Thermal recording material
View Patent ↗Provided is a thermal recording material superior in color development sensitivity, and having good preservation properties such as in heat resistance, moisture resistance, water resistance and the like. A thermal recording material comprising a support and a thermal recording layer comprising a colorless or pale basic leucodye and a developer to develop color of the basic leucodye, wherein the aforementioned developer comprises a first developer which is a condensate or condensed composition represented by the following formula (I) and a second developer other than the first developer, and the proportion of the first developer to the total amount of the developers is not less than 2 wt % and less than 50 wt %: wherein R is a hydrogen atom, a halogen atom, a hydroxyl group, a lower alkyl group, an alkoxyl group, a cyano group, a nitro group, an aryl group or an aralkyl group, R in the number of m may be the same or different, m is an integer of 0 to 3, n is an integer of 0 to 3, and X and Y are each a hydrogen atom, an alkyl group or an aryl group.
1. A thermal recording material comprising a support and a thermal recording layer comprising a colorless or pale basic leucodye and a developer to develop color of the basic leucodye, wherein the aforementioned developer comprises a first developer which is a condensate or condensed composition represented by the following formula (I) and a second developer other than the first developer, wherein the second developer is at least one kind selected from the group consisting of bisphenol A, 4,4′-dihydroxydiphenylsulfone, 4-hydroxy-4′-n-propoxydiphenylsulfone, 2,4′-dihydroxydiphenylsulfone, 4-hydroxy-4′-allyloxydiphenylsulfone, and bis(3-allyl-4-hydroxyphenyl)sulfone, and the proportion of the first developer to the total amount of the developers is not less than 5 wt % and less than 40 wt %:
wherein R is a halogen atom, a hydroxyl group, a lower alkyl group, an alkoxyl group, a cyano group, a nitro group, an aryl group or an aralkyl group, R in the number of m may be the same or different, m is an integer of 0 to 3, n is an integer of 0 to 3, and X and Y are each a hydrogen atom, an alkyl group or an aryl group.
2. The thermal recording material of claim 1 , wherein the first developer is a condensed composition represented by the formula (I) mainly comprising a condensate of the formula (I) wherein n=0, and further comprising at least one kind of condensate selected from condensates of the formula (I) wherein n is 1-3.
3. The thermal recording material of claim 2 , wherein the content of the condensate of the formula (1) wherein n=0 is 40-99%.
4. The thermal recording material of claim 1 , wherein the second developer is at least one kind selected from the group consisting of bisphenol A, 4,4′-dihydroxydiphenylsulfone, and 4-hydroxy-4′-n-propoxydiphenylsulfone.
5. The thermal recording material of claim 1 , wherein the second developer is bisphenol A.
6. The thermal recording material of claim 1 , wherein the proportion of the first developer to the total amount of the developers is not less than 5 wt % and less than 25 wt %.
7. The thermal recording material of claim 1 , wherein R in the formula (I) is bonded to the p-position of the hydroxyl group of a phenol group.
8. The thermal recording material of claim 1 , wherein thermal recording layer further comprises a sensitizer.
9. The thermal recording material of claim 8 , wherein the sensitizer is diphenylsulfone.