Degradable ball sealer
View Patent ↗High strength, degradable ball sealer for temporarily sealing off lower zones in a wellbore from the flow of a fluid injected into the well. The degradable ball sealer may also seal openings formed through slidable packers or sleeves received within a tubing string in the well, from the flow of a fluid injected into the well. The ball sealer includes an aluminum-based alloy matrix containing gallium, with graphitic carbon particulate and salt particulate homogeneously distributed within the aluminum-based alloy matrix.
1. A degradable article constructed of a high strength material comprising:
an aluminum-based alloy matrix containing gallium; and
a plurality of carbon particles and a plurality of salt particles homogeneously distributed within the aluminum-based alloy matrix,
wherein the concentration of gallium in the degradable article is highest at the outermost surface of the degradable article and the article is galvanically corrodible.
2. The degradable article of claim 1 , wherein the salt is selected from among metal halides, metal sulphides and metal carbonates, wherein the metal comprises one or more of lithium, sodium, potassium, beryllium, magnesium, calcium and strontium.
3. The degradable article of claim 1 wherein the high strength material comprises 10 to 35 percent by weight carbon, 3 to 25 percent by weight salt, 1 to 10 percent by weight gallium, and 45 to 85 percent by weight aluminum-based alloy.
4. The degradable article of claim 1 wherein the high strength material comprises 15 to 20 percent by weight carbon, 5 to 20 percent by weight salt, 1 to 9 percent by weight gallium, and 55 to 80 percent by weight aluminum-based alloy.
5. The degradable article of claim 1 wherein the gallium is almost entirely distributed within the primary phase grains of the aluminum-based alloy matrix.
6. The degradable article of claim 5 wherein at least 95 weight percent of the gallium is incorporated within aluminum grains.
7. The degradable article of claim 1 wherein the ball sealer is generally spherical.
8. The degradable article of claim 1 , wherein the article is a ball sealer for sealing an opening in a well from the flow of a fluid in the well, and the ball sealer is galvanically corrodible in the well so as to be dissolvable.