Low-temperature sintered silver nanoparticle composition and electronic articles formed using the same
A silver nanoparticle composition is provided which is possible to be sintered through sintering at a low temperature in a short time and to form silver electro conductive film and wiring which is favorable for adhesion to a substrate and low in resistance, and articles using the same are provided. The silver nanoparticle composition is provided, wherein a main component of a solvent is water, a pH of the composition is within a range of 5.3 to 8.0, a silver nanoparticle included in the composition is protected by an organic acid or a derivative thereof, and the content of the organic acid or the derivative thereof with respect to silver is 2 to 20% by mass.
1. A silver nanoparticle composition, wherein a main component of a solvent is water, a pH of the composition is within a range of 5.3 to 8.0, a silver nanoparticle included in the composition is protected by an organic acid or a derivative thereof, and a content of the organic acid or the derivative thereof is within a range of 2 to 20% by mass with respect to silver, and the composition further comprising a polymer obtained by polymerizing a monomer having a vinyl group, wherein the polymer is selected from the group consisting of a vinyl chloride homopolymer, a vinyl chloride copolymer, a vinyl acetate homopolymer, and a vinyl acetate copolymer.
2. The silver nanoparticle composition according to claim 1 , wherein a content of the silver nanoparticle with respect to the entire content of the composition is within a range of 15 to 75% by mass.
3. The silver nanoparticle composition according to claim 1 , wherein a content of an ammonia component present in the composition with respect to the entire content of the composition is more than 0.1% by mass.
4. The silver nanoparticle composition according to claim 1 , wherein a content of a nitric acid component present in the composition with respect to the entire content of the composition is more than 0.1% by mass.
5. The silver nanoparticle composition according to claim 1 , wherein a primary particle average diameter of the silver nanoparticle to be measured by a transmission electron microscope is equal to or smaller than 100 nm.
6. The silver nanoparticle composition according to claim 1 , wherein the organic acid or the derivative thereof is a carboxylic acid having 5 to 8 carbon atoms or a derivative thereof.
7. The silver nanoparticle composition according to claim 1 , wherein the organic acid or the derivative thereof is heptanoic acid or a derivative thereof.
8. The silver nanoparticle composition according to claim 1 , comprising a polymer having a glass transition temperature (T g ) of 0° C. or higher and 100° C. or lower.
9. The silver nanoparticle composition according to claim 1 , comprising a water-dispersible polymer having at least one or more of an OH group, a polyoxyethylene glycol group, and a polyethylene glycol group.
10. The silver nanoparticle composition according to claim 9 , comprising a polymer having a urethane bond.
11. The silver nanoparticle composition according to claim 1 , wherein a surface resistivity of a silver thin film obtained by applying the silver nanoparticle composition according to claim 1 to a base material and subjecting it to heat treatment in air at 60° C. for 15 seconds is equal to or less than 100 Ω/square.
12. silver thin film or a silver wiring formed using the silver nanoparticle composition according to claim 1 .
13. An RF-ID antenna, wherein an antenna part of an RF-ID is formed from a silver wiring formed by applying the silver nanoparticle composition according to claim 1 to a base material and firing the wiring to be converted into silver.
14. An RF-ID inlet using the antenna according to claim 13 .
15. An EMI shield, wherein a grid part of the EMI shield is formed from a wiring which is a silver wiring formed by firing a wiring formed from the silver nanoparticle composition according to claim 1 to be converted into silver.
16. An electronic circuit, wherein a wiring formed by a printing method from the silver nanoparticle composition according to claim 1 is fired to be converted into silver and form a silver wiring.