Silica crucible for pulling silicon single crystal and method of producing the same
There is provided a silica crucible for pulling a silicon single crystal, comprising silica glass and having a two-layer structure of an outer layer and an inner layer, wherein the inner layer, in a sectional side view of the crucible, has a wavy inner surface shape having mountain parts and valley parts at least between a start position and an end position for the pulling of a silicon single crystal in a silicon melt surface, and when a distance from an upper opening end of the crucible to the start position for the pulling of the silicon single crystal is 100, only a crucible portion from the upper opening end to a position within a range of 40 to 100 is crystalline.
1. A silica crucible for pulling a silicon single crystal, comprising silica glass and having a two-layer structure of an outer layer and an inner layer,
wherein when a height position of the bottom of the crucible is 0 and a height position of the upper opening end of the crucible is 100 in a sectional side view of the crucible, the start position for the pulling of the silicon single crystal is within a height position range of 50 to 95 from the bottom of the crucible and the end position for the pulling of the silicon single crystal is within a height position range of 0 to 10 from the bottom of the crucible,
wherein the inner layer, in a sectional side view of the crucible, has a wavy inner surface shape having mountain parts and valley parts at least between the start position and the end position for the pulling of a silicon single crystal in a silicon melt surface,
the wavy inner surface shape is formed of an amorphous structure, and
when a distance from an upper opening end of the crucible to the start position for the pulling of the silicon single crystal is 100, only a crucible portion from the upper opening end to a position within a range of 40 to 100 is crystalline, and
wherein the crucible portion from the upper opening end to the position within the range of 40 to 100 does not have a crystallization promoter.
2. A silica crucible for pulling a silicon single crystal according to claim 1 , wherein the inner layer has such an inner surface shape that a distance between a top position of the mountain part and a deepest position of the valley part is 0.1 to 3 mm and a distance between tops of the mountain parts is 10 to 100 mm.
3. A method of producing a silica crucible for pulling a silicon single crystal according to claim 2 , wherein a crystalline structure of a crystalline portion of the crucible is formed by melt-molding the silica crucible at a state provided with a ring-shaped cutoff portion containing 0.01-1 mass % of a crystallization promoter and extending upward from an upper opening end of the crucible.
4. A method of producing a silica crucible for pulling a silicon single crystal according to claim 1 , wherein a crystalline structure of a crystalline portion of the crucible is formed by melt-molding the silica crucible at a state provided with a ring-shaped cutoff portion containing 0.01-1 mass % of a crystallization promoter and extending upward from an upper opening end of the crucible.
5. A method of producing a silica crucible for pulling a silicon single crystal according to claim 4 , wherein the crystallization promoter is at least one of aluminum oxide, calcium oxide, barium oxide, calcium carbonate and barium carbonate.