Polarizing plate
Provided are a polarizing plate and a liquid crystal display device. The polarizing plate has lighter weight, a smaller thickness, and excellent physical properties such as durability, water resistance, workability, and light leakage preventing ability. In addition, the polarizing plate prevents curling occurring in the polarizing plate or a polarizer in formation thereof, and has excellent thermal resistance or thermal shock resistance.
1. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer is directly attached to at least one surface of the polarizer, and the first surface of the pressure-sensitive adhesive layer is directly attached to the adhesive layer,
wherein the first surface has a higher tensile modulus than the second surface,
wherein the first surface has a tensile modulus at 25° C. of 1 to 1,000 MPa, and
wherein the second surface has a tensile modulus at 25° C. of 0.01 to 1.0 MPa.
2. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the first surface has a tensile modulus at 25° C. of 1 to 1,000 MPa, and
wherein the second surface has a tensile modulus at 25° C. of 0.01 to 1.0 MPa.
3. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state, and
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound.
4. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound, and
wherein the epoxy compound has a weight average molecular weight of 1,000 to 5,000.
5. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound, and
wherein the acryl-based monomer is a hydrophilic acryl-based monomer or a hydrophobic acryl-based monomer.
6. The polarizing plate according to claim 5 , wherein the hydrophilic acryl-based monomer has a hydroxyl group, a carboxyl group or an alkoxy group.
7. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound, an acryl-based monomer, and 1 to 40 parts by weight of a reactive oligomer in a cured state, and
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound.
8. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes a non-solvent type adhesive composition including an epoxy compound and an acryl-based monomer in a cured state, and
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound.
9. A polarizing plate, comprising:
a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state, and having a viscosity at 25° C. of 5 to 1,000 cps, and
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound.
10. A liquid crystal display device, comprising:
a liquid crystal panel; and
a polarizing plate which is attached to one or both surfaces of the liquid crystal panel, and which comprises a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the liquid crystal panel is attached to the second pressure-sensitive adhesive layer,
wherein the first surface has a tensile modulus at 25° C. of 1 to 1,000 MPa, and
wherein the second surface has a tensile modulus at 25° C. of 0.01 to 1.0 MPa.
11. A liquid crystal display device, comprising:
a liquid crystal panel; and
a polarizing plate which is attached to one or both surfaces of the liquid crystal panel, and which comprises a polarizer; an active energy beam-curable adhesive layer; and a pressure-sensitive adhesive layer, which are sequentially disposed,
wherein the active energy beam-curable adhesive layer includes an adhesive composition including an epoxy compound and an acryl-based monomer in a cured state,
wherein the epoxy compound includes an alicyclic epoxy compound and a glycidyl ether-type epoxy compound,
wherein the pressure-sensitive adhesive layer includes a first pressure-sensitive adhesive layer forming a first surface; and a second pressure-sensitive adhesive layer forming a second surface, and the first and second surfaces include pressure-sensitive adhesive layers having different tensile modulus,
wherein the liquid crystal panel is a passive matrix-type panel, an active matrix-type panel, an in-plane switching panel or a vertically-aligned panel,
wherein the first surface has a tensile modulus at 25° C. of 1 to 1,000 MPa, and
wherein the second surface has a tensile modulus at 25° C. of 0.01 to 1.0 MPa.