Polycarbonate-polysiloxane copolymer, and method for preparing same
A polycarbonate-polysiloxane copolymer includes a polysiloxane unit. The polycarbonate-polysiloxane copolymer can have superior melt flowability and ductility while maintaining high transparency and low haze.
1. A polycarbonate-polysiloxane copolymer comprising a polysiloxane unit represented by Formula 1:
wherein:
R 1 and R 2 are the same or different and are each independently C 1 -C 10 alkyl, C 6 -C 18 aryl, halogenated C 1 -C 10 alkyl, alkoxylated C 1 -C 10 alkyl, halogenated C 6 -C 18 aryl or alkoxylated C 6 -C 18 aryl,
each X is the same or different and each is independently C 6 -C 20 alkylene, and
n is an integer from 20 to 100.
2. The polycarbonate-polysiloxane copolymer according to claim 1 , wherein the polysiloxane unit is present in an amount about 0.1 to about 20.0% by weight, based on the total weight of the polycarbonate-polysiloxane copolymer.
3. The polycarbonate-polysiloxane copolymer according to claim 1 , wherein the polycarbonate-polysiloxane copolymer has a haze of about 8% or less and a transmittance of about 75% or more as measured at a thickness of 3 mm, a ⅛″ Izod impact strength of about 70 kgf·cm/cm or more as measured at room temperature by ASTM D256, and a ⅛″ Izod impact strength of about 55 kgf·cm/cm or more as measured at −30 ° C. by ASTM D256.
4. The polycarbonate-polysiloxane copolymer according to claim 1 , wherein each X in Formula 1 is independently C 8 -C 20 alkylene.
5. The polycarbonate-polysiloxane copolymer according to claim 1 , wherein each X in Formula 1 is independently C 12 -C 20 alkylene.
6. The polycarbonate-polysiloxane copolymer according to claim 1 , wherein the polycarbonate-polysiloxane copolymer has a tensile strength retention of about 88.0% to about 99.0% after measuring changes in tensile strength of an ASTM No.1 dumb-bell specimen after dipping in gasoline for 7 days.
7. The polycarbonate-polysiloxane copolymer according to claim 6 , wherein the polycarbonate-polysiloxane copolymer has a ⅛″ Izod impact strength of 59.9 kg·cm/cm or more as measured at −30 ° C. by ASTM D256.
8. A method for preparing a polycarbonate-polysiloxane copolymer, comprising adding an aromatic dihydroxy compound and phosgene to a polysiloxane represented by Formula 2:
wherein:
R 1 and R 2 are the same or different and are each independently C 1 -C 10 alkyl, C 6 -C 18 aryl, halogenated C 1 -C 10 alkyl, alkoxylated C 1 -C 10 alkyl, halogenated C 6 -C 18 aryl, or alkoxylated C 6 -C 18 aryl,
each X is the same or different and each is independently C 6 -C 20 alkylene or C 6 -C 18 arylene, and
n is an integer from 20 to 100, and
polymerizing the mixture.
9. The method according to claim 8 , wherein the aromatic dihydroxy compound is added in an amount of about 80.0 to about 99.9 parts by weight with respect to about 0.1 to about 20.0 parts by weight of the polysiloxane.
10. The method according to claim 8 , wherein the aromatic dihydroxy compound and the phosgene are added in two divided portions.
11. The method according to claim 8 , wherein each X in Formula 2 is independently C 6 -C 20 alkylene.
12. The method according to claim 8 , wherein each X in Formula 2 is independently C 8 -C 20 alkylene.
13. The method according to claim 8 , wherein each X in Formula 2 is independently C 12 -C 20 alkylene.