Gas vent for electrochemical cell
View Patent ↗An electrochemical cell system is configured to utilize an ionically conductive medium flowing through a plurality of electrochemical cells. One or more gas vents are provided along a flow path for the ionically conductive medium, so as to permit gasses that evolve in the ionically conductive medium during charging or discharging to vent outside the cell system, while constraining the ionically conductive medium within the flow path of the electrochemical cell system.
1. An electrochemical cell system comprising:
one or more electrochemical cells, each comprising:
(i) a fuel electrode comprising a metal fuel; and
(ii) an oxidant electrode spaced from the fuel electrode comprising active material;
a liquid ionically conductive medium for conducting ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes;
a housing configured to contain the ionically conductive medium in the one or more electrochemical cells;
a gas permeable and liquid impermeable membrane positioned along a portion of the housing and configured to close the portion of the housing to contain the ionically conductive medium therein, the gas permeable and liquid impermeable membrane having an inner surface facing the ionically conductive medium wherein the inner surface comprises a first portion and a second portion; wherein the first portion of the gas permeable and liquid impermeable membrane does not have the oxidant electrode active material and provides a vent for the cell to permit gas in the housing to permeate therethrough for venting of the gas from the one or more electrochemical cells and the second portion of the gas permeable and liquid impermeable membrane has the oxidant electrode active material to comprise the oxidant electrode; and
wherein the fuel electrode and the oxidant electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce an oxidant at the oxidant electrode to generate a discharge potential difference therebetween for application to a load.
2. The electrochemical cell system of claim 1 , wherein the gas permeable and liquid impermeable membrane comprises a fluoropolymer material.
3. The electrochemical cell system of claim 2 , wherein the fluoropolymer material comprises polytetrafluoroethylene.
4. The electrochemical cell system of claim 1 , wherein the liquid ionically conductive medium is configured to flow in a flow path through and among the one or more electrochemical cells.
5. The electrochemical cell system of claim 4 , wherein the gas permeable and liquid impermeable membrane is positioned downstream along the flow path from the fuel electrode and the oxidant electrode, and configured to vent by permeation gases generated during electrochemical reactions at the fuel and oxidant electrodes.
6. The electrochemical cell system of claim 4 , wherein the gas permeable and liquid impermeable membrane is configured to contact the ionically conductive medium while it flows through the flow path.
7. The electrochemical cell system of claim 5 , wherein the housing comprises a cell module configured to receive the fuel electrode, and at least one sidewall configured to receive the oxidant electrode and the gas permeable and liquid impermeable membrane, wherein the at least one sidewall is assembled onto the cell module to constrain the ionically conductive medium to the flow path.
8. The electrochemical cell system of claim 1 , wherein each electrochemical cell further comprises a charging electrode selected from the group consisting of (a) the oxidant electrode, (b) a separate charging electrode spaced from the fuel and oxidant electrodes, and (c) a portion of the fuel electrode.
9. The electrochemical cell system of claim 8 , wherein the fuel electrode and the charging electrode are configured to, during re-charge, reduce a reducible species of the metal fuel to electrodeposit the metal fuel on the fuel electrode and oxidize an oxidizable species of the oxidant by application of a re-charge potential difference therebetween from a power source.
10. The electrochemical cell system of claim 9 , wherein the fuel electrode comprises a series of permeable electrode bodies arranged in spaced apart relation;
wherein the spaced apart relation of the permeable electrode bodies enables the re-charge potential difference to be applied between the charging electrode and at least one of the permeable electrode bodies, with the charging electrode functioning as the anode and the at least one permeable electrode body functioning as the cathode, such that the reducible fuel species are reduced and electrodeposited as the metal fuel in oxidizable form on the at least one permeable electrode body, whereby the electrodeposition causes growth of the metal fuel among the permeable electrode bodies such that the electrodeposited metal fuel establishes an electrical connection between the permeable electrode bodies.
11. The electrochemical cell system of claim 9 , wherein the reducible species of the metal fuel comprises ions of zinc, iron, aluminum, magnesium, or lithium, and wherein the metal fuel is zinc, iron, aluminum, magnesium, or lithium.
12. The electrochemical cell system of claim 1 , wherein the ionically conductive medium comprises an aqueous electrolyte solution.
13. The electrochemical cell system of claim 12 , wherein the aqueous electrolyte solution comprises sulfuric acid, phosphoric acid, triflic acid, nitric acid, potassium hydroxide, sodium hydroxide, sodium chloride, potassium nitrate, or lithium chloride.
14. The electrochemical cell system of claim 1 , wherein each electrochemical cell has an associated said housing.
15. An electrochemical cell system comprising:
a housing;
one or more electrochemical cells positioned within the housing, each comprising:
(i) a fuel electrode comprising a metal fuel; and
(ii) an oxidant electrode spaced from the fuel electrode comprising active material;
a gas permeable and liquid impermeable membrane positioned to define a portion of a surface of the housing, wherein the gas permeable and liquid impermeable membrane comprises an inner surface having a first portion and a second portion;
a liquid ionically conductive medium, within the housing, for conducting ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes;
wherein the fuel electrode and the oxidant electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce an oxidant at the oxidant electrode to generate a discharge potential difference therebetween for application to a load;
wherein the gas permeable and liquid impermeable membrane is configured to prevent permeation of the ionically conductive medium out of the housing, the inner surface facing the ionically conductive medium, and wherein the first portion of the inner surface of the gas permeable and liquid impermeable membrane does not have the oxidant electrode active material and provides a vent for the cell to permit gas in the housing to permeate therethrough for venting of the gas from the one or more electrochemical cells, and the second portion of the gas permeable and liquid impermeable membrane has the oxidant electrode active material to comprise the oxidant electrode.