IP Library Granted Patent US 9,359,558
Granted Patent B2
US 9,359,558 · App. 13/689,235 · Granted Jun 7, 2016

Carbon to liquids system and method of operation

Inventors: Vitali Victor Lissianski (Schenectady, NY); Surinder Prabhjot Singh (Schenectady, NY); Dhaval Ajit Bhandari (Troy, NY)
Assignee: General Electric Company
C10G2/34C10G2/32C10K3/04
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Quick Facts
Patent No.
US 9,359,558
App. No.
13/689,235
Granted
Jun 7, 2016
Kind
B2
Abstract

A method of operating a carbon to liquids system is provided. The method includes receiving a flow of syngas and reacting, in a reactor, the syngas and a catalyst in a Fischer-Tropsch reaction to produce a product including steam, wherein the reactor includes a polymeric material that is configured to permit the permeation of the steam therethrough. The method also includes recycling the permeated steam to a vessel positioned upstream from the reactor.

Claims (12)

1. A method of operating a carbon to liquids system comprising:

receiving a flow of a syngas into a reactor, wherein the reactor includes a polymeric material that permits permeation of steam through the material;

channeling a cooling fluid flow through the reactor past an outer surface of the material;

reacting the syngas in the presence of a catalyst in a Fischer-Tropsch reaction to produce a product and steam at or near an inner surface of the material, wherein the steam permeates through the material and forms a mixture of the cooling fluid and the steam in the reactor; and

thereafter recycling the mixture of the steam and the cooling fluid to a vessel positioned upstream from the reactor.

2. The method in accordance with claim 1 further comprising shifting the syngas to facilitate increasing a hydrogen to carbon monoxide ratio of the syngas, wherein the shifted syngas is reacted in the reactor.

3. The method in accordance with claim 1 , wherein the cooling fluid at least partially comprises natural gas.

4. The method in accordance with claim 3 , wherein recycling further comprises recycling the mixture of steam and cooling fluid to at least one of a steam methane reformer and a catalytic partial oxidation reactor wherein the mixture reduces the energy requirements of the reformer and/or reactor.

5. The method in accordance with claim 4 , wherein recycling further comprises recycling the mixture of steam and cooling fluid to at least one of a boiler and a heat exchanger before recycling the mixture of steam and cooling fluid to the steam methane reformer wherein the mixture reduces the energy requirements of the boiler and/or exchanger.

6. The method in accordance with claim 5 , wherein the recycling of the mixture of steam and cooling fluid to at least one of a boiler and a heat exchanger further comprises channeling the steam and cooling fluid directly to at least one of the boiler and the heat exchanger.

7. The method in accordance with claim 1 wherein recycling the mixture of steam and cooling fluid facilitates increasing conversion of the syngas during the Fischer-Tropsch reaction to greater than about 45%.

8. The method in accordance with claim 1 wherein the cooling fluid functions to maintain the temperature of the Fischer-Tropsch reaction at a predetermined temperature.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 22, 2019
From: GENERAL ELECTRIC COMPANY
To: AIR PRODUCTS AND CHEMICALS, INC.
Reel/Frame 050798/0659 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2013
From: LISSIANSKI, VITALI VICTOR; SINGH, SURINDER PRABHJOT; BHANDARI, DHAVAL AJIT
To: GENERAL ELECTRIC COMPANY
Reel/Frame 029620/0058 →
Continuity (1)
Related Publication 20140148520A1 · May 29, 2014