Method of modifying a surface of a nozzle of a liquid dispenser used for manufacturing a liquid crystal display

1. A method of modifying a surface of a nozzle of a liquid dispenser used to dispense liquid for manufacturing a liquid crystal display (LCD), the method comprising:

primarily modifying the surface of the nozzle by performing one of oxygen (O 2 ) or ozone (O 3 ) plasma treatment with respect to the surface of the nozzle;

secondarily modifying the primarily modified surface of the nozzle by treating the primarily modified surface with aminopropyltriethoxysilane; and

tertiary modifying the secondarily modified surface of the nozzle by allowing an epoxy resin to react with the secondarily modified surface of the nozzle.

2. The method of claim 1 , wherein the tertiary modified surface of the nozzle comprises an epoxy resin layer having a thickness of about 10 nm.

3. The method of claim 1 , wherein the tertiary modifying of the secondarily modified surface of the nozzle comprises dropping the epoxy resin on the secondarily modified surface of the nozzle.

4. The method of claim 1 , wherein the tertiary modifying of the secondarily modified surface of the nozzle comprises dipping the secondarily modified surface of the nozzle into the epoxy resin.

5. The method of claim 1 , wherein the epoxy resin comprises epoxy terminated silicone.

6. The method of claim 5 , wherein the epoxy terminated silicone comprises epoxy terminated polydimethylsiloxane.

7. The method of claim 6 , wherein the polydimethylsiloxane has an average molecular weight of about 500 to about 8000.

8. The method of claim 5 , wherein the epoxy terminated silicone comprises epoxy silane.

9. The method of claim 8 , wherein the epoxy silane comprises one selected from the group consisting of 3-(2,3-epoxyproxy)propyltrimethoxysilane, (3-glycydoxypropyl)triethoxysilane, 5,6-epoxyhexyltriethoxysilane, (3-glycydoxypropyl)methyldiethoxysilane, (3-glycydoxypropyl)methyldimethoxysilane, (3-grycydoxypropyl)dimethoxylethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltriethoxysilane, and 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane.

10. The method of claim 5 , wherein the nozzle comprises one of SUS (steel use stainless), tungsten compounds, or aluminum.

11. The method of claim 10 , wherein the nozzle has a bore in a range of about 150 μm to about 300 μm.

12. The method of claim 10 , wherein the liquid comprises at least one of liquid crystal, a sealant, or alignment solution used for manufacturing a liquid crystal display.

13. The method of claim 1 , wherein in the tertiary modifying step, the epoxy resin and an amine group formed on a surface of the nozzle from the secondarily modifying step react with one another, and the nozzle is maintained at temperature at about 70° to about 100° for about 4 hours to about 7 hours during the tertiary modifying step.

14. The method of claim 1 , wherein the plasma treatment injecting one of the O 2 or the O 3 is performed in a reaction chamber for about 30 seconds to about one minute by using a plasma injector while maintaining an internal pressure of the reaction chamber under about 50 mTorr to about 100 mTorr.

15. A method of forming a liquid crystal layer, the method comprising:

preparing a nozzle to drop liquid;

modifying a surface of the nozzle through the method according to claim 1 ;

mounting the nozzle having the modified surface on a liquid dispenser;

preparing liquid crystal;

preparing a substrate for a liquid crystal display; and

exhausting the liquid crystal on the substrate through the nozzle with the modified surface mounted on the liquid dispenser.

16. A method for manufacturing a Liquid Crystal Display (LCD), the method comprising:

modifying a surface of a nozzle of a liquid dispenser, the method including:

primarily modifying the surface of the nozzle by performing one of oxygen (O 2 ) or ozone (O 3 ) plasma treatment with respect to the surface of the nozzle,

secondarily modifying the primarily modified surface of the nozzle by treating the primarily modified surface with aminopropyltriethoxysilane, and

tertiary modifying the secondarily modified surface of the nozzle by allowing an epoxy resin to react with the secondarily modified surface of the nozzle;

installing the nozzle with the surface modified by the primarily, secondarily and tertiary modifying steps on a liquid dispenser to dispense a liquid comprising at least one of liquid crystal, a sealant and alignment solution;

forming gate lines, data lines, thin film transistors and pixel electrodes on a first substrate, wherein each thin film transistors is connected to a corresponding one of the gate lines and data lines and the pixel electrodes are connected to the thin film transistors;

forming a first alignment layer on the first substrate having the thin film transistors thereon and rubbing the first alignment layer;

dispensing liquid crystal on the first alignment layer;

forming color filters and a common electrode on a second substrate;

forming a second alignment layer on the second substrate having the color filters and the common electrode thereon and rubbing the second alignment layer;

applying a sealant to an outer portion of at least one of the first and second substrates;

combining the first and second substrates to each other by applying a pressure to the first and second substrates, thereby forming a liquid crystal layer between the combined first and second substrates;

processing the combined first and second substrates by cutting the combined first and second substrates; and

checking to determine whether there are any defects in the processed first and second substrates.

17. The method of claim 16 , wherein the dispensing of the liquid crystal on the first alignment layer is performed using the liquid dispenser having the nozzle with the surface modified by the primarily, secondarily and tertiary modifying steps.

18. The method of claim 16 , wherein the forming of at least one of the first and the second alignment layers is performed by dispensing the alignment solution using the liquid dispenser having the nozzle with the surface modified by the primarily, secondarily and tertiary modifying steps.

19. The method of claim 16 , wherein the applying of the sealant is performed by dispensing the sealant using the liquid dispenser having the nozzle with the surface modified by the primarily, secondarily and tertiary modifying steps.