Molding composition with reduced light scattering
The present invention relates to a molding composition comprising (A) a copolymer containing at least one α,β-unsaturated monocarbonitrile and at least one aromatic vinyl monomer, (B) a graft rubber with an average particle size of from 100 to 280 nm, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl monomer and of at least one α,β-unsaturated monocarbonitrile, (C) a graft rubber with an average particle size of from 410 to 1000 nm, composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl polymer and of at least one α,β-unsaturated monocarbonitrile, and wherein the ratio by weight of component (B) to component (C) is from 3:1 to 1:1. The invention also relates to the process of producing the molding composition and its use.
1. A molding composition comprising
(A) from 50 to 70% by weight of a copolymer comprising, as main units, at least one α,β-unsaturated monocarbonitrile in amounts of at least 30% by weight, based on the total weight of component (A), and at least one aromatic vinyl monomer, as component (A),
(B) from 20 to 30% by weight of a graft rubber with an average particle size of from 100 to 280 nm, comprising a graft base b 1 , composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell b 2 , composed of at least one aromatic vinyl monomer and of at least one α,β-unsaturated monocarbonitrile, as component (B),
(C) from 10 to 20% by weight of a graft rubber with an average particle size of from 410 to 1000 nm, comprising a graft base c 1 , composed of at least one α,β-unsaturated monocarboxylic ester, and at least one graft shell c 2 , composed of at least one aromatic vinyl polymer and of at least one α,β-unsaturated monocarbonitrile, as component (C), and
(D) from 0 to 10% by weight of additives, as component (D),
where the entirety of the amounts of components (A), (B), (C), and (D) is 100% by weight,
wherein
the ratio by weight of component (B) to component (C) is in the range from 3:1 to 1:1, and
the content of the α,β-unsaturated monocarbonitrile in component (B), in % by weight based on the total weight of the graft shell b 2 , and in component (C), in % by weight based on the total weight of the graft shell c 2 , is in each case from 5 to 10 percentage points below the content of α,β-unsaturated monocarbonitrile in component (A), in % by weight based on the total weight of component (A).
2. The molding composition according to claim 1 , wherein the particle size of the graft rubbers, averaged over all of the graft rubbers (B) and (C), is in the range from 280 to 320 nm.
3. The molding composition according to claim 1 , wherein component (A) comprises acrylonitrile as α,β-unsaturated monocarbonitrile, and styrene and/or α-methylstyrene as aromatic vinyl monomer.
4. The molding composition according to claim 2 , wherein component (A) comprises acrylonitrile as α,β-unsaturated monocarbonitrile, and styrene and/or α-methylstyrene as aromatic vinyl monomer.
5. The molding composition according to claim 1 , wherein, in components (B) and (C), the α,β-unsaturated monocarboxylic ester is an alkyl acrylate or alkyl methacrylate respectively derived from an alcohol having from 1 to 8 carbon atoms.
6. The molding composition according to claim 1 , wherein, in components (B) and (C), the aromatic vinyl monomer is styrene.
7. The molding composition according to claim 4 , wherein, in components (B) and (C), the aromatic vinyl monomer is styrene.
8. The molding composition according to claim 1 , wherein, in components (B) and (C), the α,β-unsaturated monocarbonitrile is acrylonitrile.
9. The molding composition according to claim 4 , wherein, in components (B) and (C), the α,β-unsaturated monocarbonitrile is acrylonitrile.
10. A process for producing the molding composition according to claim 1 , which comprises mixing, in the melt, components (A), (B), (C), and, if present, (D).
11. A foil, a molding, or a fiber, comprising the molding composition according to claim 1 .
12. A process for producing foils, moldings, or fibers which comprises processing the molding composition according to claim 1 .
13. The process according to claim 12 which comprises thermoforming, extruding, injection-molding, calendering, blow molding, pressing, or pressure-sintering the molding composition according to claim 10 .