Mass transfer apparatus and method for separation of gases
View Patent ↗A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.
1. A separation apparatus comprising a mass transfer stage that has an upper end and a lower end, the mass transfer stage including:
a gas injector module at the upper end of the mass transfer stage, the gas injector module including a first inlet for supplying a gaseous flow into the mass transfer stage, the gaseous flow being supplied into the gas injector module in the form of bubbles, the gas injector module including a second inlet at the upper end of the mass transfer stage for supplying an aqueous liquid flow into the gas injector module;
a gas absorption module that is downstream of and adjacent to the gas injector module and proximal to the lower end of the mass transfer stage as compared to the gas injector module such that liquid flow out of the gas injector module flows into the gas absorption module;
a gas separation module that is downstream of and adjacent to the gas absorption module and is at the lower end of the mass transfer stage such that liquid flow out of the gas absorption module flows into the gas separation module, the gas separation module including a gas trap, a first outlet in fluid communication with the gas trap, and a second outlet for aqueous liquid flow out of the mass transfer stage; and
a return line in fluid communication with the second outlet of the gas separation module, the return line including a gas trap.
2. The separation apparatus of claim 1 , comprising a second mass transfer stage including a gas injection module, a gas absorption module, and a gas separation module.
3. The separation apparatus of claim 2 , wherein the second mass transfer stage is adjacent to the first mass transfer stage such that an aqueous liquid flow out of the gas separation module of the second mass transfer stage flows into the gas injection module of the first mass transfer stage.
4. The separation apparatus of claim 3 , wherein the first outlet of the gas separation module of the first mass transfer stage directly feeds to a gas net of the gas injection module of the second mass transfer stage.
5. The separation apparatus of claim 2 , further comprising one or more additional mass transfer stages, each mass transfer stage including a gas injection module, a gas absorption module, and a gas separation module.
6. The separation apparatus of claim 5 , comprising about 10 or more mass transfer stages.
7. The separation apparatus of claim 1 , the mass transfer stage including a surrounding wall, the surround wall having a construction to withstand a pressure of about 1000 pounds per square inch or more.
8. The separation apparatus of claim 1 , the return line including an upper end, the upper end of the return line being in fluid communication with the second inlet of the gas injector module at the upper end of the mass transfer stage.
9. A system for separating gases from one another, the system comprising:
a compressor;
a flow line extending from a water or land surface to a depth of about 1000 feet or more;
a gas separation apparatus within the flow line, the gas separation apparatus comprising a plurality of mass transfer stages in series with one another and including a top-most mass transfer stage and a bottom-most mass transfer stage, each mass transfer stage including
a gas injector module at the upper end of the mass transfer stage, the gas injector module including a first inlet for supplying a gaseous flow into the mass transfer stage, the gaseous flow being supplied into the gas injector module in the form of bubbles, the gas injector module including a second inlet at the upper end of the mass transfer stage for supplying an aqueous flow into the gas injector module;
a gas absorption module that is downstream of and adjacent to the gas injector module and proximal to the lower end of the mass transfer stage as compared to the gas injector module such that liquid flow out of the gas injector module flows into the gas absorption module;
a gas separation module that is downstream of and adjacent to the gas absorption module and is at the lower end of the mass transfer stage such that liquid flow out of the gas absorption module flows into the gas separation module, the gas separation module including a gas trap, a first outlet in fluid communication with the gas trap, and a second outlet for aqueous flow out of the mass transfer stage; and
a first gas supply line extending from the compressor to the first inlet of the gas injector module of the bottom-most mass transfer stage; wherein
every mass transfer stage of the gas separation apparatus is paired with another mass transfer stage of the gas separation apparatus such that the first outlet of the gas separation module of the lower mass transfer stage of the pair is in fluid communication with the first inlet of the gas injector module of the upper mass transfer stage of the pair.
10. The system of claim 9 , further comprising a return line in fluid communication with the second outlet of the gas separation module of the bottom-most mass transfer stage.
11. The system of claim 10 , further comprising one or more gas traps on the return line.