Osmotic separation systems and methods
Separation processes using osmotically driven membrane systems are disclosed generally involving the extraction of solvent from a first solution to concentrate solute by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources. Pre-treatment and post-treatment may also enhance the osmotically driven membrane processes.
1. A method of maximizing draw solute recovery in an osmotically driven membrane system, the method comprising the steps of:
providing a first osmotically driven membrane system comprising a forward osmosis membrane, the system configured for receiving a first solution comprising a solvent on a first side of the membrane and a concentrated draw solution on a second side of the membrane;
osmotically separating the solvent from the first solution with the concentrated draw solution via an osmotic concentration gradient across the membrane, thereby forming a second solution on the first side of the membrane and a dilute draw solution on the second side of the membrane, wherein the second solution comprises at least one first ionic species of solute via reverse ion exchange through the membrane;
recovering at least one draw solute and the solvent from the dilute draw solution, wherein the recovered solvent comprises at least one second ionic species of solute;
recycling the recovered at least one draw solute to the first osmotically driven membrane system;
providing a second osmotically driven membrane system comprising a reverse osmosis membrane;
pressurizing the recovered solvent in the second osmotically driven membrane system to recover a substantially pure solvent and a concentrated solution comprising the at least one second ionic species of solute;
recycling the concentrated solution comprising the at least one second ionic species of solute to the first osmotically driven membrane system, wherein the concentrated solution is added to the first solution, thereby resulting in the second solution comprising the at least one first ionic species of solute and the at least one second ionic species of solute;
ionically balancing the at least one first species of solute with the at least one second species of solute to form additional removable draw solutes; and
recovering the additional draw solutes and a third solution from the second solution.
2. The method of claim 1 further comprising the step of recycling the additional draw solutes into the concentrated draw solution.
3. The method of claim 1 , wherein the step of recovering at least one draw solute and the solvent from the dilute draw solution comprises distillation.
4. The method of claim 1 , wherein the concentrated draw solution comprises ammonia and carbon dioxide in a molar ratio of at least 1:1.
5. A system for osmotic extraction of a solvent from a first solution, comprising:
a forward osmosis system comprising:
a first chamber having an inlet fluidly connected to a source of the first solution comprising the solvent;
a second chamber having an inlet fluidly connected to a source of a concentrated draw solution, the concentrated draw solution having an osmotic concentration greater than the first solution; and
a semi-permeable membrane separating the first chamber from the second chamber, wherein the greater osmotic concentration causes separation of the first solution and the formation of a dilute draw solution in the second chamber and a concentrated first solution comprising at least one first ionic species of solute in the first chamber;
a first separation system fluidly coupled to the forward osmosis system downstream of the second chamber and configured to receive the dilute draw solution therefrom and to separate the dilute draw solution into draw solutes and a solvent stream comprising the solvent from the first solution and at least one second ionic species of solute;
a pressure exchanger fluidly coupled to the separation system and configured to pressurize and transport the solvent stream;
a reverse osmosis system fluidly coupled to the pressure exchanger and comprising:
a first chamber configured for receiving the pressurized solvent stream;
a semi-permeable reverse osmosis membrane coupled to the first chamber; and
a second chamber coupled to the semi-permeable reverse osmosis membrane and configured for receiving a solvent fluxed through the reverse osmosis membrane, wherein the first chamber of the reverse osmosis system is fluidly coupled to the first chamber of the forward osmosis system to provide reverse osmosis concentrate comprising a concentrated solvent stream and the at least one second ionic species of solute to the first chamber of the forward osmosis system as at least a portion of the first solution, wherein the at least one second ionic species of solute ionically balances with the at least one first ionic species of solute to form additional draw solutes in the first chamber of the forward osmosis system;
a second separation system fluidly coupled to the first chamber of the forward osmosis system and configured for receiving the concentrated first solution and the additional draw solutes therefrom and removing at least one of the additional draw solutes and a product stream from the concentrated first solution; and
a first recycling system in fluid communication with the second separation system for returning the additional draw solutes to the concentrated draw solution.
6. The system of claim 5 , wherein the concentrated draw solution comprises ammonia and carbon dioxide in a molar ratio of at least one to one.
7. The system of claim 5 , wherein at least one of the first and second separation systems comprises at least one of a distillation column or a contact membrane.
8. The method of claim 1 , wherein the at least one first ionic species of solute comprises NH 4 + .
9. The method of claim 1 , wherein the at least one second ionic species of solute comprises at least one of Na + or CO 3 − .
10. The method of claim 1 further comprising the step of introducing a plurality of seeds to the first side of the forward osmosis membrane.
11. The method of claim 1 , wherein the step of recycling the recovered at least one draw solute comprises mechanical vapor recompression of the recovered at least one draw solute.
12. The system of claim 5 , wherein the at least one first ionic species of solute comprises NH 4 + .
13. The system of claim 5 , wherein the at least one second ionic species of solute comprises at least one of Na + or CO 3 − .
14. The system of claim 5 further comprising means for introducing a plurality of seeds to the first chamber.
15. The system of claim 5 further comprising a second recycling system in fluid communication with the first separation system for returning the separated draw solutes to the forward osmosis system.
16. The system of claim 15 , wherein at least one of the first and second recycling systems comprises a compressor.