IP Library Granted Patent US 8,080,310
Granted Patent B2
US 8,080,310 · App. 13/175,256 · Granted Dec 20, 2011

Multilayer, heat-shrinkable film comprising a plurality of microlayers

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Quick Facts
Patent No.
US 8,080,310
App. No.
13/175,256
Granted
Dec 20, 2011
Kind
B2
Abstract

A multilayer, heat-shrinkable film generally includes at least one bulk layer and a microlayer section comprising a plurality of microlayers. The ratio of the thickness of any of the microlayers to the thickness of the bulk layer ranges from about 1:2 to about 1:40.

Claims (22)

1. A method of making a multilayer, heat-shrinkable film, comprising:

a. extruding a bulk layer;

b. coextruding a plurality of microlayers to form a microlayer section;

c. merging said bulk layer and said microlayer section to form a multilayer film; and

d. stretch-orienting said multilayer film under conditions that impart heat-shrinkability to said film;

wherein, each of said microlayers and said bulk layer have a thickness, the ratio of the thickness of any of said microlayers to the thickness of said bulk layer ranging from about 1:2 to about 1:40; and

wherein, said film has a total free shrink (ASTM D2732-03) of at least about 10% at 200° F., and an Elmendorf Tear value (ASTM D1922-06a) of at least 10 grams, as measured in at least one direction along a length or width dimension of said film.

2. The method of claim 1 , wherein, said film has a thickness of less than about 0.7 mil.

3. The method of claim 1 , wherein said film is stretch-oriented at a ratio of at least 3 in at least one direction along a length or width dimension of said film.

4. The method of claim 3 , wherein said film is stretch-oriented at a ratio of at least 4 in at least one direction along a length or width dimension of said film.

5. The method of claim 1 , wherein said film is stretch-oriented at a ratio of at least 5 in at least one direction along a length or width dimension of said film.

6. The method of claim 1 , wherein

said microlayers each have a thickness ranging from about 0.001 to 0.015 mil; and

said bulk layer has a thickness ranging from about 0.03 to 0.5 mil.

7. The method of claim 1 , wherein said heat-shrinkable film has an Elmendorf Tear value (ASTM D1922-06a) of at least about 30 grams/mil, as measured in at least one direction along a length or width dimension of said film.

8. The method of claim 1 , wherein said microlayer section comprises a repeating sequence of layers represented by the structure:

A/B,

wherein,

A represents a microlayer comprising one or more polymers,

B represents a microlayer comprising a blend of two or more polymers, and

A has a composition that is different from that of B.

9. The method of claim 8 , wherein A and B comprise one or more of ethylene/alpha-olefin copolymer, ethylene/vinyl acetate copolymer, polypropylene homopolymer or copolymer, ethylene/methacrylic acid copolymer, maleic-anhydride-grafted polyethylene, polyamide, or low density polyethylene.

Assignments (2)
CHANGE OF NAME Recorded Nov 7, 2025
From: CRYOVAC, INC.
To: CRYOVAC, LLC
Reel/Frame 073507/0044 →
SECURITY INTEREST Recorded Oct 31, 2025
From: CRYOVAC, LLC
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 073428/0495 →