Electrophotographic photoreceptor, image-forming apparatus, and electrophotographic cartridge
View Patent ↗When an abutting pressure of the cleaning blade on a photoreceptor is increased, a chattering occurs due to the so-called a stick-slip phenomenon that the blade repeatedly undergoes sticking to the outermost surface of the photoreceptor and slipping thereon. As a result, a possibility of noise generation becomes higher and there is a possibility that toner particles might pass through during slipping to cause a cleaning failure, resulting in a streaky image defect. There is also a higher possibility that the so-called a filming phenomenon might occur, in which a component of the toner sticks to the photoreceptor surface by the action of the blade pressure and becomes difficult to remove, so as to lead to persistent image defects. Furthermore, since the photoreceptor is rotated with toners in the state of being strongly pressed thereagainst, the image defects are apt to be caused due to peripheral-direction scratches. An electrophotographic photoreceptor is provided in which the outermost layer of the photoreceptor contains a specific charge-transporting material and a specific binder resin.
1. An electrophotographic photoreceptor, comprising:
(I) a charge-transporting layer comprising:
(A) a charge-transporting material of formula (I):
wherein:
R 1 is a phenyl group having one or two substituents;
R 2 is a hydrogen atom; and
R 3 and R 4 are each independently an unsubstituted phenyl group or a phenyl group substituted with a methyl group; and
(B) a copolymer binder resin of formula (4):
wherein m and n represent molar proportion, and m:n is from 90:10 to 45:55, and the copolymer binder resin of formula (4) has a weight average molecular weight of 40,000 to 100,000;
(II) a charge-generating layer comprising a charge-generating material; and
(III) a conductive substrate,
wherein the charge-transporting layer is the outermost layer.
2. The electrophotographic photoreceptor of claim 1 , wherein, in formula (4), m:n is from 85:15 to 45:55.
3. An image-forming apparatus, comprising the electrophotographic photoreceptor of claim 1 , wherein the image-forming apparatus comprises:
a charging unit, which charges the electrophotographic photoreceptor;
an exposure unit, which exposes the charged electrophotographic to light to form an electrostatic latent image;
a development unit, which develops the electrostatic latent image with a toner;
a transfer unit, which transfers the toner to a receiving object; and
a cleaning unit, which cleans a cleaning blade counter-abutting on the electrophotographic photoreceptor.
4. The image-forming apparatus of claim 3 , wherein the toner has an average degree of circularity, as determined with a flow particle image analyzer, of 0.930-1.000.
5. An electrophotographic cartridge, comprising:
the electrophotographic photoreceptor of claim 1 ;
a charging unit; and
a cleaning unit comprising a cleaning blade.
6. The electrophotographic photoreceptor of claim 1 , wherein, in formula (4), m:n is from 90:10 to 50:50.
7. The electrophotographic photoreceptor of claim 1 , wherein, in formula (4), m:n is from 85:15 to 50:50.
8. The electrophotographic photoreceptor of claim 1 , wherein, in formula (4), m:n is from 80:20 to 50:50.
9. The electrophotographic photoreceptor of claim 1 , wherein, in formula (4), m:n is from 80:20 to 67:33.
10. The electrophotographic photoreceptor of claim 1 , wherein, in formula (1), R 1 is a phenyl group substituted with a methyl group.
11. The electrophotographic photoreceptor of claim 10 , wherein, in formula (1), R 3 and R 4 are each an unsubstituted phenyl group.
12. The electrophotographic photoreceptor of claim 10 , wherein, in formula (1), R 3 and R 4 are each a phenyl group substituted with a methyl group.
13. The electrophotographic photoreceptor of claim 11 , wherein, in formula (4), m:n is from 90:10 to 67:33.
14. The electrophotographic photoreceptor of claim 12 , wherein, in formula (4), m:n is from 90:10 to 67:33.