Tyre, the inner wall of which is provided with a heat-expandable rubber layer
View Patent ↗A heat-expandable rubber layer is provided to an inner all of a pneumatic tire when the tire is in an uncured state. The rubber layer is expanded when the tire is in a vulcanized state. Once expanded, the rubber layer is capable of reducing rolling noises of the tire. The rubber layer includes an elastomer composition based on at least an elastomer, e.g., natural rubber or butyl rubber; a reinforcing filler, e.g., silica and/or carbon black; between 10 and 80 phr of a blowing agent, e.g., an azodicarbonamide compound; and between 10 and 50 phr of a hot-melt compound with a melting point between 70° C. and 150° C., e.g., urea. The combination of the blowing agent and the hot-melt compound, at recommended high contents, makes it possible to very greatly reduce an expansion ratio and therefore a thickness of the rubber layer once the pneumatic tire is vulcanized, without affecting noise absorption properties provided by the blowing agent.
1. A pneumatic tyre in an unvulcanized state, the tyre comprising:
an inner wall; and
a heat-expandable rubber layer positioned on the inner wall, the heat-expandable layer being formed of an elastomer composition including at least:
an elastomer,
a reinforcing filler,
between 20 and 80 phr of a blowing agent, and
between 10 and 50 phr of a hot-melt compound having a melting point between 70° C. and 150° C.
2. A pneumatic tyre according to claim 1 , wherein the elastomer is a diene elastomer selected from a group that includes natural rubbers, synthetic polyisoprenes, polybutadienes, butadiene copolymers, isoprene copolymers, and mixtures thereof.
3. A pneumatic tyre according to claim 2 , wherein the diene elastomer is 50 to 100 phr of a natural rubber or a synthetic polyisoprene.
4. A pneumatic tyre according to claim 2 , wherein the diene elastomer is 50 to 100 phr of butyl rubber.
5. A pneumatic tyre according to claim 1 , wherein the elastomer composition includes between 10 and 100 phr of the reinforcing filler.
6. A pneumatic tyre according to claim 5 , wherein the elastomer composition includes between 10 and 50 phr of the reinforcing filler.
7. A pneumatic tyre according to claim 1 , where the reinforcing filler includes silica or carbon black or a mixture of silica and carbon black.
8. A pneumatic tyre according to claim 1 , wherein the blowing agent is selected from a group of compounds that includes azos, nitrosos, hydrazines, carbazides, semicarbazides, tetrazoles, carbonates, citrates, and mixtures thereof.
9. A pneumatic tyre according to claim 8 , wherein the blowing agent is selected from a group of compounds that includes diazo, dinitroso, sulphonyl semicarbazide, sulphonyl hydrazide, and mixtures thereof.
10. A pneumatic tyre according to claim 9 , wherein the blowing agent is an azodicarbonamide compound.
11. A pneumatic tyre according to claim 1 , wherein the elastomer composition includes between 20 and 70 phr of the blowing agent.
12. A pneumatic tyre according to claim 1 , wherein an amount of the hot-melt compound in the elastomer composition is in a range of from 10 to 45 phr.
13. A pneumatic tyre according to claim 1 , wherein a total amount of the blowing agent and the hot-melt compound is between 30 and 115 phr.
14. A pneumatic tyre according to claim 1 , wherein the melting point of the hot-melt compound is between 100° C. and 150° C.
15. A pneumatic tyre according to claim 1 , wherein the hot-melt compound is urea or a hot-melt derivative of urea.
16. A pneumatic tyre according to claim 1 , wherein a density of the heat-expandable rubber layer is between 1.000 and 1.3000 g/cm 3 .
17. A pneumatic tyre according to claim 1 , wherein a thickness of the heat-expandable rubber layer is between 0.5 and 5 mm.
18. A pneumatic tyre in a vulcanized state obtained from curing an unvulcanized pneumatic tyre, wherein the unvulcanized pneumatic tyre includes:
an inner wall; and
a heat-expandable rubber layer positioned on the inner wall, the heat-expandable layer being formed of an elastomer composition including at least:
an elastomer,
a reinforcing filler,
between 20 and 80 phr of a blowing agent, and
between 10 and 50 phr of a hot-melt compound having a melting point between 70° C. and 150° C.
19. A pneumatic tyre according to claim 18 , wherein a density of the heat-expandable rubber layer, which has been expanded after the curing, is within a range of from 0.200 to 0.600 g/cm 3 .
20. A pneumatic tyre according to claim 18 , wherein a thickness of the heat-expandable rubber layer, which has been expanded after the curing, is between 2 and 20 mm.
21. A pneumatic tyre according to claim 18 , wherein a volume expansion ratio of the heat-expandable rubber layer, which has been expanded after the curing, is between 100% and 400%.