average particle diameter of from 1 to 200 nm being formed of a copolymer having a weight average molecular weight exceeding 10,000 of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton as a side chain with an ethylenically unsaturated compound selected from the group consisting of acrylic acid, methacrylic acid, a derivative of acrylic acid, a derivative of methacrylic acid, styrene and vinyl acetate;

(5) at least one curing catalyst; and

(6) at least one solvent.

2. The coating composition according to claim 1 wherein

the amount of the alkoxysilane compound or polyalkoxysilane compound (1) is 10 to 90 wt %;

the amount of the aminosilane compound (2) is 1 to 55 wt %;

the amount of the epoxysilane compound (3) is 1 to 60 wt %;

the amount of the organic fine particles (4) is 0.1 to 65 wt %;

the amount of the curing catalyst (5) is 0.1 to 30 wt %; and

the amount of the solvent (6) is 10 to 1000 parts by weight for 100 parts by weight of the total amount of the components (1) to (5).

3. The coating composition according to claim 1 wherein the curing catalyst is an organic acid.

4. A cured film obtainable by curing the coating composition of claim 1 .

5. A method for producing a cured film comprising curing the coating composition according to claim 1 by heating.

6. A method for producing a coating composition comprising mixing the following components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having an average particle diameter of from 1 to 200 nm being formed of a copolymer having a weight average molecular weight exceeding 10,000 of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton as a side chain with an ethylenically unsaturated compound selected from the group consisting of acrylic acid, methacrylic acid, a derivative of acrylic acid, a derivative of methacrylic acid, styrene and vinyl acetate;

(5) at least one curing catalyst; and

(6) at least one solvent.

7. The method according to claim 6 comprising:

preparing a first mixed solution comprising at least the components (1) and (4);

preparing a second mixed solution comprising at least the components (1), (2) and (3); and

mixing the first mixed solution and the second mixed solution.

8. A transparent cured film comprising organic fine particles having an ultraviolet absorbing group and an average particle diameter of 1 to 200 nm, the particles being dispersed in a matrix having an Si—O bond, and having a transmittance of visible light of 80% or more and a haze value of 10% or less;

the organic fine particles being formed of a copolymer, having a weight average molecular weight exceeding 10,000, of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or triazine skeleton as a side chain with ethylenically unsaturated compound selected from the group consisting of acrylic acid, methacrylic acid, derivative of acrylic acid, derivative of methacrylic acid, styrene and vinyl acetate, said transparent cured film obtained by a method comprising admixing components (1) to (6) to form a mixture:

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) a copolymer having a weight average molecular weight exceeding 10,000 of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton as a side chain with an ethylenically unsaturated compound selected from the group consisting of acrylic acid, methacrylic acid, a derivative of acrylic acid, a derivative of methacrylic acid, styrene and vinyl acetate;

(5) at least one curing catalyst; and

(6) at least one solvent; and

curing said mixture.

9. The transparent cured film according to claim 8 , wherein said at least one alkoxysilane compound is represented by formula (1):

(R 1 ) m Si(OR 2 ) 4-m   (1)

wherein R 1 is individually an alkyl group having 1 to 4 carbon atoms, a vinyl group, a phenyl group, or an alkyl group having 1 to 3 carbon atoms replaced by a methacryloxy group, R 2 is an alkyl group having 1 to 4 carbon atoms, and m is an integer of 0, 1, or 2.

10. The transparent cured film according to claim 8 , wherein said aminosilane compound is selected from the group consisting of N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-(2-aminoethyl)-3-amonopropyltriethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, and N-methylaminopropyltrimethoxysilane.

11. The transparent cured film according to claim 8 , wherein said epoxysilane compound is selected from the group consisting of 3-glycydoxypropylmethyldiethoxysilane, 3-glycydoxypropyltrimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, and 3-glycydoxypropyltriethoxysilane.

