Coated steel stamped product
The invention relates to a process for making a hot stamped coated steel sheet product, comprising the steps of pre-coating a steel strip or sheet with aluminum- or aluminum alloy, cutting said pre-coated steel strip or sheet to obtain a pre-coated steel blank, heating the blank in a furnace preheated to a temperature and during a time defined by diagram according to thickness, at a heating rate V c between 20 and 700° C. comprised between 4 and 12° C./s and at a heating rate V c ′ between 500 and 700° C. comprised between 1.5 and 6° C./s, to obtain a heated blank; then transferring said heated blank to a die, hot stamping the heated blank in the die obtain a hot stamped steel sheet product, cooling at a mean rate V r between the exit of the heated blank from the furnace, down to 400° C., of at least 30° C./s.
1. A coated steel stamped product, comprising:
a strip of base steel having a first side and a second side; and
a coating on at least one of said first side of said strip of base steel and said second side of said strip of base steel,
wherein said coating results from the interdiffusion between said base steel, and aluminum or aluminum alloy pre-coating, and
wherein said coating comprises, proceeding from the base steel outwards,
an Interdiffusion layer having a hardness HV50 g between 290 and 410 (HV50 g designating the hardness measured under a load of 50 grams),
an Intermediate layer having a hardness HV50 g between 810 and 1100,
an Intermetallic layer having a hardness HV50 g between 522 and 715, and
a Superficial layer having a hardness HV50 g between 810 and 1100, and
said entire coating comprises, in surfacic fraction, less than 10% of porosities.
2. The coated steel stamped product according to claim 1 , wherein said Superficial layer comprises, in surfacic fraction, less than 20% of porosities.
3. The coated steel stamped product according to claim 1 , wherein said coating has a thickness greater than 30 micrometers.
4. The coated steel stamped product according to claim 1 , wherein said Interdiffusion layer has a thickness less than 15 micrometers.
5. The coated steel stamped product according to claim 1 ,
wherein said Intermetallic layer occupies less than 10% of an extreme surface of said product.
6. The coated steel stamped product according to claim 1 wherein the steel composition in the strip of base steel comprises iron and the following components by weight based on total weight:
0.1%<carbon<0.5%;
0.5%<manganese<3%;
0.1%<silicon<1%;
0.01%<chromium<1%;
nickel<0.1%;
copper<0.1%;
titanium<0.2%;
phosphorus<0.1%;
sulfur<0.05%; and
0.0005%<boron<0.10%.
7. The coated steel stamped product according to claim 1 , wherein the steel composition in the strip of base steel comprises iron and the following components by weight based on total weight:
0.20%<carbon<0.5%;
0.8%<manganese<1.5%;
0.1%<silicon<0.35%;
0.01%<chromium<1%;
nickel<0.1%;
copper<0.1%;
titanium<0.1%;
aluminum<0.1%;
phosphorus<0.05%;
sulfur<0.03%; and
0.0005%<boron<0.01%.
8. The coated steel stamped product according to claim 1 , wherein the aluminum or aluminum alloy pre-coating comprises from 8% to 11% silicon by weight, and from 2% to 4% iron by weight.
9. The coated steel stamped product according to claim 1 , wherein
(a) the Interdiffusion layer comprises, by weight:
86-95% Fe,
4-10% Al, and
0-5% Si,
(b) the Intermediate layer comprises, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si,
(c) the Intermetallic layer comprises, by weight:
62-67% Fe,
30-34% Al, and
2-6% Si, and
(d) the Superficial layer comprises, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si.
10. A coated steel stamped product according to claim 1 , wherein said Interdiffusion layer comprises two sub layers.
11. A coated steel stamped product according to claim 1 , wherein
said Interdiffusion layer has a hardness HV50 g between 290 and 410,
said Intermediate layer has a hardness HV50 g between 900 and 1000,
said Intermetallic layer has a hardness HV50 g between 580 and 650, and
said Superficial layer has a hardness HV50 g between 900 and 1000.
12. The coated steel stamped product according to claim 1 , wherein
said coated stamped steel product has a thickness between 0.7 and 3 mm, and
said product is produced by a process comprising:
heating said product at a rate V c between 4 and 12° C./s where V c is the mean heating rate between 20 and 700° C.,
heating said product at a rate V c ′ between 1.5 and 6° C./s where V c ′ is the mean heating rate between 500 and 700° C., and
heating said product from 2 to 13 minutes, including heating time and holding time, to a temperature of 880 to 940° C.
