Process for the preparation of abs compositions having an improved surface after storage under warm moist conditions
View Patent ↗The present invention relates to a process for the preparation of compositions comprising vinyl aromatic copolymers prepared by the emulsion polymerisation process and having salt inclusions resulting from their preparation, which compositions are distinguished by an improved surface quality after storage under warm moist conditions and in that respect are suitable for the production of molded bodies having a class A surface.
1. A process for preparing a composition comprising:
A) from 0 to 98 parts by weight, based on the sum of A and B, of a thermoplastic polymer other than B or of a mixture of a plurality of thermoplastic polymers other than B, and
B) from 2 to 100 parts by weight, based on the sum of A and B, of
B1) at least one graft polymer prepared by an emulsion polymerisation process,
B2) optionally at least one graft polymer prepared by a mass, suspension and/or solution polymerisation process,
B3) optionally at least one rubber-free vinyl (co)polymer, and
C) from 0 to 30 parts by weight, based on the sum of A and B, of at least one polymer additive,
wherein the sum of the parts by weight of A and B is 100,
wherein
(i) component B comprises at least one inorganic salt comprising a cation selected from the group consisting of the alkali metals, alkaline earth metals and aluminium and an anion selected from the group consisting of chloride, sulfate, nitrate, phosphate, acetate and formate, in a concentration of from 100 to 5000 mg/kg, based on the total composition, and
a) in a first process step, the totality of the salt-containing component is treated completely with water by contacting said component with liquid water and/or with a water-vapour-containing atmosphere,
b) in a second process step, melting and kneading the component that has been treated with water, and
c) optionally in a third process step, mixing the component with remaining components of the composition, and melting and kneading the mixture, and thereby dispersing the components of the mixture in one another,
wherein at least in one of b) or c) a low pressure of at least 200 mbar is applied, and water introduced into the process in a) is thereby removed.
2. The process according to claim 1 , wherein exposure time of said salt-containing component B in a) to water and/or water vapour is at least 10 hours and not more than 500 hours.
3. The process according to claim 1 , wherein said salt-containing component B is in granulate form.
4. The process according to claim 1 , wherein in a) the totality of said salt-containing component is treated with water by a water-vapour-containing atmosphere comprising a relative humidity of at least 70%.
5. The process according to claim 1 , wherein treatment with liquid water takes place at a temperature range of from 5 to 95° C., and treatment with a water-vapour-containing atmosphere takes place at a temperature range of from 20 to 95° C.
6. The process according to claim 1 , wherein said salt-containing component B has a water content after treatment of from 0.10 to 1.8 wt.%, based on component B.
7. The process according to claim 1 , wherein said composition comprises:
A) from 30 to 85 parts by weight of said component A, based on the sum of A and B,
B) from 15 to 70 parts by weight of said component B, based on the sum of A and B,
C) from 0.3 to 7 parts by weight of said component C, based on the sum of A and B.
8. The process according to claim 1 , wherein said salt is an alkali, alkaline earth or aluminium chloride or an alkali, alkaline earth or aluminium sulfate, and/or a mixture thereof.
9. The process according to claim 1 , wherein said salt is magnesium sulfate.
10. The process according to of claim 1 , wherein treatment with a water-vapour-containing atmosphere takes place at a temperature of from 20 to 95° C. and at a relative humidity of at least 70%.
11. The process according to claim 1 , wherein said composition comprises as component C at least one selected from the group consisting of flameproofing agents, flameproofing synergists, smoke-inhibiting additives, antidripping agents, internal and external lubricants and demoulding agents, flowability aids, antistatics, conductivity additives, UV stabilisers, light stabilisers, heat stabilisers, antioxidants, transesterification inhibitors, hydrolytic stabilisers, additives comprising antibacterial action, additives that improve scratch resistance, IR absorbers, optical brighteners, fluorescent additives, fillers and reinforcing materials, acids, colourants and pigments.
12. The process according to claim 1 , wherein the totality of components A and C and residual amounts of component B are added to the composition in (b) and are dispersed in one another by kneading, and water introduced into said process in a) is removed by applying a low pressure of at least 200 mbar.
13. The process according to claim 1 , wherein said component B comprises at least two components selected from the group consisting of B1, B2 and B3.
14. A composition prepared by a process according to claim 1 .
15. A moulded body and/or moulding produced from a polymer composition prepared by a process of claim 1 comprising a class A surface and a partial or full high-gloss finish, wherein the gloss level in high-gloss regions is at least 95, determined in reflection according to DIN 67530 at a measuring angle of 60°, which can optionally be subjected partially or completely to a further surface treatment step optionally by, painting, in-mould decoration, metallisation by vacuum deposition and/or galvanisation.