Exhaust-gas treatment apparatus and exhaust-gas treatment method
View Patent ↗An object is to provide an exhaust-gas treatment apparatus capable of realizing a dissolved-salt spray method easily and at low cost. An exhaust-gas treatment apparatus that removes SO 2 and SO 3 contained in combustion exhaust gas includes a desulfurization apparatus based on the lime-gypsum method. Desulfurizing effluent, containing dissolved salt, from the desulfurization apparatus is sprayed to an upstream side of the desulfurization apparatus to remove SO 3 . A wet electrical dust precipitator may be provided downstream of the desulfurization apparatus. Furthermore, effluent from the wet electrical dust precipitator may be made to merge with the desulfurizing effluent from the desulfurization apparatus.
1. An exhaust-gas treatment method of removing SO2 and SO3 contained in combustion exhaust gas, using a desulfurization apparatus based on a lime-gypsum method that mainly removes SO2; a gypsum separator that separates gypsum from the desulfurization effluent from the desulfurization apparatus; a sedimentation tank that further separates the desulfurizing effluent from the gypsum separator into a sedimented liquid containing sedimented particulate solid content that has not been separated in the gypsum separator and a supernatant liquor;
a lower part of the sedimentation tank for taking out the sedimentation liquid from the sedimentation tank; a reservoir which is disposed in a bottom of the desulfurization apparatus and to which the sedimented liquid taken out from the lower part of the sedimentation tank is supplied; a pump for taking out the supernatant liquor from the sedimentation tank; and
a spray section having a spray nozzle that is designed to spray all of the supernatant liquor as atomized droplets, being supplied by the pump, to an upstream side of the desulfurization apparatus, said method comprising:
spraying desulfurizing effluent from the desulfurization apparatus based on a lime-gypsum method to an upstream side of the desulfurization apparatus, wherein
the supernatant liquor contains MgSO4 as a dissolved salt, and
an exit temperature of the spray nozzle is 130° C. or more,
atomized and dried particles of the dissolved salt produced from the atomized droplets adsorb SO3 in the combustion exhaust gas by spraying of the supernatant liquor,
the dissolved salt is reproduced at the reservoir from the dissolved salt that adsorbed SO3, and
the supernatant liquor of the desulfurizing effluent containing the reproduced dissolved salt is sprayed from the spray nozzle.