IP Library Granted Patent US 8,282,974
Granted Patent B2
US 8,282,974 · App. 12/885,217 · Granted Oct 9, 2012

Tandem use of catholyte and anolyte to clean and sanitize fruit and vegetables

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Quick Facts
Patent No.
US 8,282,974
App. No.
12/885,217
Granted
Oct 9, 2012
Kind
B2
Abstract

A method for de-soiling and disinfecting produce, the method including: treating the produce with a catholyte solution to yield a catholyte treated produce; sonicating the catholyte treated produce to yield a sonicated produce; and treating the sonicated produce with an anolyte solution.

Claims (34)

1. A method for de-soiling and disinfecting produce, the method comprising:

treating the produce with a catholyte solution for at least 15 seconds to yield a catholyte treated produce,

wherein treatment with the catholyte solution for at least 15 seconds yields at least a 19% increase in de-soiling of the produce as compared to treating the produce with a liquid detergent solution having the same surface tension as the catholyte solution, and

wherein the catholyte solution has a pH that ranges from approximately 12.3 to approximately 13.0;

sonicating the catholyte-treated produce for at least 20 seconds to yield a sonicated produce,

wherein sonication for at least 20 seconds yields at least a 1.5-fold increase in de-soiling of the catholyte-treated produce as compared to treating the produce with the catholyte solution without sonication, and

wherein sonication occurs at an ultrasonication frequency that ranges from approximately 20 kHz to approximately 60 kHz; and

treating the sonicated produce with an anolyte solution for at least 20 seconds,

wherein treatment with the anolyte solution for at least 20 seconds yields at least a 1 log unit reduction in microbial load as compared to the microbial load of produce not treated with the anolyte solution,

wherein the anolyte solution has a concentration at least 80 ppm Free Available Chlorine (FAC), and

wherein the anolyte solution has a pH that ranges from approximately 6.2 to approximately 7.4,

wherein the catholyte and anolyte solutions were generated by an electrolytic cell that produces laminar flow.

2. The method of claim 1 , further comprising electrolyzing an ionic solution to generate the catholyte solution and anolyte solution.

3. The method of claim 1 , wherein the ionic solution is a brine solution or a bicarbonate solution.

4. The method of claim 1 , wherein the electrolyzing occurs less than 12 hours prior to treating the produce with the catholyte solution and the anolyte solution.

5. The method of claim 1 , wherein treatment with the catholyte solution comprises immersing the produce in a wash tank containing the catholyte solution.

6. The method of claim 5 , further comprising spraying the produce with the catholyte solution prior to immersing the produce in the wash tank.

7. The method of claim 1 , wherein the catholyte solution is a diluted catholyte solution that is used as a 10% dilution.

8. The method of claim 1 , wherein the sonicating occurs in a wash tank containing the catholyte solution.

9. The method of claim 1 , wherein the sonicating occurs at multiple frequencies.

10. The method of claim 1 , wherein treatment with the anolyte solution comprises immersing the produce in a wash tank containing the anolyte solution or spraying the produce with the anolyte solution.

11. The method of claim 1 , wherein the produce is selected from the group consisting of lettuce, a leafy vegetable, a ground plant, a tree fruit, a berry, a nut, and any combination thereof.

12. A method for de-soiling and disinfecting produce, the method comprising:

immersing the produce in a wash tank containing a catholyte solution for at least 15 seconds to yield an immersed produce,

wherein immersion in the catholyte solution for at least 15 seconds yields at least a 19% increase in de-soiling as compared to immersing the produce in a liquid detergent solution having the same surface tension as the catholyte solution, and

wherein the catholyte solution has a pH that ranges from approximately 12.3 to approximately 13.0;

sonicating the immersed produce for at least 20 seconds to yield a sonicated produce,

wherein sonication for at least 20 seconds yields at least a 1.5-fold increase in de-soiling of the immersed produce as compared to treating the produce with the catholyte solution without sonication, and

wherein the sonicating occurs at an ultrasonication frequency that ranges from approximately 20 kHz to approximately 60 kHz; and

treating the sonicated produce with an anolyte solution for at least 20 seconds,

wherein treatment with the anolyte solution for at least 20 seconds yields at least a 1 log unit reduction in microbial load as compared to the microbial load of produce not treated with the anolyte solution,

wherein the anolyte solution comprises a concentration at least 80 ppm FAC, and

wherein the anolyte solution has a pH that ranges from approximately 6.2 to approximately 7.4,

wherein the catholyte and anolyte solutions were generated by an electrolytic cell that produces laminar flow.

