Composition for anti-glare film and anti-glare film prepared using the same
The present invention provides a composition for an anti-glare film that includes a binder resin; and an organic particle which is included in an amount of 1 to 30 parts by weight based on 100 parts by weight of the binder resin and in which concave and convex patterns are formed on a surface thereof, and an anti-glare film that is manufactured by using the same. Accordingly, the storage stability of a particle that is included in an anti-glare film for high resolution is improved to increase the durability and a lifespan of products, a glare phenomenon that is caused by incident light and recognized by an user is prevented, and image clarity and contrast ratio that is realized by using an image display device are improved.
1. A composition for an anti-glare film comprising:
a binder resin; and
an organic particle which is included in an amount of 1 to 30 parts by weight based on 100 parts by weight of the binder resin and in which concave and convex patterns are formed on a surface thereof,
wherein a height of the concave and convex patterns of the organic particle is in a range of 0.01 to 2 μm, a width of the concave and convex patterns of the organic particle is in a range of 0.01 to 4 μm, and a total distribution ratio of the concave and convex patterns of the organic particle is in a range of 10 to 100% of a total surface area of the organic particle.
2. The composition for an anti-glare film as set forth in claim 1 , wherein an average diameter of the organic particle is in the range of 1 to 10 μm.
3. The composition for an anti-glare film as set forth in claim 1 , wherein a difference between average refractive indices of the organic particle and the binder resin is 0.01 to 0.3.
4. The composition for an anti-glare film as set forth in claim 1 , wherein the organic particle is a single material or a copolymer of two or more materials selected from polystyrene, polymethyl methacrylate, polymethyl acrylate, polyacrylate, polyacrylate-co-styrene, polymethylacrylate-co-styrene, poly-methylmethacrylate-co-styrene, polycarbonate, polyvinyl chloride, poly-butyleneterephthalate, polyethyleneterephthalate, polyamides, polyimides, polysulfone, polyphenylene oxide, polyacetal, epoxy resin, phenol resin, silicon resin, melamine resin, benzoguanamine, polydivinylbenzene, polydi-vinylbenzene-co-styrene, polydivinylbenzene-co-acrylate, polydiallyl phthalate, and triallylisocyanurate polymer.
5. The composition for an anti-glare film as set forth in claim 1 , wherein the binder resin is a single material or a mixture of two or more materials selected from a reactive acrylate oligomer and a polyfunctional acrylate monomer.
6. The composition for an anti-glare film as set forth in claim 5 , wherein the reactive acrylate oligomer is a single material or a mixture of two or more materials selected from urethane acrylate oligomer, an epoxy acrylate oligomer, polyester acrylate and polyether acrylate.
7. The composition for an anti-glare film as set forth in claim 5 , wherein the poly-functional acrylate monomer is a single material or a mixture of two or more materials selected from dipentaerythritol hexaacrylate, dipentaerythritol hydroxy pentaacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, trimethylene propyl triacrylate, propoxylated glycerol triacrylate, trimethy-lopropane ethoxy triacrylate, 1,6-hexanedioldiacrylate, propoxylated glycero triacrylate, tripropylene glycol diacrylate and ethyleneglycol diacrylate.
8. The composition for an anti-glare film as set forth in claim 1 , further comprising: 50 to 500 parts by weight of an organic solvent based on 100 parts by weight of the binder resin.
9. The composition for an anti-glare film as set forth in claim 1 , further comprising: 0.1 to 10 parts by weight of a UV curing initiator based on 100 parts by weight of the binder resin.
10. The composition for an anti-glare film as set forth in claim 1 , further comprising: one or more additives selected from a leveling agent, a wetting agent, a defoaming agent and silica having an average particle diameter in the range of 1 to 50 nm.
11. An anti-glare film comprising:
a binder resin; and
an anti-glare layer that includes an organic particle which is included in an amount of 1 to 30 parts by weight based on 100 parts by weight of the binder resin and in which concave and convex patterns are formed on a surface thereof,
wherein a height of the concave and convex patterns of the organic particle is in a range of 0.01 to 2 μm, a width of the concave and convex patterns of the organic particle is in a range of 0.01 to 4 μm, and a total distribution ratio of the concave and convex patterns of the organic particle is in a range of 10 to 100% of a total surface area of the organic particle.
12. The anti-glare film as set forth in claim 11 , wherein an average diameter of the organic particle is in the range of 1 to 10 μm.
13. The anti-glare film as set forth in claim 11 , wherein a difference between average refractive indices of the organic particle and the binder resin is 0.01 to 0.3.
14. The anti-glare film as set forth in claim 11 , wherein the organic particle is a single material or a copolymer of two or more materials selected from polystyrene, polymethyl methacrylate, polymethyl acrylate, polyacrylate, polyacrylate-co-styrene, polymethylacrylate-co-styrene, polymethyl-methacrylate-co-styrene, polycarbonate, polyvinyl chloride, poly-butyleneterephthalate, polyethyleneterephthalate, polyamides, polyimides, polysulfone, polyphenylene oxide, polyacetal, epoxy resin, phenol resin, silicon resin, melamine resin, benzoguanamine, polydivinylbenzene, polydi-vinylbenzene-co-styrene, polydivinylbenzene-co-acrylate, polydiallyl phthalate, and triallylisocyanurate polymer.
15. The anti-glare film as set forth in claim 11 , wherein the binder resin is a single material or a mixture of two or more materials selected from a reactive acrylate oligomer and a polyfunctional acrylate monomer.
16. The an anti-glare film as set forth in claim 15 , wherein the reactive acrylate oligomer is a single material or a mixture of two or more materials selected from urethane acrylate oligomer, an epoxy acrylate oligomer, polyester acrylate and polyether acrylate.
17. The anti-glare film as set forth in claim 15 , wherein the polyfunctional acrylate monomer is a single material or a mixture of two or more materials selected from dipentaerythritol hexaacrylate, dipentaerythritol hydroxy pentaacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, trimethylene propyl triacrylate, propoxylated glycerol triacrylate, trimethylopropane ethoxy triacrylate, 1,6-hexanedioldiacrylate, propoxylated glycero triacrylate, tripropylene glycol diacrylate and ethyleneglycol diacrylate.
18. The anti-glare film as set forth in claim 11 , further comprising: a transparent substrate layer that is provided on at least one side of the anti-glare layer.
19. The anti-glare film as set forth in claim 11 , further comprising: a low reflective layer that is provided on the anti-glare layer.
20. The anti-glare film as set forth in claim 11 , further comprising: an anti-pollution layer that is provided on the anti-glare layer.