IP Library Granted Patent US 8,192,539
Granted Patent B2
US 8,192,539 · App. 13/111,607 · Granted Jun 5, 2012

Mixtures of zeolite and RAP/RAS

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Quick Facts
Patent No.
US 8,192,539
App. No.
13/111,607
Granted
Jun 5, 2012
Kind
B2
Abstract

Embodiments of the invention provide method for preparing mixtures of natural or artificial zeolite with at least one of recycled asphalt shingles and recycled asphalt pavement. The prepared mixtures are also within the scope of the invention. Mixtures prepared as described herein may be useful, for example, for mixture with hot mix asphalt and cold patch asphalt.

Claims (24)

1. An asphalt mix additive comprising:

a zeolite in an amount between 0.01% and 0.5% by weight per ton of asphalt mix; and

recycled asphalt shingles in an amount between 0.5% and 50% by weight per ton of asphalt mix.

2. The asphalt mix additive of claim 1 , wherein said zeolite is selected from the group consisting of amicite, analcime, barrerite, bellbergite, bikitaite, boggsite, brewsterite, chabazite, clinoptilolite, cowlesite, dachiardite, edingtonite, epistilbite, erionite, faujasite, ferrierite, garronite, gismondine, gmelinite, gobbinsite, gonnardite, goosecreekite, harmotome, herschelite, heulandite, laumontite, levyne, maricopaite, mazzite, merlinoite, mesolite, montesommaite, mordenite, natrolite, offretite, paranatrolite, paulingite, pentasil (also known as zsm-5), perlialite, phillipsite, pollucite, scolecite, sodium dachiardite, stellerite, stilbite, tetranatrolite, thomsonite, tschernichite, wairakite, wellsite, willhendersonite, yugawaralite, zeolite A, zeolite X, zeolite P, zeolite Y, zeolite 4A, zeolite 13X, and mixtures thereof.

3. The asphalt mix additive of claim 1 , wherein said zeolite is Zeolite A.

4. The asphalt mix additive of claim 1 , wherein said zeolite contains water in an amount between 5 and 35% by weight of the zeolite.

5. The asphalt mix additive of claim 1 , wherein said recycled asphalt shingles are organic recycled asphalt shingles comprising, by weight, 30-50% asphalt cement, 5-15% felt, 10-20% mineral filler, and 30-50% mineral granules.

6. The asphalt mix additive of claim 1 , wherein said recycled asphalt shingles are fiberglass shingles comprising, by weight, 15-50% asphalt cement, 5-15% felt, 15-20% mineral filler, and 30-50% mineral granules.

7. An asphalt mix additive comprising:

a zeolite in an amount between 0.01% and 0.5% by weight per ton of asphalt mix; and

reclaimed asphalt pavement in an amount between 5% and 90% by weight per ton of asphalt mix.

8. The asphalt mix additive of claim 7 , wherein said zeolite is selected from the group consisting of amicite, analcime, barrerite, bellbergite, bikitaite, boggsite, brewsterite, chabazite, clinoptilolite, cowlesite, dachiardite, edingtonite, epistilbite, erionite, faujasite, ferrierite, garronite, gismondine, gmelinite, gobbinsite, gonnardite, goosecreekite, harmotome, herschelite, heulandite, laumontite, levyne, maricopaite, mazzite, merlinoite, mesolite, montesommaite, mordenite, natrolite, offretite, paranatrolite, paulingite, pentasil (also known as zsm-5), perlialite, phillipsite, pollucite, scolecite, sodium dachiardite, stellerite, stilbite, tetranatrolite, thomsonite, tschernichite, wairakite, wellsite, willhendersonite, yugawaralite, zeolite A, zeolite X, zeolite P, zeolite Y, zeolite 4A, zeolite 13X, and mixtures thereof.

9. The asphalt mix additive of claim 7 , wherein said zeolite is Zeolite A.

10. The asphalt mix additive of claim 7 , wherein said zeolite contains water in an amount between 5 and 35% by weight of the zeolite.

11. The asphalt mix additive of claim 7 , wherein said reclaimed asphalt pavement comprises 93-97% mineral aggregate and 3-7% asphalt cement.

12. An asphalt mix additive comprising:

a zeolite;

recycled asphalt shingles; and

sand.