13. A coated steel stamped product, comprising:
a strip of base steel; and
a coating on said strip of base steel, said coating comprising aluminum or aluminum alloy,
wherein said coating comprises, proceeding from the base steel outwards,
an Intermetallic layer having a hardness HV50 g between 522 and 715, and
a Superficial layer having a hardness HV50 g between 810 and 1100, and
said entire coating comprises, in surfacic fraction, less than 10% of porosities.
14. The coated steel stamped product according to claim 13 , wherein said coating has a thickness greater than 30 micrometers.
15. The coated steel stamped product according to claim 13 ,
wherein said Intermetallic layer occupies less then 10% of an extreme surface of said product.
16. The coated steel stamped product according to claim 13 , wherein said Superficial layer comprises, in surfacic fraction, less than 20% of porosities.
17. The coated steel stamped product according claim 13 , wherein
(a) the Intermetallic layer comprises, by weight:
62-67% Fe,
30-34% Al, and
2-6% Si, and
(b) the Superficial layer comprises, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si.
18. A coated steel stamped product, comprising:
a strip of base steel having a first side and a second side; and
a coating on at least one of said first side of said strip of base steel and said second side of said strip of base steel,
wherein said coating results from the interdiffusion between said base steel, and aluminum or aluminum alloy pre-coating, and
wherein said coating comprises, proceeding from the base steel outwards,
an Interdiffusion layer comprising, by weight:
86-95% Fe,
4-10% Al, and
0-5% Si,
an Intermediate layer comprising, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si,
an Intermetallic layer comprising, by weight:
62-67% Fe,
30-34% Al, and
2-6% Si, and
a Superficial layer comprising, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si, and
said entire coating comprises, in surfacic fraction, less than 10% of porosities.
19. The coated steel stamped product according to claim 18 , wherein said Superficial layer comprises, in surfacic fraction, less than 20% of porosities.
20. The coated steel stamped product according to claim 18 , wherein said coating has a thickness greater than 30 micrometers.
21. The coated steel stamped product according to claim 18 , wherein said Interdiffusion layer has a thickness less than 15 micrometers.
22. The coated steel stamped product according to claim 18 ,
wherein said Intermetallic layer occupies less than 10% of an extreme surface of said product.
23. The coated steel stamped product according to claim 18 , wherein the steel composition in the strip of base steel comprises iron and the following components by weight based on total weight:
0.1%<carbon<0.5%;
0.5%<manganese<3%;
0.1%<silicon<1%;
0.01%<chromium<1%;
nickel<0.1%;
copper<0.1%;
titanium<0.2%;
aluminum<0.1%;
phosphorus<0.1%;
sulfur<0.05%; and
0.0005%<boron<0.10%.
24. The coated steel stamped product according to claim 18 , wherein the steel composition in the strip of base steel comprises iron and the following components by weight based on total weight:
0.20%<carbon<0.5%;
0.8%<manganese<1.5%;
0.1%<silicon<0.35%;
0.01%<chromium<1%;
nickel<0.1%;
copper<0.1%;
titanium<0.1%;
aluminum<0.1%;
phosphorus<0.05%;
sulfur<0.03%; and
0.0005%<boron<0.01%.
25. The coated steel stamped product according to claim 18 , wherein the aluminum or aluminum alloy pre-coating comprises from 8% to 11% silicon by weight, and from 2% to 4% iron by weight.
26. A coated steel stamped product according to claim 18 , wherein said Interdiffusion layer comprises two sub layers.
27. A coated steel stamped product, comprising:
a strip of base steel; and
a coating on said strip of base steel, said coating comprising aluminum or aluminum alloy,
wherein said coating comprises, proceeding from the base steel outwards,
(a) an Intermetallic layer comprising, by weight:
62-67% Fe,
30-34% Al, and
2-6% Si, and
(b) a Superficial layer comprising, by weight:
39-47% Fe,
53-61% Al, and
0-2% Si, and
said entire coating comprises, in surfacic fraction, less than 10% of porosities.
28. The coated steel stamped product according to claim 27 , wherein said coating has a thickness greater than 30 micrometers.
29. The coated steel stamped product according to claim 27 ,
wherein said Intermetallic layer occupies less than 10% of an extreme surface of said product.
30. The coated steel stamped product according to claim 27 , wherein said Superficial layer comprises, in surfacic fraction, less than 20% of porosities.