Assignments (26)
CHANGE OF NAME Recorded Aug 8, 2025
From: BUD ANTLE, INC.
To: BUD ANTLE, LLC
Reel/Frame 072388/0634 →
RELEASE OF SECURITY INTEREST Recorded Aug 8, 2025
From: COÖPERATIEVE RABOBANK U.A.
To: BUD ANTLE, LLC
Reel/Frame 071976/0516 →
SECURITY INTEREST Recorded Aug 6, 2025
From: BUD ANTLE, LLC (F/K/A BUD ANTLE, INC.); ORGANICGIRL, LLC
To: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH
Reel/Frame 071944/0797 →
PARTIAL RELEASE OF SECURITY INTEREST (57108/0639) Recorded Aug 5, 2025
From: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH
To: BUD ANTLE, LLC (AS SUCCESSOR-BY-CONVERSION TO BUD ANTLE, INC. AND AS SUCCESSOR-BY-ASSIGNMENT TO DOLE FRESH VEGETABLES, INC.)
Reel/Frame 072394/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 27, 2023
From: DOLE FRESH VEGETABLES, INC.
To: BUD ANTLE, INC.
Reel/Frame 062506/0201 →
SECURITY AGREEMENT Recorded Aug 6, 2021
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 057108/0639 →
RELEASE OF SECURITY INTEREST Recorded Aug 6, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.; BUD ANTLE, INC.; DOLE DIVERSIFIED NORTH AMERICA, INC. (F/K/A DOLE BERRY COMPANY AND SUNNYRIDGE FARM, INC.); RENAISSANCE CAPITAL CORPORATION; DFC HOLDINGS, LLC; DOLE FRESH FRUIT COMPANY; ROYAL PACKING LLC (F/K/A ROYAL PACKING CO.)
Reel/Frame 057108/0601 →
RELEASE (REEL 042197 / FRAME 0586) Recorded Aug 5, 2021
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0460 →
RELEASE (REEL 042232 / FRAME 0777) Recorded Aug 5, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0392 →
RELEASE (REEL 042206 / FRAME 0828) Recorded Aug 5, 2021
From: BANK OF AMERICA, N.A.
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0499 →
SECURITY AGREEMENT Recorded Apr 12, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 042232/0777 →
SECURITY AGREEMENT Recorded Apr 11, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 042206/0828 →
SECURITY AGREEMENT Recorded Apr 10, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS ADMINISTRATIVE AGENT
Reel/Frame 042197/0586 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING CO.; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041932/0215 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING CO.; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041929/0297 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING LLC; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041927/0361 →
SECURITY AGREEMENT Recorded Nov 7, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 031597/0857 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 031588/0825 →
SECURITY AGREEMENT Recorded Nov 5, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 031580/0121 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2013
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC., A CALIFORNIA CORPORATION
Reel/Frame 031560/0239 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2013
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC., A CALIFORNIA CORPORATION; DOLE FRESH FRUIT COMPANY, A NEVADA COMPANY; ROYAL PACKING LLC, A CALIFORNIA LIMITED LIABILITY COMPANY; DOLE BERRY COMPANY, A FLORIDA COMPANY; DOLE FRESH VEGETABLES, INC., A CALIFORNIA CORPORATION
Reel/Frame 031559/0711 →
SECURITY AGREEMENT Recorded Apr 3, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 030140/0571 →
CORRECTIVE ASSIGNMENT TO CORRECT THE FIRST ASSIGNOR NAME PREVIOUSLY RECORDED ON REEL 026903 FRAME 809.ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT Recorded Oct 5, 2011
From: DOLE FRESH VEGETABLES, INC.; DOLE FOOD COMPANY, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH
Reel/Frame 027024/0509 →
SECURITY AGREEMENT Recorded Sep 15, 2011
From: DOLE FRESH VEGETABLES, INC.; DOLE FOOD COMPANY, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH
Reel/Frame 026915/0652 →
SECURITY AGREEMENT Recorded Sep 14, 2011
From: DOLE FRESH VEGETABLE, INC.; DOLE FOOD COMPANY, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH
Reel/Frame 026903/0809 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 10, 2010
From: JOHNSON, THOMAS W.; DULL, BOB J.
To: DOLE FRESH VEGETABLES, INC.
Reel/Frame 025346/0412 →