Method of producing low oxygen-content molybdenum powder by reducing molybdenum trioxide
Disclosed is a method of producing low oxygen-content molybdenum powders by reducing molybdenum trioxide, which includes charging a first reducing agent and the molybdenum trioxide, which are in the direct contact with each other on a micro-sieve on an upper portion of a bracket in a body, charging a second reducing agent in the bracket under the micro-sieve, coupling the body with a cover to close the body, and performing a reduction reaction by raising an internal temperature of the body by performing the first reduction reaction due to direct contact between the first reducing agent and the molybdenum trioxide, and performing the second reduction reaction due to evaporation of the second reducing agent. The first and second reduction reactions are performed at a temperature in a range of 550° C. to 650° C., and a temperature in a range of 1000° C. to 1200° C., respectively.
1. A method of producing molybdenum powders having a particle size of 5 μm or less and an oxygen content of 3000 ppm or less by reducing molybdenum trioxide, the method comprising:
charging a first reducing agent and the molybdenum trioxide on a micro-sieve, which is located on an upper portion of a bracket installed in a body, while the first reducing agent and the molybdenum trioxide are directly making contact with each other;
charging a second reducing agent in the bracket under the micro-sieve;
coupling the body with a cover to close the body; and
performing a reduction reaction by raising an internal temperature of the body,
wherein the first reducing agent and the second reducing agent comprise calcium powders, and the calcium powders constituting the first reducing agent have a particle size different from a particle size constituting the second reducing agent.
2. The method of claim 1 , wherein the first reducing agent is charged in a content of 25 parts by weight to 75 parts by weight based on 100 parts by weight of molybdenum trioxide powders, and the second reducing agent is charged in a content of 200 parts by weight to 300 parts by weight based on 100 parts by weight of the molybdenum trioxide powders.
3. The method of claim 1 , wherein the performing of the reduction reaction by raising the internal temperature of the body comprises:
performing a first reduction reaction due to direct contact between the first reducing agent and the molybdenum trioxide; and
performing a second reduction reaction due to evaporation of the second reducing agent.
4. The method of claim 3 , wherein the first reduction reaction is performed at a temperature in a range of 550° C. to 650° C., and the second reduction reaction is performed at a temperature in a range of 1000° C. to 1200° C.
5. The method of claim 4 , wherein a time to raise a temperature to a reduction temperature for the first and second reduction reactions is in a range of 30 minutes to two hours, and a time to maintain the first and second reduction reactions is in a range of one hour to three hours.