Positive electrode active material for nonaqueous electrolyte secondary battery, method for making the same, positive electrode including the same, and battery including the positive electrode
View Patent ↗A positive electrode active material for a nonaqueous electrolyte secondary battery includes a positive electrode active material particle and a compound containing a rare earth element and a carbonate, the compound having a particle size of 1 to 100 nm and being adhered to a surface of the positive electrode active material particle. The ratio of the compound relative to the positive electrode active material particle is 0.005% to 0.4% by mass on a rare earth element basis. The positive electrode active material particle is composed of a lithium transition metal oxide having a layered structure.
1. A nonaqueous electrolyte secondary battery comprising:
a positive electrode;
a negative electrode;
a separator; and
a nonaqueous electrolyte, wherein
the positive electrode comprising a positive electrode active material,
the positive electrode active material comprising:
positive electrode active material particles; and
particles comprising a compound containing a rare earth element and a carbonate,
wherein the particles comprising a compound containing a rare earth element and a carbonate have a particle size of 1 to 100 nm and the particles comprising a compound containing a rare earth element and a carbonate are directly dispersed particles on the positive electrode active material particles, and
wherein the ratio of the particles comprising a compound containing a rare earth element and a carbonate relative to the positive electrode active material particles is 0.005% to 0.4% by mass on a rare earth element basis, and
the positive electrode active material particles are composed of a lithium transition metal oxide having a layered structure.
2. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the nonaqueous electrolyte comprises a nitrile compound comprising a chain saturated hydrocarbon group and a nitrile group.
3. The nonaqueous electrolyte secondary battery according to claim 2 , wherein the number of nitrile groups in the nitrile compound is 2 or 3.
4. A method for making the nonaqueous electrolyte secondary battery of claim 1 , comprising making the nonaqueous electrolyte secondary battery by:
a compound adhering step of adhering particles comprising a compound containing a rare earth element and a carbonate to a surface of a positive electrode active material particle, the compound adhering step comprising
mixing a positive electrode active material particle with a solution in which carbon dioxide is dissolved, and
adding a solution in which a salt containing at least one element selected from rare earth elements is dissolved.
5. The method according to claim 4 , further comprising:
a heat treatment step of conducting heat treatment at a temperature of 500° C. or less after the compound adhering step.
6. The method according to claim 4 , wherein a bubbling technique is used to dissolve carbon dioxide in the solution.
7. The method according to claim 5 , wherein a bubbling technique is used to dissolve carbon dioxide in the solution.
8. The method according to claim 5 , wherein the heat treatment step is conducted at a temperature of from 80° C. to 500° C.
9. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the size of the particles comprising a compound containing a rare earth element and a carbonate compound are from 1 nm to 50 nm.
10. The nonaqueous electrolyte secondary battery according to claim 1 , wherein said lithium transition metal oxide comprises at least one selected from the group consisting of lithium cobaltate, a Ni—Co—Mn lithium complex oxide, a Ni—Al—Mn lithium complex oxide, and a Ni—Co—Al lithium complex oxide.
11. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the ratio of the particles comprising a compound containing a rare earth element and a carbonate to the positive electrode active material particles is 0.01% to 0.34% by mass on a rare earth element basis.
12. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the particles comprising a compound containing a rare earth element and a carbonate are evenly dispersed particles on the positive electrode active material particles.
13. The nonaqueous electrolyte secondary battery according to claim 11 , wherein the particles comprising a compound containing a rare earth element and a carbonate are evenly dispersed particles on the positive electrode active material particles.
14. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the rare earth element in the compound containing a rare earth element and a carbonate is at least one selected from erbium, lanthanum, neodymium, samarium, and europium.
15. The nonaqueous electrolyte secondary battery according to claim 11 , wherein the rare earth element in the compound containing a rare earth element and a carbonate is at least one selected from erbium, lanthanum, neodymium, samarium, and europium.
16. The nonaqueous electrolyte secondary battery according to claim 13 , wherein the rare earth element in the compound containing a rare earth element and a carbonate is at least one selected from erbium, lanthanum, neodymium, samarium, and europium.