Acrylic pressure-sensitive adhesive composition for polarizing film
The present invention relates to an acrylic pressure sensitive adhesive composition comprising (meth)acrylic copolymers including alkyl(meth)acrylic acid ester monomer having 1˜12 carbon atoms of alkyl group, characterized in that the gel content is 10˜55%, the swelling ratio is 30˜110, the weight average molecular weight of sol eluted from the adhesive by ethyl acetate is at least 800,000, the molecular weight distribution is 2.0˜7.0; and a polarizer and a liquid crystal display comprising the above composition show excellent durability under a high temperature and humidity condition, and can improve the light leakage phenomenon and provide excellent operability at the time of manufacturing polarizer by effectively providing high modulus and stress release property.
1. An acrylic pressure sensitive adhesive composition for polarizing film comprising (meth)acrylic copolymers including alkyl(meth)acrylic acid ester monomer having 1 to 12 carbon atoms of alkyl group and a multifunctional crosslinking agent,
wherein the meth(acrylic) copolymers comprise an acrylic polymer for crosslinking structure and an acrylic polymer for non-crosslinking structure,
wherein the meth(acrylic) copolymers and the multifunctional crosslinking agent form a pressure sensitive adhesive composition including a compact crosslinking structure and a free polymer having no crosslinking structure by a crosslinking reaction, the free polymer having no crosslinking structure being the acrylic polymer for non-crosslinking structure, the crosslinking structure being defined by the gel content represented by the following formula (1) of 21 to 33% and the swelling ration represented by the following formula (2) of 60 to 105,
wherein the free polymer having no crosslinking structure has the weight average molecular weight of 1,250,000 to 1,720,000, wherein the free polymer has the ratio of weight average molecular weight and number average molecular weight of 3 to 5.5,
wherein the acrylic polymer for non-crosslinking structure has no crosslinkable functional group:
gel content(%)=B/A×100 (1)
swelling ratio=C/B (2)
wherein A represents the weight of the pressure sensitive adhesive composition including the crosslinking structure and the free polymer, B represents the dry weight of insoluble content of the pressure sensitive adhesive composition including the crosslinking structure and the free polymer after dipping in ethyl acetate at ambient temperature for 48 hours, and C represents the weight of insoluble content which is swollen by ethyl acetate after dipping in ethyl acetate at ambient temperature for 48 hours (weight of insoluble content of pressure sensitive adhesive composition including the crosslinking structure and the free polymer + weight of permeated solvent), and
wherein the gel content and swelling ratio satisfy the following formula (3):
−2.83 x+ 130 ≦y≦− 2.83 x+ 180 (3)
wherein x represents gel content, and y represents swelling ratio.
2. The acrylic pressure sensitive adhesive composition for polarizing film of claim 1 , wherein the (meth)acrylic copolymers comprise 80 to 99.8 parts by weight of (meth)acrylic acid ester monomers having 2 to 12 carbon atoms of alkyl group and 0.01 to 5 parts by weight of vinyl and/or acrylic cross-linkable monomers having carboxyl group or hydroxy group which is cross-linkable with multifunctional crosslinking agent.
3. The acrylic pressure sensitive adhesive composition for polarizing film of claim 2 , wherein the (meth)acrylic acid ester monomers are one or more selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl (meth)acrylate, sec-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, isononyl (meth)acrylate, lauryl (meth)acrylate.
4. The acrylic pressure sensitive adhesive composition for polarizing film of claim 2 , wherein the cross-linkable monomers are one or more selected from the group consisting of 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate,4-hydroxybutyl (meth)acrylate, 2-hydroxyethyleneglycol (meth)acrylate, 2-hydroxypropyleneglycol (meth)acrylate, acrylic acid, methacrylic acid, acrylic acid dimer, itaconic acid, maleic acid, and maleic anhydride.
5. The acrylic pressure sensitive adhesive composition for polarizing film of claim 2 , wherein the,(meth)acrylic copolymers further comprise 20 or less parts by weight of copolymerizable vinyl monomers.
6. The acrylic pressure sensitive adhesive composition for polarizing film of claim 1 , wherein the multifunctional crosslinking agent is one or more selected from the group consisting of isocyanate, epoxy, aziridine and metal chelate compounds.
7. The acrylic pressure sensitive adhesive composition for polarizing film of claim 1 , wherein the composition further comprises 0.05 to 5 parts by weight of silane coupling agent, 1 to 100 parts by weight of tackifier, based on 100 parts by weight of the (meth)acrylic copolymers.
8. The acrylic pressure sensitive adhesive composition for polarizing film of claim 1 , wherein the composition further comprises one or more additives selected from the group consisting of plasticizer, epoxy resins, curing agent, UV stabilizers, antioxidants, coloring agents,reinforcing agents, fillers, antifoaming agents, and surfactants.