IP Library Granted Patent US 8,999,032
Granted Patent B2
US 8,999,032 · App. 13/609,015 · Granted Apr 7, 2015

Application of carbon nanotubes on agglomerates of ore fines to increase the mechanical strength thereof

Inventors: Flavio de Castro Dutra (Belo Horizonte, BR); Hamilton Porto Pimenta (Belo Horizonte, BR); Valdirene Gonzaga De Resende (Belo Horizonte, BR); Aloísio Antônio de Melo Borges (Belo Horizonte, BR)
Assignee: Vale S.A.
B01J2/18C22B1/24C22B1/243Y10S977/702
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,999,032
App. No.
13/609,015
Granted
Apr 7, 2015
Kind
B2
Abstract

An application of carbon nanotubes on agglomerates of ore fines to increase the mechanical strength is provided. A process for the preparation of ore agglomerates having enhanced mechanical strength by the application of the carbon nanotubes is also provided.

Claims (27)

1. An agglomerate product comprising:

iron, nickel or manganese ore fines, or a mixture thereof; and

a binding agent comprising sodium silicate and carbon nanotubes;

wherein the agglomerate product has a mechanical strength higher than a corresponding agglomerate product without carbon nanotubes.

2. The agglomerate product of claim 1 , wherein the agglomerates of ore fines have an increase in mechanical strength of about 52% to 63% as compared to agglomerates of ore fines without carbon nanotubes.

3. A method of applying carbon nanotubes on agglomerates of ore fines to increase the mechanical strength, comprising:

dispersing carbon nanotubes into a matrix by mechanical mixing or by ultrasonic processing;

performing a mechanical mixture with the ore fines; and

agglomerating the mixture.

4. The method of claim 3 , wherein the agglomerates of ore fines have an increase in mechanical strength of about 52% to 63% as compared to agglomerates of ore fines without carbon nanotubes.

5. The method of claim 4 , wherein the agglomerates of ore fines are selected from a group consisting of iron ore fines, nickel ore fines, manganese ore fines and mixtures thereof.

6. A process for the preparation of ore agglomerates having high mechanical strength, comprising:

dispersing carbon nanotubes into a matrix to form a mixture;

preparing the mixture;

pelletizing or briquetting or extruding the mixture to form pellets or briquettes;

screening the formed pellets or briquettes;

drying the pellets or briquettes; and

screening the pellets or briquettes.

7. The process of claim 6 wherein the matrix comprises at least a binding agent.

8. The process of claim 7 wherein the binding agent comprises liquid sodium silicate.

9. The process of claim 7 wherein the matrix comprises additives including at least one of manioc, corn starch and micron silica.

10. The process of claim 6 wherein:

dispersing the carbon nanotubes is performed by mechanical mixtures or by using ultrasonic processor equipment,

pelletizing is performed by using a disc or drum, and

drying is performed in a conveyor belt furnace at temperatures between about 150 to 200.degree. C.

11. The process of claim 6 wherein the carbon nanotubes are incorporated in the matrix in proportions up to 5% by mass.

12. The process of claim 6 , wherein the ore agglomerates comprise a material selected from the group consisting of iron ore fines, nickel ore fines, manganese ore fines, and mixtures thereof.

Assignments (2)
CHANGE OF ADDRESS Recorded Sep 13, 2017
From: VALE S.A.
To: VALE S.A.
Reel/Frame 043849/0613 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 1, 2013
From: DUTRA, FLAVIO DE CASTRO; PIMENTA, HAMILTON PORTO; DE RESENDE, VALDIRENE GONZAGA; BORGES, ALOISIO ANTONIO DE MELO
To: VALE S.A.
Reel/Frame 029902/0967 →
Continuity (2)
Provisional Application 61532420 · Sep 8, 2011
Related Publication 20130243973A1 · Sep 19, 2013