Process for production of aromatic carbonate
The present invention provides a process for the production of an aromatic carbonate, comprising the steps of: continuously feeding an aliphatic carbonate represented by following general formula (1) as a starting material, an aromatic monohydroxy compound represented by following general formula (2) as a reactant, and a metal-containing catalyst into a stage above the bottom of a first multi-stage distillation column so as to bring about reaction; continuously withdrawing from the reaction system in a gaseous form a low boiling point component containing an alcohol by-produced in the reaction; and continuously withdrawing from a lower portion of the column in a liquid form an aromatic carbonate represented by following general formula (3) obtained from the starting material and the reactant Ar 1 OH (2) wherein R 1 in general formulae (1) and (2) represents an aliphatic group having 4 to 6 carbon atoms, and Ar 1 represents an aromatic group having 5 to 30 carbon atoms wherein R 2 and Ar 2 in general formulae (3) are the same as R 1 and Ar 1 in the starting material and the reactant, respectively.
1. A process for the production of an aromatic carbonate, comprising:
continuously feeding an aliphatic carbonate represented by following general formula (1) as a starting material, an aromatic monohydroxy compound represented by following general formula (2) as a reactant, and a metal-containing catalyst into a stage above a bottom of a first multi-stage distillation column so as to bring about reaction; and
continuously withdrawing from a reaction system in a gaseous form a low boiling point component containing an alcohol by-produced in the reaction, and continuously withdrawing from a lower portion of the column in a liquid form an aromatic carbonate represented by following general formula (3) obtained from the starting material and the reactant,
Ar 1 OH (2),
wherein R 1 in general formulae (1) and (2) represents an aliphatic group having 4 to 6 carbon atoms, and Ar 1 represents an aromatic group having 5 to 30 carbon atoms,
wherein R 2 and Ar 2 in general formula (3) are the same as R 1 and Ar 1 in the starting material and the reactant, respectively,
wherein said metal-containing catalyst is dissolved in a liquid phase in said reaction, or is present in a liquid form during said reaction, and said metal-containing catalyst comprises an organic titanate having at least one Ti—O—Ti linkage therein.
2. The process according to claim 1 , wherein said aromatic carbonate comprises a diaryl carbonate represented by following general formula (4):
wherein Ar 2 in general formula (4) is the same as Ar 1 in the reactant.
3. The process according to claim 1 , wherein R 1 in the aliphatic carbonate represented by general formula (1) is a saturated aliphatic group having 4 to 6 carbon atoms.
4. The process according to claim 1 , wherein R 1 in the aliphatic carbonate represented by general formula (1) is a saturated aliphatic group having 5 or 6 carbon atoms.
5. The process according to claim 1 , wherein R 1 in the aliphatic carbonate represented by general formula (1) is an alkyl group.
6. The process according to claim 1 , wherein the aromatic monohydroxy compound represented by general formula (2) comprises phenol.
7. The process according to claim 1 , wherein the column bottom temperature in said distillation column is in a range of from 150 to 250° C.
8. The process according to claim 1 , wherein a molar ratio of the reactant to the starting material fed into said multi-stage distillation column is in a range of from 0.1 to 5.
9. The process according to claim 1 , wherein the first multi-stage distillation column has not less than two theoretical distillation stages therein, and the catalyst is made to be present in at least two of the stages.
10. The process according to claim 2 , further comprising the steps of:
continuously feeding into a second multi-stage distillation column the reaction liquid withdrawn from the lower portion of the first multi-stage distillation column in the process according to claim 1 either as is or after removing the starting material and/or reactant therefrom, so as to carry out a disproportionation reaction;
continuously withdrawing in a gaseous form by distillation a low boiling point component containing an aliphatic carbonate by-produced in the reaction; and
continuously withdrawing from a lower portion of the second multi-stage distillation column in a liquid form the diaryl carbonate represented by the general formula (4).
11. The process according to claim 10 , wherein the steps according to claim 13 are performed to recycle the aliphatic carbonate for use as the starting material.
12. The process according to claim 11 , wherein R 1 in the aliphatic carbonate represented by general formula (1) is a saturated aliphatic group having 5 or 6 carbon atoms.
13. The process according to claim 12 , wherein R 1 in the aliphatic carbonate represented by general formula (1) is an alkyl group.
14. The process according to claim 13 , wherein the aromatic monohydroxy compound represented by general formula (2) comprises phenol.
15. The process according to claim 14 , wherein the column bottom temperature in said distillation column is in a range of from 150 to 250° C.
16. The process according to claim 15 , wherein a molar ratio of the reactant to the starting material fed into said multi-stage distillation column is in a range of from 0.1 to 5.
17. The process according to claim 16 , wherein the first multi-stage distillation column has not less than two theoretical distillation stages therein, and the catalyst is made to be present in at least two of the stages.