Polylactic acid-polyalkylene glycol copolymer with fast crystallization rate and composition comprising the same
The provided are a polylactic acid-polyalkylene glycol copolymer and a composition comprising the same which have excellent crystallization rate, wherein the polylactic acid-polyalkylene glycol copolymer is prepared by melt-reacting polylactic acid with polyalkylene glycol of which one end group is substituted with a functional group and has improved eco-friendliness, injection moldability, and excellent heat resistance which makes it to be suitably applied to various molded articles requiring great heat resistance, such as disposables, kitchen utensils and containers, electric-electronic parts and automobile parts.
1. A polylactic acid-polyalkylene glycol copolymer, wherein said polylactic acid-polyalkylene glycol copolymer is prepared by melt-reacting polylactic acid with a polyalkylene glycol of Formula 1,
wherein, R 1 is an amine, an isocyanate, a carbodiimide, or an aziridine; R 2 is hydrogen, a C 1 -C 8 alkyl or alkenyl group, or a C 6 -C 8 aryl group; R 3 is a C 1 -C 8 alkyl or alkenyl group, or a C 6 -C 8 aryl group; 1 is an integer from 0-200; and m is an integer from 0-200;
wherein said polylactic acid-polyalkylene glycol copolymer comprises 0.05-25.0 weight percent (wt %) of said polyalkylene glycol of Formula 1, and has a heat deformation temperature of 70° C. or more.
2. The polylactic acid-polyalkylene glycol copolymer according to claim 1 , wherein said polylactic acid is L-polylactic acid or D-polylactic acid.
3. A composition comprising 0.01-5.0 parts by weight of a nucleating agent, based on 100 parts by weight of the polylactic acid-polyalkylene glycol copolymer according to claim 1 .
4. A composition comprising 0.01-5.0 parts by weight of a nucleating agent, based on 100 parts by weight of the polylactic acid-polyalkylene glycol copolymer according to claim 2 .
5. The composition according to claim 3 , wherein said nucleating agent is at least one selected from the group consisting of a benzohydrazide derivative, talc, sodium stearate, calcium lactate, ethylene bis(12-hydroxystearylamide), a terephthalimide derivative, 1,4-cyclohexanedicarboxylic dianilide, and zinc phenyl phosphate.
6. The composition according to claim 4 , wherein said nucleating agent is at least one selected from the group consisting of a benzohydrazide derivative, talc, sodium stearate, calcium lactate, ethylene bis(12-hydroxystearylamide), a terephthalimide derivative, 1,4-cyclohexanedicarboxylic dianilide, and zinc phenyl phosphate.
7. The composition according to claim 3 , having a crystallinity degree of 40% or more, and a crystallization rate (t 1/2 ) of 15-30 seconds, when crystallization is induced at 110° C.
8. The composition according to claim 4 , having a crystallinity degree of 40% or more, and a crystallization rate (t 1/2 ) of 15-30 seconds, when crystallization is induced at 110° C.
9. The polylactic acid-polyalkylene glycol copolymer according to claim 1 , wherein the temperature for the melting-reaction is in the range of 160-250° C.