12. The transparent cured film according to claim 8 , wherein said at least one curing catalyst is at least one member selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, nitrous acid, perchloric acid, sulfamic acid, formic acid, acetic acid, propionic acid, butyric acid, oxalic acid, succinic acid, maleic acid, lactic acid, p-toluenesulfonic acid, citric acid, lithium hydroxide, sodium hydroxide, potassium hydroxide, n-hexylamine, dimethylamine, tributylamine, diazabicycloundecene, ethanolamine acetate, dimethylaniline formate, tetraethylammonium benzoate, sodium acetate, potassium acetate, sodium propionate, potassium propionate, sodium formate, potassium formate, benzoyltrimethylammonium acetate, tetramethylammonium acetate, tin octylate, tetraisopropyl titanate, tetrabutyl titanate, aluminum triisobutoxide, aluminum triisopropoxide, aluminum acetylacetonate, SnCl 4 , TiCl 4 , and ZnCl 4 .

13. The transparent cured film according to claim 8 , wherein said at least one solvent is at least one member selected from the group consisting of methanol, ethanol, n-propyl alcohol, i-propyl alcohol, n-butyl alcohol, sec-butyl alcohol, t-butyl alcohol, n-hexyl alcohol, n-octyl alcohol, ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol monobutyl ether, ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene monomethyl ether acetate, diacetone alcohol, methylcellosolve, ethylcellosolve, propylcellosolve, butylcellosolve, cyclohexanone, acetone, methyl ethyl ketone, methyl isobutyl ketone, tetrahydrofuran, 1,4-dioxane, 1,2-dimethoxyethane, xylene, dichloroethane, toluene, acetic acid, methyl acetate, ethyl acetate, and ethoxyethyl acetate.

14. The transparent cured film according to claim 8 , wherein the volume fraction of the organic fine particles in the transparent cured film is 0.5 to 70 vol %.

15. The transparent cured film according to claim 8 , wherein the SiO 2 -reduced weight derived from Si contained in the transparent cured film is 30 to 80 wt % of the total weight of the transparent cured film.

16. A resin multilayer body obtainable by forming the transparent cured film of claim 8 on a resin substrate.

17. A coating composition comprising components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton of which the weight average molecular weight exceeds 10,000 and the average particle diameter is from 1 to 200 nm;

(5) at least one curing catalyst; and

(6) at least one solvent.

18. A coating composition comprising components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles formed of a copolymer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton of which the weight average molecular weight exceeds 10,000 and the average particle diameter is from 1 to 200 nm;

(5) at least one curing catalyst; and

(6) at least one solvent.

19. A coating composition comprising components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having an average particle diameter is from 1 to 200 nm and formed of a copolymer having a weight average molecular weight exceeding 10,000 of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton with an ethylenically unsaturated compound;

(5) at least one curing catalyst; and

(6) at least one solvent.

20. A method for producing a coating composition comprising mixing the following components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton of which the weight average molecular weight exceeds 10,000 and the average particle diameter is from 1 to 200 nm;

(5) at least one curing catalyst; and

(6) at least one solvent.

21. A coating composition obtained by the method of claim 20 .

22. A method for producing a coating composition comprising mixing the following components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles formed of a copolymer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton of which the weight average molecular weight exceeds 10,000 and the average particle diameter is from 1 to 200 nm;

(5) at least one curing catalyst; and

(6) at least one solvent.

23. A coating composition obtained by the method of claim 22 .

24. A method for producing a coating composition comprising mixing the following components (1) to (6):

(1) at least one alkoxysilane compound or polyalkoxysilane compound;

(2) an aminosilane compound;

(3) an epoxysilane compound;

(4) organic fine particles having an average particle diameter of from 1 to 200 nm and formed of a copolymer having a weight average molecular weight exceeding 10,000 of an acrylic monomer having a benzophenone skeleton, benzotriazole skeleton or a triazine skeleton with an ethylenically unsaturated compound;

(5) at least one curing catalyst; and

(6) at least one solvent.

25. A coating composition obtained by the method of claim 24 .