NdFeB sintered magnet and method for producing the same
The present invention is aimed at providing a method for producing an NdFeB sintered magnet having a higher coercivity and higher squareness of the magnetization curve than ever before. A method for producing an NdFeB sintered magnet according to the present invention includes the steps of forming a layer containing Dy and/or Tb on the surface of an NdFeB sintered magnet base material and then performing a grain boundary diffusion process for diffusing Dy and/or Tb from the aforementioned layer through the crystal grain boundaries of the magnet base material into the magnet base material by heating the magnet base material to a temperature equal to or lower than the sintering temperature thereof, and this method is characterized in that a) the content of a rare earth in a metallic state in the magnet base material is equal to or higher than 12.7 at %; b) the aforementioned layer is a powder layer formed by depositing a powder; and c) the powder layer contains Dy and/or Tb in a metallic state by an amount equal to or higher than 50 mass %.
1. A method for producing an NdFeB sintered magnet, including steps of forming a layer containing Dy and/or Tb on a surface of an NdFeB sintered magnet base material and then performing a grain boundary diffusion process for diffusing Dy and/or Tb from the aforementioned layer through crystal grain boundaries of the magnet base material into the magnet base material by heating the magnet base material to a temperature equal to or lower than a sintering temperature of the magnet base material, wherein:
a) a content of a rare earth in a metallic state in the magnet base material is equal to or higher than 12.7 at %;
b) the aforementioned layer is a powder layer formed by depositing a powder;
c) the powder layer contains 50 mass % or more Dy and/or Tb in a metallic state; and
d) the powder layer contains 1 mass % or more Al.
2. The method for producing an NdFeB sintered magnet according to claim 1 , wherein an amount of the powder layer on the surface the magnet base material is equal to or more than 7 mg per 1 cm 2 .
3. A method for producing an NdFeB sintered magnet, including steps of forming a layer containing Dy and/or Tb on a surface of an NdFeB sintered magnet base material and then performing a grain boundary diffusion process for diffusing Dy and/or Tb from the aforementioned layer through crystal grain boundaries of the magnet base material into the magnet base material by heating the magnet base material to a temperature equal to or lower than a sintering temperature of the magnet base material, wherein:
a) a content of a rare earth in a metallic state in the magnet base material is equal to or higher than 12.7 at %;
b) the aforementioned layer is a powder layer formed by depositing a powder;
c) the powder layer contains 50 mass % or more Dy and/or Tb in a metallic state; and
d) the powder layer contains 10 mass % or more Co and/or Ni in total.
4. The method for producing an NdFeB sintered magnet according to claim 3 , wherein the powder layer is melted during the grain boundary diffusion process.
5. The method for producing an NdFeB sintered magnet according to claim 1 , wherein the powder layer is melted during the grain boundary diffusion process.
6. The method for producing an NdFeB sintered magnet according to claim 3 , wherein an amount of the powder layer on the surface the magnet base material is equal to or more than 7 mg per 1 cm 2 .