13. The asphalt mix additive of claim 12 , wherein said zeolite is selected from the group consisting of amicite, analcime, barrerite, bellbergite, bikitaite, boggsite, brewsterite, chabazite, clinoptilolite, cowlesite, dachiardite, edingtonite, epistilbite, erionite, faujasite, ferrierite, garronite, gismondine, gmelinite, gobbinsite, gonnardite, goosecreekite, harmotome, herschelite, heulandite, laumontite, levyne, maricopaite, mazzite, merlinoite, mesolite, montesommaite, mordenite, natrolite, offretite, paranatrolite, paulingite, pentasil (also known as zsm-5), perlialite, phillipsite, pollucite, scolecite, sodium dachiardite, stellerite, stilbite, tetranatrolite, thomsonite, tschernichite, wairakite, wellsite, willhendersonite, yugawaralite, zeolite A, zeolite X, zeolite P, zeolite Y, zeolite 4A, zeolite 13X, and mixtures thereof.

14. The asphalt mix additive of claim 12 , wherein said zeolite is Zeolite A.

15. The asphalt mix additive of claim 12 , wherein said zeolite contains water in an amount between 5 and 35% by weight of the zeolite.

16. The asphalt mix additive of claim 12 , wherein said recycled asphalt shingles are organic recycled asphalt shingles comprising, by weight, 30-50% asphalt cement, 5-15% felt, 10-20% mineral filler, and 30-50% mineral granules.

17. The asphalt mix additive of claim 12 , wherein said recycled asphalt shingles are fiberglass shingles comprising, by weight, 15-50% asphalt cement, 5-15% felt, 15-20% mineral filler, and 30-50% mineral granules.

Assignments (21)
CHANGE OF NAME Recorded Dec 2, 2021
From: PQ CORPORATION
To: PQ LLC
Reel/Frame 058295/0836 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING PARTY NAME PREVIOUSLY RECORDED AT REEL: 057089 FRAME: 0345. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Aug 6, 2021
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 057109/0688 →
PARTIAL RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 056539/0903 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION
Reel/Frame 057089/0255 →
PARTIAL RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 038861/0071 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 057089/0345 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 038860/0900 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION
Reel/Frame 057089/0382 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Jun 10, 2021
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS AGENT
Reel/Frame 056539/0903 →
RELEASE OF SECURITY INTEREST IN PATENTS AT R/F 053281/0474 Recorded Jun 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 056539/0782 →
SECURITY INTEREST Recorded Jul 22, 2020
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 053281/0474 →
RELEASE OF SECURITY INTEREST AT R/F 38860/0012 Recorded Jul 22, 2020
From: WELLS FARGO BANK, N.A., AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 053281/0616 →
PATENT SECURITY AGREEMENT (NOTES) Recorded Jun 1, 2016
From: PQ CORPORATION
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 038860/0012 →
PATENT SECURITY AGREEMENT (ABL) Recorded Jun 1, 2016
From: PQ CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038861/0071 →
PATENT SECURITY AGREEMENT (TERM) Recorded Jun 1, 2016
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 038860/0900 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION; POTTERS INDUSTRIES, LLC
Reel/Frame 038612/0222 →
RELEASE OF SECURITY INTEREST Recorded May 4, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION; POTTERS INDUSTRIES, LLC
Reel/Frame 038611/0927 →
SECURITY AGREEMENT Recorded Nov 30, 2012
From: PQ CORPORATION; POTTERS INDUSTRIES, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 029377/0878 →
SECURITY AGREEMENT Recorded Nov 29, 2012
From: PQ CORPORATION; POTTERS INDUSTRIES, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 029370/0103 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Nov 26, 2012
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: PQ CORPORATION
Reel/Frame 029349/0592 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Nov 26, 2012
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: PQ CORPORATION
Reel/Frame 029349/0556 →
FIRST LIEN GRANT OF SECURITY INTEREST IN PATENTS AMENDMENT NO. 1 Recorded Apr 3, 2012
From: PQ CORPORATION
To: CREDIT SUISSE AG, AS SUCCESSOR AGENT
Reel/Frame 027980/0194 →
SECOND LIEN GRANT OF SECURITY INTEREST IN PATENTS AMENDMENT NO. 1 Recorded Apr 3, 2012
From: PQ CORPORATION
To: CREDIT SUISSE AG, AS SUCCESSOR AGENT
Reel/Frame 027980/0219 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2011
From: BARGER, SCOTT; SOTELO, ARMANDO; MICCO, DANIEL; RIBEIRO, FLAVIO ERNESTO
To: PQ CORPORATION
Reel/Frame 026751/0001 →