Multilayered body for medical containers and medical container
The present invention provides a multilayered body for medical containers, in which the innermost layer formed from a cyclic polyolefin exhibits favorable adhesion to another layer without using an adhesive, which exhibits excellent heat resistance, and which provides favorable blocking resistance when formed as a film, as well as a medical container formed from this multilayered body for medical containers, which suffers minimal deterioration in properties such as transparency and peel strength even when subjected to sterilization with high-pressure steam or the like.
1. A multilayered body for medical containers used in forming a medical container, comprising at least
an innermost layer composed of a cyclic polyolefin,
an intermediate layer which is formed adjacently to said innermost layer and comprises, as a main component, a linear low-density polyethylene produced using a single-site catalyst, and
an outermost layer containing a high-density polyethylene,
wherein said cyclic polyolefin is a hydrogenated product of a ring-opening polymer of a cyclic olefin monomer and the body has a total thickness within a range from 60 to 1,000 μm, and is composed of three layers consisting of said innermost layer having a thickness of 5 to 100 μm, said intermediate layer, and said outermost layer having a thickness of 5 to 100 μm.
2. The multilayered body for medical containers according to claim 1 , wherein a density of said linear low-density polyethylene is not less than 0.860 g/cm 3 but less than 0.940 g/cm 3 .
3. The multilayered body for medical containers according to claim 1 , wherein a density of said high-density polyethylene is within a range from 0.940 to 0.970 g/cm 3 .
4. The multilayered body for medical containers according to claim 1 , wherein said outermost layer is a mixture of said high-density polyethylene and a high-pressure low-density polyethylene.
5. The multilayered body for medical containers according to claim 1 , wherein said outermost layer is composed solely of said high-density polyethylene.
6. A medical container comprising a holding portion for holding a medical fluid, wherein at least said holding portion is formed from a multilayered body for medical containers according to claim 1 .
7. The medical container according to claim 6 , wherein said multilayered body for medical containers is a blow-molded body.
8. The medical container according to claim 6 , wherein said multilayered body for medical containers is a film, and said holding portion is prepared by hot-plate molding of said film.
9. The medical container according to claim 6 , wherein said multilayered body for medical containers is a film, and said holding portion is prepared by forming said film as a bag.
10. The multilayered body for medical containers according to claim 1 , wherein said innermost layer consists of a cyclic polyolefin.
11. The multilayered body for medical containers according to claim 1 , wherein the intermediate layer comprises a linear low-density polyethylene produced using a single-site catalyst in an amount of at least 50% by weight.
12. The multilayered body for medical containers according to claim 1 , wherein the intermediate layer comprises a linear low-density polyethylene produced using a single-site catalyst in an amount of at least 65% by weight.
13. The multilayered body for medical containers according to claim 1 , wherein said intermediate layer comprises said linear low-density polyethylene produced using a single-site catalyst in an amount of at least 80% by weight.
14. The multilayered body for medical containers according to claim 1 , wherein said outermost layer comprises said high-density polyethylene in an amount of at least 70% by weight.
15. The multilayered body for medical containers according to claim 1 , wherein the glass transition temperature of the cyclic polyolefin is within a range from 70 to 180° C.
16. The multilayered body for medical containers according to claim 1 , wherein the glass transition temperature of the cyclic polyolefin is within a range from 100 to 140° C.
17. The multilayered body for medical containers according to claim 1 , wherein a density of said linear low-density polyethylene is within a range from 0.900 to 0.917 g/cm 3 .
18. The multilayered body for medical containers according to claim 1 , wherein the intermediate layer further comprises a high-density polyethylene.
19. The multilayered body for medical containers according to claim 1 , wherein the multilayered body consists of the innermost layer, the intermediate layer, and the outermost layer.