Polyvinylalcohol based resin adhesive for polarizing plate, polarizing plate including same, and an image display device
The present invention relates to an adhesive for a polarizing plate including a polyvinyl alcohol-based resin, a titanium lactate ammonium salt, hydroxycarboxylic acid and water, and having a pH of 3.5 to 6.5, thereby having improved adhesive strength and water resistance, and a polarizing plate and an image display device including the same.
1. An adhesive for a polarizing plate having a pH of 3.5 to 6.5, the adhesive comprising:
a polyvinyl alcohol-based resin;
titanium lactate ammonium salt;
hydroxycarboxylic acid; and
water,
wherein a weight ratio of the titanium lactate ammonium salt and the hydroxycarboxylic acid is 4:1 to 25:1.
2. The adhesive for a polarizing plate of claim 1 , wherein the polyvinyl alcohol-based resin includes one or more types selected from the group consisting of an acetoacetyl group-modified polyvinyl alcohol-based resin, a cation-modified polyvinyl alcohol-based resin and an anion-modified polyvinyl alcohol-based resin.
3. The adhesive for a polarizing plate of claim 1 , wherein the hydroxycarboxylic acid is a compound represented by the following Chemical Formula 2:
wherein, in Chemical Formula 2, R 1 and R 2 are each independently a C 1-5 alkyl group substituted with a hydroxyl group or a carboxyl group, an unsubstituted C 1-5 alkyl group, hydrogen or a hydroxyl group.
4. The adhesive for a polarizing plate of claim 1 , wherein the hydroxycarboxylic acid includes one or more types selected from the group consisting of lactic acid, citric acid, glycolic acid, malic acid, tartaric acid, glyceric acid and gluconic acid.
5. The adhesive for a polarizing plate of claim 1 , comprising:
the titanium lactate ammonium salt in 30 to 150 parts by weight;
the hydroxycarboxylic acid in 1 to 13 parts by weight; and
the water in 1000 to 10000 parts by weight, with respect to 100 parts by weight of the polyvinyl alcohol-based resin.
6. A polarizing plate comprising:
a polarizer;
a polymer film attached on one or both surfaces of the polarizer; and
an adhesive layer for attaching the polarizer and the polymer film,
wherein the adhesive layer is formed using the adhesive for a polarizing plate of claim 1 .
7. The polarizing plate of claim 6 , wherein the polymer film is a protective film formed with a cellulose-based resin.
8. The polarizing plate of claim 6 , wherein a percentage of a peeled area is 10% or less with respect to a total area when the polarizing plate is left for 24 hours at a temperature of 60° C. and relative humidity of 100%.
9. An image display device comprising the polarizing plate of claim 6 .
10. A polarizing plate comprising:
a polarizer;
a polymer film attached on one or both surfaces of the polarizer; and
an adhesive layer for attaching the polarizer and the polymer film,
wherein the adhesive layer is formed using the adhesive for a polarizing plate of claim 2 .
11. A polarizing plate comprising:
a polarizer;
a polymer film attached on one or both surfaces of the polarizer; and
an adhesive layer for attaching the polarizer and the polymer film,
wherein the adhesive layer is formed using the adhesive for a polarizing plate of claim 3 .
12. A polarizing plate comprising:
a polarizer;
a polymer film attached on one or both surfaces of the polarizer; and
an adhesive layer for attaching the polarizer and the polymer film,
wherein the adhesive layer is formed using the adhesive for a polarizing plate of claim 4 .
13. A polarizing plate comprising:
a polarizer;
a polymer film attached on one or both surfaces of the polarizer; and
an adhesive layer for attaching the polarizer and the polymer film,
wherein the adhesive layer is formed using the adhesive for a polarizing plate of claim 5 .