High temperature-resistant article, method for producing the same, and high temperature-resistant adhesive
A method for producing a high temperature-resistant article comprises an assembling step of foaming an assembly of a first substrate and a second substrate with an adhesive layer interposed therebetween and comprising paste of powder of at least one carbide of niobium carbide, hafnium carbide, tantalum carbide and tungsten carbide; and a bonding step of heating the assembly to bond the first substrate and the second substrate by sintering, thereby obtaining a high temperature-resistant article comprising the assembly after sintering. Moreover, a method for producing a high temperature-resistant article comprises a coating step of coating a slurry comprising powder of at least one carbide of niobium carbide, hafnium carbide, tantalum carbide and tungsten carbide on a surface of a high temperature-resistant substrate; a drying step of drying the substrate after the coating step; and a film-forming step of heating the substrate after the drying step to form a carbide coating film on the surface of the substrate by sintering, thereby obtaining a high temperature-resistant article having the carbide coating film. A high temperature-resistant article of a complicated shape can be easily produced at low costs by these methods.
1. A method for producing an article, comprising:
a coating step of coating a slurry comprising a powder of at least one carbide selected from the group consisting of niobium carbide, hafnium carbide, tantalum carbide, and tungsten carbide on a surface of a substrate;
a drying step of drying the substrate after the coating step; and
a film-forming step of heating the substrate after the drying step to form a carbide coating film on the surface of the substrate by sintering at a temperature of 2,000 to 2,800° C.,
thereby obtaining an article having the carbide coating film, wherein
the article and the substrate are resistant to melting at temperatures of at least 2,000° C., and
the average particle diameter of the powder is 0.2 to 5 μm.
2. The method for producing an article according to claim 1 , wherein the slurry contains additive powder comprising a carbide of a transition metal or a transition metal having a melting point of not more than the sintering temperature in the film-forming step.
3. The method for producing an article according to claim 2 , wherein the transition metal is one selected from the group consisting of Ti, Cr, Fe, Co and Ni.
4. The method for producing an article according to claim 1 , wherein the slurry contains an organic binder.
5. The method for producing an article according to claim 1 , wherein the substrate is a graphite substrate or a boron nitride substrate.
6. The method for producing an article according to claim 1 , wherein the coating step is a spraying coating step of spraying the slurry onto the surface of the substrate or a spin coating step of pouring the slurry on the surface of the substrate spinning.
7. The method for producing an article according to claim 1 , wherein the carbide coating film has a thickness of 5 to 30 μm.
8. The method for producing an article according to claim 1 , wherein
the substrate is a graphite substrate having a thermal expansion coefficient of 5.5 to 8.8×10 −6 /K, and
the slurry is a tantalum carbide slurry comprising carbide powder containing tantalum carbide as a main component, and
the carbide coating film has a thickness of 30 to 200 μm.