Marker composite and medical implant comprising an X-ray marker
A marker composite for medical implants composed of a biocorrodible metallic material and a medical implant comprising an X-ray marker which was made of the marker composite. The marker composite contains a large number of particles composed of a radio-opaque metal, which are embedded in an electrically non-conductive polymer. The particles have an additional electrically non-conductive coating.
1. A medical implant composed of a biocorrodible metallic material and comprising an X-ray marker which is composed of or is made of a marker composite comprising a plurality of particles of a radio-opaque metal, each individual particle coated with a coating selected from the group consisting of an oxide coating, a carbide coating, and a parylene coating such that the each of the plurality of particles are separated from one another by the coating, and wherein the coated particles are embedded in an electrically non-conductive polymer as a carrier matrix, wherein the carrier matrix is positioned between the biocorrodible metallic material and each of the plurality of coated particles to prevent contact between the biocorrodible metallic material and each of the plurality of coated particles.
2. The medical implant according to claim 1 , wherein the implant is a stent.
3. The medical implant according to claim 1 , wherein the biocorrodible metallic material is a magnesium alloy.
4. The medical implant according to claim 1 , wherein the X-ray marker is present in the form of a coating or a cavity filling.
5. The medical implant according to claim 1 , wherein the radio-opaque metal is composed of an element selected from the group consisting of gold, iridium, platinum, and tantalum.
6. The medical implant according to claim 5 , wherein the element is tantalum.
7. The medical implant according to claim 1 , wherein the coating is the oxide or carbide coating and is an oxide or carbide of the radio-opaque metal.
8. The medical implant according to claim 1 , wherein the polymer is selected from the group consisting of a polyurethane, a silicone, a poly(butyl methacrylate), a cyanoacrylate, and an epoxy resin.
9. A marker composite for a medical implant composed of a biocorrodible metallic material, wherein the marker composite comprises a plurality of individual particles suspended in an electrically non-conductive carrier matrix formed from a polymer, wherein each particle is of a radio-opaque metal individually coated with a coating selected from the group consisting of a carbide of the radio-opaque material, an oxide of the radio-opaque metal, and parylene, thereby preventing contact between the radio-opaque metal of different particles.
10. The marker composite according to claim 9 , wherein the carrier matrix provides a protective coating that prevents contact between each of the plurality of particles and the metallic material of the implant, and the radio-opaque metal is composed of an element selected from the group consisting of gold, iridium, platinum, and tantalum.
11. The marker composite according to claim 10 , wherein the radio-opaque metal is tantalum.
12. The marker composite according to claim 9 , wherein the polymer is selected from the group consisting of a polyurethane, a silicone, a poly(butyl methacrylate), a cyanoacrylate, and an epoxy resin.