Room temperature-curable polyorganosiloxane composition
View Patent ↗A room temperature-curable polyorganosiloxane composition is a two component-type room temperature-curable polyorganosiloxane composition including (A) a base composition and (B) a cross-linking agent composition. The component (A) contains (a1) polyorganosiloxane having a hydroxyl group or an alkoxy group at a molecular end and (a2) an inorganic filler. The component (B) includes (b1) an organosilicon compound having three or more hydrolyzable groups in one molecule, (b2) polyorganosiloxane having an alkoxy group at a molecular end and represented by the following general formula and, and (b3) a curing catalyst. In the two component-type room temperature-curable polyorganosiloxane composition, it is possible to appropriately adjust a compounding ratio of the base component and the cross-linking component according to the use of an automatic mixer/discharger or the like without deteriorating properties such as deep-part curability, curing uniformity, and storage stability.
1. A room temperature-curable polyorganosiloxane composition comprising:
(A) a base composition including: (a1) polyorganosiloxane having a hydroxyl group or an alkoxy group at a molecular end; and (a2) an inorganic filler; and
(B) a cross-linking agent composition including: (b1) an organosilicon compound having, in one molecule, three hydrolyzable groups or more combined with silicon atoms, or a partial hydrolysate of the organosilicon compound; (b2) polyorganosiloxane having an alkoxy group at a molecular end and represented by a general formula:
where R 1 's represent alkyl groups or alkoxyalkyl groups that are identical or different, and R 2 's and R 3 's both represent unsubstituted or halogen- or cyano group-substituted univalent hydrocarbon groups that are identical or different, Y represents an oxygen atom or an unsubstituted bivalent hydrocarbon group, a is 0 or 1, b is 0 or 1, and n is an integer of 1 to 30; and (b3) a curing catalyst including an organic compound containing a nitrogen atom,
wherein the base composition (A) contains the inorganic filler (a2) at a ratio of 1 to 500 parts by mass to 100 parts by mass of the component (a1), and the cross-linking agent composition (B) is compounded so that, to 100 parts by mass of the component (a1), the component (b2) is 0.5 to 20 parts by mass and the curing catalyst (b3) is 0.01 to 10 parts by mass, and the number of the alkoxy groups of the component (b1) per one piece of the hydroxyl group or the alkoxy group of the component (a1) is 2 to 20.
2. The room temperature-curable polyorganosiloxane composition according to claim 1 ,
wherein the component (a1) is polyorganosiloxane having the hydroxyl group at the molecular end.
3. The room temperature-curable polyorganosiloxane composition according to claim 1 ,
wherein (b3) the curing catalyst is an amino group-containing alkoxysilane represented by a general formula: (R 4 O) 3 Si—R 5 —NH—R 6 where R 4 's represent alkyl groups or alkoxyalkyl groups that are identical or different, R 5 represents an unsubstituted bivalent hydrocarbon group, and R 6 represents a hydrogen atom, or an unsubstituted or halogen- or cyano group-substituted univalent hydrocarbon group, or an aminoalkyl group.
4. The room temperature-curable polyorganosiloxane composition according to claim 1 ,
wherein the base composition (A) and the cross-linking agent composition (B) are compounded at a mass ratio of 100:3 to 100:20.
5. The room temperature-curable polyorganosiloxane composition according to claim 1 ,
wherein (b3) the curing catalyst includes at least one selected from diethylhydroxylamine, dimethylhydroxylamine, and guanidine derivatives.
6. The room temperature-curable polyorganosiloxane composition according to claim 5 ,
wherein (b3) the curing catalyst includes organotin compound and the guanidine derivative.