Weatherable thermoplastic resin composition having excellent low gloss characteristic and method of preparing the same
The present invention provides a weather resistant thermoplastic resin with low gloss and a method of preparing the same. The thermoplastic resin of the present invention comprises a (meth)acrylic acid alkyl ester-based polymer (A) and a (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B), and an aromatic vinyl-cyanide vinyl based copolymer (C), wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase.
1. A weatherable thermoplastic resin composition comprising:
(A) a (meth)acrylic acid alkyl ester-based polymer;
(B) a (meth)acrylic acid alkyl ester-based oligomeric prepolymer, and
(C) an aromatic vinyl-cyanide vinyl based copolymer,
wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase, and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase, and
wherein said (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) is prepared by polymerizing a mixture comprising a mercapto compound having either two or more carboxyl groups or two or more hydroxyl groups and a (meth)acrylic acid alkyl ester monomer.
2. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester-based polymer (A) comprises a (meth)acrylic acid alkyl ester compound unit and an unsaturated hydroxy or carboxylic acid compound unit.
3. The weatherable thermoplastic resin composition of claim 2 , wherein said (meth)acrylic acid alkyl ester-based polymer (A) comprises about 60 to about 95% by weight of a (meth)acrylic acid alkyl ester compound unit; about 1 to about 20% by weight of an unsaturated hydroxy or carboxylic acid compound unit; about 0 to about 20% by weight of an aromatic vinyl-based compound; and about 0 to about 10% by weight of a vinyl cyanide based compound.
4. The weatherable thermoplastic resin composition of claim 1 , wherein the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) comprises a mole ratio of the mercapto compound having either two or more carboxyl groups or two or more hydroxyl groups to the (meth)acrylic acid alkyl ester monomer of about 24:76 to about 2.5: 97.5.
5. The weatherable thermoplastic resin composition of claim 2 , wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) are connected by ester-bonds between the unsaturated hydroxyl group or unsaturated carboxyl group of the (meth)acrylic acid alkyl ester-based polymer (A) and the carboxyl groups or hydroxyl groups of the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B).
6. The weatherable thermoplastic resin composition of claim 1 , wherein the aromatic vinyl-cyanide vinyl based copolymer (C) comprises about 60 to about 95% by weight of an aromatic vinyl-based compound, about 5 to about 40% by weight of a vinyl cyanide based compound, and about 0 to about 10% by weight of a (meth)acrylic acid alkyl ester.
7. The weatherable thermoplastic resin composition of claim 2 , comprising a weight ratio of the (meth)acrylic acid alkyl ester-based polymer (A) to the aromatic vinyl-cyanide vinyl based copolymer (C) of about 5:95 to about 35:65, and wherein the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) is present in an amount of an equivalent ratio of about 0.1 to about 3 based on the copolymerized unsaturated hydroxy or carboxylic acid compound of the (meth)acrylic acid alkyl ester-based polymer (A).
8. The weatherable thermoplastic resin composition of claim 2 , wherein said (meth)acrylic acid alkyl ester unit comprises methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, pentyl methacrylate, hexyl methacrylate, heptyl methacrylate, octyl methacrylate, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, pentyl acrylate, hexyl acrylate, heptyl acrylate, octyl acrylate, ethyl hexyl acrylate, or a combination thereof.
9. The weatherable thermoplastic resin composition of claim 2 , wherein said unsaturated hydroxy or carboxylic acid compound unit comprises hydroxyalkyl acrylate, hydroxyalkyl methacrylate, acrylic acid, methacrylic acid, maleic acid, maleic anhydride, fumaric acid, fumaric anhydride, or a combination thereof.
10. The weatherable thermoplastic resin composition of claim 1 , wherein said mercapto compound having either two or more carboxyl groups or two or more hydroxyl groups comprises mercapto propandiol, mercaptosuccinic acid, mercapto purinediol, mercapto triazinediol, or a combination thereof.
11. The weatherable thermoplastic resin composition of claim 6 , wherein said aromatic vinyl-based compound comprises styrene, a-methyl styrene, para-methyl styrene, or a combination thereof, and wherein said vinyl cyanide based compound comprises acrylonitrile, methacrylonitrile, ethacrylonitrile, or a combination thereof.
12. The weatherable thermoplastic resin composition of claim 1 , wherein said (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) has a number-average molecular weight of about 600 to about 7,000.
13. The weatherable thermoplastic resin composition of claim 1 , wherein said aromatic vinyl-cyanide vinyl based copolymer (C) has a weight-average molecular weight of about 150,000 to about 300,000.
14. The weatherable thermoplastic resin composition of claim 1 , wherein the thermoplastic resin has a gloss value of about 30 or less, measured using a 75 Degree BYK-Gardner Gloss Meter of an extruded sheet formed of the composition having a thickness of about 1 mm.