Retardation compensators of negative C-type for liquid crystal display
Disclosed is a negative C-type retardation compensator for a liquid crystal display. The negative C-type retardation compensator for the liquid crystal display includes polyarylate having a thio group or a sulfur oxide group in a polymer main chain thereof. Accordingly, the retardation compensator has an absolute value of negative retardation that is larger in a thickness direction than a retardation compensator which includes polyarylate having no thio group or sulfur oxide group in a polymer main chain thereof even though the retardation compensator having the thio group or sulfur oxide group and the retardation compensator having no thio group or sulfur oxide group are the same as each other in thickness. Thereby, the negative C-type retardation compensator for liquid crystal displays is capable of being desirably applied to the liquid crystal displays.
1. A negative C-type retardation compensator for a liquid crystal display comprising:
1) a transparent base layer; and
2) a polyarylate coating layer which is layered on the transparent base layer and has a thio group or a sulfur oxide group in a polymer main chain thereof,
wherein the polyarylate having the thio group or the sulfur oxide group in the polymer main chain is represented by Formula 1:
wherein,
a, b, c, and d are each independently an integer of 0, or 1 to 4,
m and n are molar fractions, m+n=1, 0≦m≦1, and 0.001≦n≦0.4,
R 1 and R 2 are each independently a halogen, a nitrile group, a C 1 to C 12 alkoxy group, a C 6 to C 12 arylalkyl group, a C 6 to C 12 aryl group, or a C 1 to C 12 acyl group,
R 3 and R 4 are each independently a halogen, a nitrile group, a C 1 to C 12 alkyl group, a C 1 to C 12 alkoxy group, a C 6 to C 12 arylalkyl group, a C 6 to C 12 aryl group, or a C 1 to C 12 acyl group,
W 1 is a direct bond, a C 1 to C 30 alkylidene group, a C 2 to C 30 alkylene group, a C 3 to C 30 cycloalkylidene group, a C 3 to C 30 cycloalkylene group, a C 2 to C 30 phenyl-substituted alkylene group, a carbonyl group, NR, PO 2 , an oxygen, wherein R is a hydrogen, a C 1 to C 12 alkyl group, a C 6 to C 12 arylalkyl group, or a C 6 to C 12 aryl group,
W 2 is a thio group or a sulfur oxide group,
wherein in the polyarylate coating layer, a retardation in a thickness direction which is defined by Equation 1 is negative, and an absolute value of the retardation is 10 nm or more:
R
th
=
(
n
z
-
n
x
+
n
y
2
)
×
d
[
Equation
1
]
wherein,
n x is a refractive index which is the highest in a surface direction of the coating layer,
n y is the refractive index of the direction perpendicular to the direction of n x in the surface direction of the coating layer,
n z is the refractive index of the direction perpendicular to an n xy plane, and
d is a thickness of the coating layer.
2. The negative C-type retardation compensator for a liquid crystal display according to claim 1 , wherein W 2 of Formula 1 is the thio group, the sulfinyl group, or the sulfonyl group.
3. The negative C-type retardation compensator for a liquid crystal display according to claim 1 , wherein the polyarylate having the thio group or the sulfur oxide group in the polymer main chain thereof is produced by polycondensating aromatic diol and aromatic dicarboxylic acid, or aromatic diol and aromatic dicarboxylic acid halide.
4. The negative C-type retardation compensator for a liquid crystal display according to claim 3 , wherein the aromatic dicarboxylic acid or the aromatic dicarboxylic acid halide is selected from the group consisting of terephthalic acid, isophthalic acid, dibenzoic acid, naphthalene dicarboxylic acid, 4,4′-methylenebisbenzoic acid, 1,2-bis(4-hydroxycarbonylphenyl)ethane, 2,2-bis(4-hydroxycarbonylphenyl)propane, 4,4′-oxo-bis(benzoic acid), bis(4-hydroxycarbonylphenyl)sulfide, bis(4-hydroxycarbonylphenyl)sulfone, aromatic dicarboxylic acid in which aromatic groups thereof are substituted by a C 1 to C 2 alkyl group or a halogen group, and a mixture thereof.
5. The negative C-type retardation compensator for a liquid crystal display according to claim 3 , wherein the aromatic dicarboxylic acid or the aromatic dicarboxylic acid halide is a mixture of 10 to 90 mol % of terephthalic acid halide and 90 to 10 mol % of isophthalic acid halide.
6. The negative C-type retardation compensator for a liquid crystal display according to claim 3 , wherein the aromatic diol is one or more selected from the group consisting of bis(4-hydroxyphenyl)methane, 2,2-bis(4-hydroxyphenyl)propane (BPA), 2,2-bis(4-hydroxyphenyl)ethane, 2,2-bis(4-hydroxy-3-methylphenyl)propane, 2,2-bis(4-hydroxyphenyl)heptane, 2,2-bis(4-hydroxy-3,5-dichlorophenyl)propane, 2,2-bis(4-hydroxy-3,5-dibromophenyl)propane, bis(4-hydroxyphenyl)phenylmethane, 4,4-dihydroxyphenyl-1,1-m-diisopropylbenzene, 4,4-dihydroxyphenyl-9,9-fluorene, 2,2-bis(4-hydroxyphenyl)fluorene (BHPF), 9,9-bis(3,5-dimethyl-4-hydroxyphenyl)fluorene (BDMPF), 9,9-bis(3,5-dibromo-4-hydroxyphenyl)fluorene (BFBPF), 1,1-bis(4,4′-hydroxyphenyl)cyclopentane, 1,1-bis(4,4′-hydroxyphenyl)cyclohexane, 1-methyl-1-(4-hydroxyphenyl)-4-(dimethyl-4-hydroxyphenyl)cyclohexane, 4-{1-[3-(4-hydroxyphenyl)-4-methylcyclohexyl]-1-methylethyl}phenol, 4,4-[1-methyl-4-(1-methylethyl)-1,3-cyclohexylidyl]bisphenol, and 2,2,2,2-tetrahydro-3,3,3,3-tetramethyl-1,1-spirobis-[1H]-indene-6,6-diol.
7. The negative C-type retardation compensator for a liquid crystal display according to claim 1 , wherein the transparent base layer is a glass base layer.
8. The negative C-type retardation compensator for a liquid crystal display according to claim 1 , wherein the polyarylate coating layer is an unstretched film.
9. A liquid crystal display comprising:
the negative C-type retardation compensator for a liquid crystal display of claim 1 .