Light-emitting element
To provide a light-emitting element with high emission efficiency or long lifetime, in which the use amount of a phosphorescent compound is small. To provide a light-emitting element including a light-emitting layer between a pair of electrodes, wherein the light-emitting layer includes a phosphorescent compound, a first organic compound, and a second organic compound, and the combination of the first organic compound and the second organic compound forms an exciplex. The light-emitting element transfers energy by utilizing the overlap between the emission spectrum of the exciplex and the absorption spectrum of the phosphorescent compound and thus has high energy transfer efficiency, even when the concentration of the phosphorescent compound is low.
1. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising:
a phosphorescent compound;
a first organic compound; and
a second organic compound,
wherein the first organic compound and the second organic compound are selected so that an exciplex is formed from the first organic compound and the second organic compound,
wherein the first organic compound and the second organic compound are selected so that an emission spectrum of the exciplex overlaps with an absorption band of the phosphorescent compound on the longest wavelength side, and
wherein the ratio of the weight of the phosphorescent compound to the total weight of the first organic compound and the second organic compound is from 0.1% to 2.5%.
2. The light-emitting element according to claim 1 , wherein the exciplex is formed by an interaction of a singlet exciton of the first organic compound with the second organic compound which is in a ground state.
3. The light-emitting element according to claim 1 , wherein the exciplex is formed from an anion of the first organic compound and a cation of the second organic compound.
4. The light-emitting element according to claim 1 , wherein excitation energy of the exciplex is transferred into the phosphorescent compound so that the phosphorescent compound emits phosphorescence.
5. The light-emitting element according to claim 1 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.
6. The light-emitting element according to claim 1 , wherein the phosphorescent compound is an organometallic complex.
7. The light-emitting element according to claim 6 , wherein the phosphorescent compound includes iridium.
8. The light-emitting element according to claim 1 , wherein a molar absorption coefficient of the phosphorescent compound at a peak of an emission spectrum of the exciplex is 5000M −1 cm −1 or more.
9. An electronic device comprising the light-emitting element according to claim 1 .
10. A lighting device comprising the light-emitting element according to claim 1 .
11. The light-emitting element according to claim 1 , wherein the first organic compound and the second organic compound are different organic compounds.
12. A light-emitting element comprising:
a pair of electrodes; and
an EL layer between the pair of electrodes, the EL layer comprising:
a hole-injection layer;
a hole-transport layer over the hole-injection layer;
a light-emitting layer comprising a phosphorescent compound, a first organic compound, and a second organic compound, over the hole-transport layer;
an electron-transport layer over the light-emitting layer; and
an electron-injection layer over the electron-transport layer,
wherein the first organic compound and the second organic compound are selected so that an exciplex is formed from the first organic compound and the second organic compound,
wherein the first organic compound and the second organic compound are selected so that an emission spectrum of the exciplex overlaps with an absorption band of the phosphorescent compound on the longest wavelength side, and
wherein the ratio of the weight of the phosphorescent compound to the total weight of the first organic compound and the second organic compound is from 0.1% to 2.5%.
13. A light-emitting element comprising:
a pair of electrodes;
a first EL layer;
a second EL layer; and
a charge-generation layer between the first EL layer and the second EL layer,
wherein the first EL layer, the second EL layer, and the charge-generation layer are stacked between the pair of electrodes,
wherein one of the first EL layer and the second EL layer comprises a phosphorescent compound, a first organic compound, and a second organic compound,
wherein the first organic compound and the second organic compound are selected so that an exciplex is formed from the first organic compound and the second organic compound,
wherein the first organic compound and the second organic compound are selected so that an emission spectrum of the exciplex overlaps with an absorption band of the phosphorescent compound on the longest wavelength side, and
wherein the ratio of the weight of the phosphorescent compound to the total weight of the first organic compound and the second organic compound is from 0.1% to 2.5%.