IP Library Granted Patent US 8,153,105
Granted Patent B1
US 8,153,105 · App. 12/165,919 · Granted Apr 10, 2012

Sunblock composition with photostabilizer and method of preparation

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Quick Facts
Patent No.
US 8,153,105
App. No.
12/165,919
Granted
Apr 10, 2012
Kind
B1
Abstract

A sunblock or sunscreen composition with enhanced photostability and a method for preparing and using the novel photostabilizer are provided. The combination of avobenzene, dimethyl capramide, and polyester-8, a copolymer of adipic acid and neopentyl glycol that is terminated with cyanodiphenyl propenoic acid, provides an extra layer of protection to keep the sunscreen working longer to protect the skin from damaging ultraviolet rays, namely, UVA and UVB. Sunblock products with SPF-15 for moderate sun protection. SPF-30 for higher sun protection and SPF-50, specially formulated for fair skin provides high sun protection. The sunblock compositions with the novel photostabilizer have a clean, dry formula that glides on easily for quick absorption, while enlisting sea plant extracts and anti-oxidant vitamins A, C, and E that aid in the reduction of cell damaging free radicals for younger looking skin.

Claims (41)

1. A photostabilizer composition for sunscreen or sunblock products consisting of, in combination:

a sun blocking agent that absorbs both UVA and UVB rays; and

a photostabilizer for a full UVA and UVB spectrum sunscreen that consists of avobenzone, dimethyl capramide, and polyester-8, a copolymer of adipic acid and neopentyl glycol that is terminated with cyanodiphenyl propenoic acid.

2. A method for preparing a photostabilizer composition that enhances the photostability of a sunscreen or sunblock composition, comprising the steps of:

a) selecting a mixing vessel;

b) mixing avobenzone polyester-8, a copolymer of adipic acid and neopentyl glycol that is terminated with cyanodiphenyl propenoic acid, in the vessel with a first solvent and a second solvent until the polyester-8 has completely dissolved in the first and second solvent, wherein said first solvent is dimethyl capramide (DMDA);

c) adding the mixture of step b) to an oil phase portion of a sunblock composition; and

d) continuing the mixing of the mixture of step b) and the oil phase portion of a sunblock composition for an additional period of time of approximately 30 minutes.

3. The method of claim 2 , wherein the second solvent is polyisobutene.

4. A sunscreen composition with a photostabilizer consisting of:

an aqueous phase;

an oil phase; and

a photostabilizer consisting of avobenzone, dimethyl capramide, and polyester-8, a copolymer of adipic acid and neopentyl glycol that is terminated with cyanodiphenyl propenoic acid, wherein the sunscreen composition is prepared in a cold process in a mixing tank that is operated at atmospheric pressure and room temperature between approximately 65° F. and approximately 85° F.

5. The sunscreen composition of claim 4 , wherein the aqueous phase consists of:

diisoproply adipate;

acrylates copolymer;

polyisobutene;

propylene glycol;

dimethyl capramide;

triethanolamine (TEA99%); and

algae extract (seaweed extract).

6. The sunscreen composition of claim 4 , wherein the oil phase consists of:

ascorbic acid;

oleo europaea (olive) fruit oil;

retinyl palmitate;

tocopheryl acetate;

hydroxypropyl methylcellulose

sorbitan oleate;

acrylates/C10-30 alkylacrylate cross polymer (TR-2);

carbomer;

disodium EDTA;

phenoxyethanol+methyl & butyl & ethyl & propyl & isobutyl parabens; and

fragrance.

7. The sunscreen composition of claim 4 , wherein the photostabilizer consists of:

avobenzone in an amount that is approximately 2 weight % of the total sunscreen formula;

dimethyl capramide in an amount that is approximately 1 weight % of the total sunscreen formula; and

polyester-8, a copolymer of adipic acid and neopentyl glycol that is terminated with cyanodiphenyl propenoic acid in an amount between approximately 2 to approximately 3 weight % of the total sunscreen formula.

8. The sunscreen composition of claim 4 , wherein the photostabilizer is separately prepared in a process wherein polyester-8 is mixed with a plurality of solvents until the polyester-8 is completely dissolved.

9. The sunscreen composition of claim 8 , wherein the plurality of solvents are at least one of polyisobutene and at least one of dimethyl capramide (DMDA) for a combined total of two solvents.

10. The sunscreen composition of claim 4 , wherein the photostabilizer is added to the oil phase for subsequent mixing with the aqueous phase in the preparation of the final sunscreen composition.

11. The sunscreen composition of claim 4 , wherein the photostabilizer is present in said composition in an amount from approximately 5.0 weight % to approximately 10.0 weight % based on the total weight of the composition.

Assignments (15)
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 29, 2021
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK INTERNATIONAL LLC; NC BRANDS L.P.; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC
Reel/Frame 057650/0125 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (2019) Recorded Jan 28, 2019
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CBI LABORATORIES, INC.; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 048180/0101 →
RELEASE OF SECURITY INTEREST Recorded Sep 14, 2016
From: BARCLAYS BANK PLC
To: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC; PRESTONE PRODUCTS CORPORATION
Reel/Frame 040031/0793 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Apr 5, 2016
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC. (TEXAS); KIK CUSTOM PRODUCTS INC. (DELAWARE); KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 038354/0938 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 11, 2015
From: SUN & SKIN CARE RESEARCH, LLC
To: SOLSKYN PERSONAL CARE LLC
Reel/Frame 036546/0429 →
RELEASE OF SECURITY INTEREST Recorded Sep 11, 2015
From: CAPITALSOUTH PARTNERS SBIC FUND III, L.P., AS COLLATERAL AGENT
To: SUN & SKIN CARE RESEARCH, LLC
Reel/Frame 036542/0241 →
RELEASE OF SECURITY INTEREST Recorded Sep 11, 2015
From: ACF FINCO I LP
To: SUN & SKIN CARE RESEARCH, LLC
Reel/Frame 036542/0869 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTERESTS IN PATENTS Recorded Jun 4, 2015
From: FCC, LLC DBA FIRST CAPITAL
To: ACF FINCO I LP
Reel/Frame 035831/0732 →
RELEASE OF SECURITY INTEREST Recorded Jun 20, 2014
From: REGIONS BANK
To: SUN & SKIN CARE RESEARCH, LLC
Reel/Frame 033205/0074 →
RELEASE OF SECURITY INTEREST Recorded Jun 20, 2014
From: REGIONS BANK
To: SUN & SKIN CARE RESEARCH, LLC
Reel/Frame 033205/0104 →
SECURITY INTEREST Recorded Jun 16, 2014
From: SUN & SKIN CARE RESEARCH, LLC
To: FCC, LLC, DBA FIRST CAPITAL
Reel/Frame 033112/0356 →
SECURITY AGREEMENT Recorded May 1, 2012
From: SUN & SKIN CARE RESEARCH, LLC
To: CAPITALSOUTH PARTNERS SBIC FUND III, L.P.
Reel/Frame 028133/0332 →
SECURITY AGREEMENT Recorded Apr 16, 2012
From: SUN & SKIN CARE RESEARCH, LLC
To: REGIONS BANK
Reel/Frame 028052/0166 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2012
From: SUN & SKIN CARE RESEARCH, INC.
To: SUN & SKIN CARE RESEARCH, LLC
Reel/Frame 028007/0295 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 1, 2008
From: DEANGELO, GARY
To: SUN & SKIN CARE RESEARCH, INC.
Reel/Frame 021179/0397 →